1.
Chem Commun (Camb)
; 60(13): 1715-1718, 2024 Feb 08.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38240022
RESUMO
One type of carbonyl-linked cobalt polyphthalocyanine (CL-CoPPc) is synthesised as catalysts for use in electrochemical carbon dioxide (CO2) reduction (ECR). Carbonyl linkages can decrease the intermolecular π-π stacking, and serve as intramolecular "gullies" to impede proton transfer and the hydrogen evolution reaction (HER). Therefore, the CL-CoPPc exhibits highly active and selective CO2 reduction to carbon monoxide (CO).