The Effect of Powder and Emulsion Binders on the Tribological Properties of Particulate Filled Glass Fiber Reinforced Polymer Composites.

Investigations into polymer composites are mainly focused on properties dependent on glass fiber reinforcement and particulate fillers. In the present study, the effect of the binder was examined. The specimens were produced with two types of epoxy resin, with similar numbers of glass mat layers and similar proportions of quartz powder added. However, one group was fabricated with an emulsion binder in the glass mats and another group with a powder binder. Attention was concentrated on the tribological properties of the as-prepared composites, though their strength was examined as well. The hardness of the Sikafloor matrix was found to be much more sensitive to the applied binder than that of the MC-DUR matrix. No direct correlation between the microhardness and the specific wear rate was observed and increasing the particulate filler proportion did not cause a direct increase of the specific wear rate. In particular, the highest specific wear rate, around 350 J/g, was reached for both matrices with a 1% quartz addition when the emulsion binder was applied, while in the case of the powder binder it was with 6% quartz with the MC-DUR matrix, and there was no quartz addition with the Sikafloor matrix. The highest microhardness, HV0.5 = 25, in turn, was reached for the mats with the emulsion binder in the Sikafloor matrix with an addition of 10% quartz powder, while the highest friction coefficient was exhibited in the composite with the MC-DUR matrix, when 1% of the quartz powder and the emulsion binder were applied.

Comparative Evaluation of the Tribological Properties of Polymer Materials with Similar Shore Hardness Working in Metal-Polymer Friction Systems.

This article presents comparative tests of contact strength and tribological wear resistance of polymer sliding materials of the polyamide group. The aim of this work was to study Shore hardness, indentation hardness, modulus, creep, relaxation, Martens hardness and sliding wear resistance of two commercial materials. One of these materials was produced with the recycling process in mind. Abrasion tests were performed against a stainless-steel ball (100CRr6) on a normal load of 5 N for 23,830 friction cycles. The samples were tested under dry friction conditions and taking into account the hydrothermal factor, the presence of which was assumed in the anticipated operating conditions. It was distilled water at a temperature of 50 °C. The volumetric wear of the samples under various environmental conditions was assessed and related to the mechanical properties, in particular, Shore hardness. This mechanical size, which characterizes the surface, was considered the most frequently used by engineers selecting polymeric materials for tribological applications in industry. The Shore hardness of both materials was similar, which may indicate similar tribological performance properties. However, research and analysis indicate the need to use measures that directly correspond to tribological wear. The friction and wear of both materials varied. The coefficient of friction in hydrothermal conditions was lower and the wear was higher than in the dry friction test. It seems that it was not hardness that determined the suitability in the anticipated operating conditions, but the ability to form a sliding layer on the friction surface. The properties of the material that has been envisaged as a replacement may be appropriate for the intended uses.

Peculiarities of the Phase Formation during Electroconsolidation of Al2O3-SiO2-ZrO2 Powders Mixtures.

This paper is devoted to the sintering process of Al2O3-SiO2-ZrO2 ceramics. The studied method was electroconsolidation with directly applied electric current. This method provides substantial improvements to the mechanical properties of the sintered samples compared to the traditional sintering in the air. The research covered elemental and phase analysis of the samples, which revealed phase transition of high-alumina solid solutions into mullite and corundum. Zirconia was represented mainly by tetragonal phase, but monoclinic phase was present, too. Electroconsolidation enabled samples to reach a density of 3.0 g/cm3 at 1300 °C, while the sample prepared by traditional sintering method obtained it only at 1700 °C. For the composite Al2O3-20 wt.% SiO2-10 wt.% ZrO2 fabricated by electroconsolidation, it was demonstrated that fracture toughness was higher by 20-30%, and hardness was higher by 15-20% compared to that of samples sintered traditionally. Similarly, the samples fabricated by electroconsolidation exhibited elastic modulus E higher by 15-20%. The hypothesis was proposed that the difference in mechanical and physical properties could be attributed to the peculiarities of phase formation processes during electroconsolidation.

Analysis of the Electroconsolidation Process of Fine-Dispersed Structures Out of Hot Pressed Al2O3-WC Nanopowders.

Fabrication of alumina-tungsten carbide nanocomposite was investigated. Characteristics of the densification and sintering were analyzed considering both the nano-size particle starting powders and the processing stages. Different heating rates were generated during densification and consolidation with a maximal load was applied only after a temperature of 1000 °C was reached. Due to the varying dominance of different physical processes affecting the grains, appropriate heating rates and pressure at different stages ensured that a structure with submicron grains was obtained. With directly applied alternating current, it was found that the proportion Al2O3 (50 wt.%)-WC provided the highest fracture toughness, and a sintering temperature above 1600 °C was found to be disadvantageous. High heating rates and a short sintering time enabled the process to be completed in 12 min, saving energy and time.

Wear Resistance Improvement of Cemented Tungsten Carbide Deep-Hole Drills after Ion Implantation.

The paper is dedicated to the lifetime prolongation of the tools designed for deep-hole drilling. Among available methods, an ion implantation process was used to improve the durability of tungsten carbide (WC)-Co guide pads. Nitrogen fluencies of 3 × 1017 cm-2, 4 × 1017 cm-2 and 5 × 1017 cm-2 were applied, and scanning electron microscope (SEM) observations, energy dispersive spectroscopy (EDS) analyses, X-ray photoelectron spectroscopy (XPS) and Secondary Ion Mass Spectrometry (SIMS) measurements were performed for both nonimplanted and implanted tools. The durability tests of nonimplanted and the modified tools were performed in industrial conditions. The durability of implanted guide pads was above 2.5 times more than nonimplanted ones in the best case, presumably due to the presence of a carbon-rich layer and extremely hard tungsten nitrides. The achieved effect may be attributed to the dissociation of tungsten carbide phase and to the lubrication effect. The latter was due to the presence of pure carbon layer with a thickness of a few dozen nanometers. Notably, this layer was formed at a temperature of 200 °C, much smaller than in previously reported research, which makes the findings even more valuable from economic and environmental perspectives.

Effect of Yttrium and Rhenium Ion Implantation on the Performance of Nitride Ceramic Cutting Tools.

In the paper, the results of experimental investigations of ion implanted cutting tools performance are presented. The tools, made out of Si3N4 with additives typically used for turning of Ti-6Al-4V alloy, underwent implantation with ions of yttrium (Y+) and rhenium (Re+) using the metal vapor vacuum arc method. Distribution of ions on the tool surface was measured. The cutting tools were tested in turning process with measurement of cutting forces and analysis of wear. A rather unexpected result was the increased wear of the tool after Y+ implantation with 1 × 1017 ion/cm2. It was demonstrated, however, that the tool after Y+ 2 × 1017 ion/cm2 ion implantation provided the best machining performance.