Nanotechnology for catalysis and solar energy conversion.

This roadmap on Nanotechnology for Catalysis and Solar Energy Conversion focuses on the application of nanotechnology in addressing the current challenges of energy conversion: 'high efficiency, stability, safety, and the potential for low-cost/scalable manufacturing' to quote from the contributed article by Nathan Lewis. This roadmap focuses on solar-to-fuel conversion, solar water splitting, solar photovoltaics and bio-catalysis. It includes dye-sensitized solar cells (DSSCs), perovskite solar cells, and organic photovoltaics. Smart engineering of colloidal quantum materials and nanostructured electrodes will improve solar-to-fuel conversion efficiency, as described in the articles by Waiskopf and Banin and Meyer. Semiconductor nanoparticles will also improve solar energy conversion efficiency, as discussed by Boschloo et al in their article on DSSCs. Perovskite solar cells have advanced rapidly in recent years, including new ideas on 2D and 3D hybrid halide perovskites, as described by Spanopoulos et al 'Next generation' solar cells using multiple exciton generation (MEG) from hot carriers, described in the article by Nozik and Beard, could lead to remarkable improvement in photovoltaic efficiency by using quantization effects in semiconductor nanostructures (quantum dots, wires or wells). These challenges will not be met without simultaneous improvement in nanoscale characterization methods. Terahertz spectroscopy, discussed in the article by Milot et al is one example of a method that is overcoming the difficulties associated with nanoscale materials characterization by avoiding electrical contacts to nanoparticles, allowing characterization during device operation, and enabling characterization of a single nanoparticle. Besides experimental advances, computational science is also meeting the challenges of nanomaterials synthesis. The article by Kohlstedt and Schatz discusses the computational frameworks being used to predict structure-property relationships in materials and devices, including machine learning methods, with an emphasis on organic photovoltaics. The contribution by Megarity and Armstrong presents the 'electrochemical leaf' for improvements in electrochemistry and beyond. In addition, biohybrid approaches can take advantage of efficient and specific enzyme catalysts. These articles present the nanoscience and technology at the forefront of renewable energy development that will have significant benefits to society.

Terahertz emission from lateral photo-Dember currents.

The photo-Dember effect is a source of impulsive THz emission following femtosecond pulsed optical excitation. This emission results from the ultrafast spatial separation of electron-hole pairs in strong carrier gradients due to their different diffusion coefficients. The associated time dependent polarization is oriented perpendicular to the excited surface which is inaptly for efficient out coupling of THz radiation. We propose a scheme for generating strong carrier gradients parallel to the excited surface. The resulting photo-Dember currents are oriented in the same direction and emit THz radiation into the favorable direction perpendicular to the surface. This effect is demonstrated for GaAs and In(0.53)Ga(0.47)As. Surprisingly the photo-Dember THz emitters provide higher bandwidth than photoconductive emitters. Multiplexing of phase coherent photo-Dember currents by periodically tailoring the photoexcited spatial carrier distribution gives rise to a strongly enhanced THz emission, which reaches electric field amplitudes comparable to a high-efficiency externally biased photoconductive emitter.

The effect of oral vocabulary on reading visually novel words: a comparison of the dual-route-cascaded and triangle frameworks.

Dual-route-cascaded (DRC) (e.g. Coltheart & Rastle, Journal of Experimental Psychology: Human Perception and Performance 20 (1994) 1197) and triangle framework (e.g. Seidenberg & McClelland, Psychological Review 96 (1989) 523) predictions were tested regarding the effect of having a word in oral vocabulary prior to reading that same word. Over two sessions, at intervals of 2--3 days, 44 Grade 1 (6--7-year-old) children were aurally familiarized with the sound and meaning of ten novel words (semantic oral instantiation), and with just the sound of another ten novel words (non-semantic oral instantiation). Two to three days later non-word naming performance was significantly more accurate for aurally trained novel words compared to pseudohomophones, which were in turn advantaged over untrained non-words. The semantic manipulation had no effect. Experiment 2 manipulated articulation during (non-semantic) training. Forty Grade 1 children participated. Again, aurally trained items were named more accurately and quickly than equivalently trained pseudohomophones, which were in turn advantaged over untrained non-words. The articulation manipulation had no effect. The results suggest that word-specific phonological information is represented in the reading system independently of semantic or articulatory influences. The results are interpreted as being problematic for both the DRC and triangle frameworks, but more so for the latter.

The development of terahertz sources and their applications.

The terahertz region of the electromagnetic spectrum spans the frequency range between the mid-infrared and the millimetre/microwave. This region has not been exploited fully to date owing to the limited number of suitable (in particular, coherent) radiation sources and detectors. Recent demonstrations, using pulsed near-infrared femtosecond laser systems, of the viability of THz medical imaging and spectroscopy have sparked international interest; yet much research still needs to be undertaken to optimize both the power and bandwidth in such THz systems. In this paper, we review how femtosecond near-infrared laser pulses can be converted into broad band THz radiation using semiconductor crystals, and discuss in depth the optimization of one specific generation mechanism based on ultra-fast transport of electrons and holes at a semiconductor surface. We also outline a few of the opportunities for a technology that can address a diverse range of challenges spanning the physical and biological sciences, and note the continuing need for the development of solid state, continuous wave, THz sources which operate at room temperature.

Conductivity of nanoporous InP membranes investigated using terahertz spectroscopy.

We have investigated the terahertz conductivity of extrinsic and photoexcited electrons in nanoporous indium phosphide (InP) at different pore densities and orientations. The form of electronic transport in the film was found to differ significantly from that for bulk InP. While photo-generated electrons showed Drude-like transport, the behaviour for extrinsic electrons deviated significantly from the Drude model. Time-resolved photoconductivity measurements found that carrier recombination was slow, with lifetimes exceeding 1 ns for all porosities and orientations. When considered together, these findings suggest that the surfaces created by the nanopores strongly alter the dynamics of both extrinsic and photoexcited electrons.

An experimental comparison of viewpoint-specific and viewpoint-independent models of object representation.

Four experiments that investigate the cognitive representation of objects in human observers are reported. Two broad classes of theory were examined: viewpoint-specific and viewpoint-independent models. The former postulate that the data structures underpinning object recognition correspond to discrete views and require additional processing to access them from unfamiliar viewpoints. The latter postulate data structures that are independent of any particular viewpoint and can be directly accessed from a wide range of viewpoints. Two experimental tasks were used: a sequential matching paradigm and a cognitive learning paradigm. Findings favour viewpoint-specific models over viewpoint-independent models.

Generation of high-power terahertz pulses in a prism.

A compact, high-power emitter of half-cycle terahertz (THz) radiation is demonstrated. The device consists of an epitaxial InAs emitter upon a GaAs prism and produces THz pulses that are 20 times more powerful than those from conventional planar InAs emitters. This improvement is a direct result of reorienting the transient THz dipole such that its axis is not perpendicular to the emitting surface.