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1.
Sensors (Basel) ; 11(3): 3135-44, 2011.
Artigo em Inglês | MEDLINE | ID: mdl-22163790

RESUMO

Capacitive sensors are the most commonly used devices for the detection of humidity because they are inexpensive and the detection mechanism is very specific for humidity. However, especially for industrial processes, there is a lack of dielectrics that are stable at high temperature (>200 °C) and under harsh conditions. We present a capacitive sensor based on mesoporous silica as the dielectric in a simple sensor design based on pressed silica pellets. Investigation of the structural stability of the porous silica under simulated operating conditions as well as the influence of the pellet production will be shown. Impedance measurements demonstrate the utility of the sensor at both low (90 °C) and high (up to 210 °C) operating temperatures.


Assuntos
Capacitância Elétrica , Eletrônica/instrumentação , Umidade , Dióxido de Silício/química , Temperatura , Ouro/química , Microscopia Eletrônica de Transmissão , Nitrogênio/química , Porosidade , Difração de Raios X
2.
Chem Commun (Camb) ; 51(12): 2440-3, 2015 Feb 11.
Artigo em Inglês | MEDLINE | ID: mdl-25568901

RESUMO

Polymerization of 1,3,5-tris(4-bromophenyl)benzene via dehalogenation on graphene and hexagonal boron nitride is investigated by scanning tunneling microscopy experiments and density functional theory calculations. This work reveals how the interactions between molecules and graphene or h-BN grown on Ni(111) govern the surface-confined synthesis of polymers through C-C coupling.

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