RESUMO
In the title mol-ecule, C27H30N4O2S·C3H7NO, the fused piperidine and cyclo-hexane rings adopt a twin chair conformation and the phenyl groups occupy equatorial sites. The phenyl rings make a dihedral angle of 40.74â (2)°. In the crystal, the di-methyl-formamide solvent mol-ecule is connected to the main mol-ecule by an N-Hâ¯O hydrogen bond. An additional N-Hâ¯O hydrogen bond connects mol-ecules into chains along [100]. Pairs of weak C-Hâ¯O hydrogen bonds connect inversion-related chains. The ethyl group was refined as disordered over two sets of sites with an occupancy ratio of 0.660â (17):0.340â (17).
RESUMO
In the title mol-ecule, C21H20ClF2NO2, the piperidine ring adopts a slightly distorted boat conformation. The two benzene rings form a dihedral angle of 87.43â (1)°. A weak intra-molecular C-Hâ¯π inter-action is observed. In the crystal, weak C-Hâ¯O hydrogen bonds and weak C-Hâ¯π inter-actions connect the mol-ecules, forming a three-dimensional network.
RESUMO
In the title compound, C23H26ClNO2, the piperidin-4-one ring adopts a distorted boat conformation. The two p-tolyl rings are nearly normal to each other, making a dihedral angle of 83.33â (10)°. They are inclined to the mean plane of the piperidine ring by 73.2â (1) and 87.22â (9)°. In the crystal, there are no significant inter-molecular inter-actions present.