Clean Block Copolymer Microparticles from Supercritical CO2: Universal Templates for the Facile and Scalable Fabrication of Hierarchical Mesostructured Metal Oxides.

Metal oxide microparticles with well-defined internal mesostructures are promising materials for a variety of different applications, but practical routes to such materials that allow the constituent structural length scales to be precisely tuned have thus far been difficult to realize. Herein, we describe a novel platform methodology that utilizes self-assembled block copolymer (BCP) microparticles synthesized by dispersion polymerization in supercritical CO2 (scCO2) as universal structure directing agents for both hydrolytic and nonhydrolytic sol-gel routes to metal oxides. Spherically structured poly(methyl methacrylate- block-4-vinylpyridine) (PMMA- b-P4VP) BCP microparticles are translated into a series of the corresponding organic/inorganic composites and pure inorganic derivatives with a high degree of fidelity for the metal oxides TiO2 and LiFePO4. The final products are comprised of particles close to 1 µm in size with a highly ordered internal morphology of interconnected spheres between 20-40 nm in size. Furthermore, our approach is readily scalable, enabling grams of pure or carbon-coated TiO2 and LiFePO4, respectively, to be fabricated in a facile two step route involving ambient temperature mixing and drying stages. Given that both length scales within these BCP microparticles can be controlled independently by minor variations in the reagent quantities used, the present general strategy could represent a milestone in the design and synthesis of hierarchical metal oxides with completely tunable dimensions.

Enabling the Polymer Circular Economy: Innovations in Photoluminescent Labeling of Plastic Waste for Enhanced Sorting.

It is widely accepted that moving from a linear to circular economy for plastics will be beneficial to reduce plastic pollution in our environment and to prevent loss of material value. However, challenges within the sorting of plastic waste often lead to contaminated waste streams that can devalue recyclates and hinder reprocessing. Therefore, the improvement of the sorting of plastic waste can lead to dramatic improvements in recyclate quality and enable circularity for plastics. Here, we discuss current sorting methods for plastic waste and review labeling techniques to enable enhanced sorting of plastic recyclates. Photoluminescent-based labeling is discussed in detail, including UV-vis organic and inorganic photoluminescent markers, infrared up-conversion, and X-ray fluorescent markers. Methods of incorporating labels within packaging, such as extrusion, surface coatings, and incorporation within external labels are also discussed. Additionally, we highlight some practical models for implementing some of the sorting techniques and provide an outlook for this growing field of research.