Thermogalvanic Hydrogel for Synchronous Evaporative Cooling and Low-Grade Heat Energy Harvesting.

Efficient heat removal and recovery are two conflicting processes that are difficult to achieve simultaneously. Here, in this work, we pave a new way to achieve this through the use of a smart thermogalvanic hydrogel film, in which the ions and water undergo two separate thermodynamic cycles: thermogalvanic reaction and water-to-vapor phase transition. When the hydrogel is attached to a heat source, it can achieve efficient evaporative cooling while simultaneously converting a portion of the waste heat into electricity. Moreover, the hydrogel can absorb water from the surrounding air to regenerate its water content later on. This reversibility can be finely designed. As an applicative demonstration, the hydrogel film with a thickness of 2 mm was attached to a cell phone battery while operating. It successfully decreased the temperature of the battery by 20 °C and retrieved electricity of 5 µW at the discharging rate of 2.2 C.

Programmable microfluidics for dynamic multiband camouflage.

Achieving multiband camouflage covering both visible and infrared regions is challenging due to the broad bandwidth and differentiated regulation demand in diverse regions. In this work, we propose a programmable microfluidic strategy that uses dye molecules in layered fluids to manipulate visible light- and infrared-semitransparent solvent to manipulate infrared light. With three primary fluid inputs, we achieve 64 chromaticity values and 8 emissivities from 0.42 to 0.90. In view of the wide tuning range, we demonstrate that the microfluidic film can dynamically change its surface reflectance to blend into varying backgrounds in both visible and infrared images. Moreover, we fabricate the microfluidic device in a textile form and demonstrate its ability to match exactly with the colors of natural leaves of different seasons in the full hyperspectrum range. Considering the broadband modulation and ease of operation, the programmable microfluidic strategy provides a feasible approach for smart optical surfaces in long-span optical spectra.

Stretchable and Self-Powered Temperature-Pressure Dual Sensing Ionic Skins Based on Thermogalvanic Hydrogels.

Tactile sensors with both temperature- and pressure-responsive capabilities are critical to enabling future smart artificial intelligence. These sensors can mimic haptic functions of human skin and inevitably suffer from tensile deformation during operation. However, almost all actual multifunctional tactile sensors are either nonstretchable or the sensing signals interfere with each other when stretched. Herein, we propose a stretchable and self-powered temperature-pressure dual functional sensor based on thermogalvanic hydrogels. The sensor operates properly under stretching, which relies on the thermogalvanic effect and constant elastic modulus of hydrogels. The thermogalvanic hydrogel elastomer exhibits an equivalent Seebeck coefficient of -1.21 mV K-1 and a pressure sensitivity of 0.056 kPa-1. Combined with unit array integration, the multifunctional sensor can be used for accurately recording tactile information on human skin and spatial perception. This work provides a conceptual framework and systematic design for stretchable artificial skin, interactive wearables, and smart robots.

Broadband light management in hydrogel glass for energy efficient windows.

Windows are critically important components in building envelopes that have a significant effect on the integral energy budget. For energy saving, here we propose a novel design of hydrogel-glass which consists of a layer of hydrogel and a layer of normal glass. Compared with traditional glass, the hydrogel-glass possesses a higher level of visible light transmission, stronger near-infrared light blocking, and higher mid-infrared thermal emittance. With these properties, hydrogel-glass based windows can enhance indoor illumination and reduce the temperature, reducing energy use for both lighting and cooling. Energy savings ranging from 2.37 to 10.45 MJ/m2 per year can be achieved for typical school buildings located in different cities around the world according to our simulations. With broadband light management covering the visible and thermal infrared regions of the spectrum, hydrogel-glass shows great potential for application in energy-saving windows.

Single-layer graphene prevents Cassie-wetting failure of structured hydrophobic surface for efficient condensation.

HYPOTHESIS: Structured hydrophobic surfaces often suffer from Cassie-wetting failure due to trapped water in structure gaps for a long-term operation. Sustainable Cassie-wetting on such surface could be achieved by coating an atom-thick and moisture-impermeable graphene on it. EXPERIMENTS: Water contact angles were measured to clarify the effect of graphene on wetting, and water impermeability was verified by moisture deposition and evaporation. Sliding angle measurements and vapor condensation were carried out to demonstrate the stable Cassie-state wetting and application. FINDINGS: Interestingly we found the graphene does not significantly disrupt the wetting behavior of the structured hydrophobic surface, showing a wettability transparency. Moreover, the impermeability of graphene keeps moisture away from the structure gaps. Owning to the combination of these two properties, droplets on the graphene-coated structured surface exhibit a stable Cassie-state hydrophobic wetting, even under the situation of moisture deposition and evaporation. Using the modified surface, we also found a 40-100% increase in condensation efficiency for a 5-hour vapor condensation at a subcooling of 40 °C. These results suggest an effective strategy to prevent Cassie-wetting failure of structured hydrophobic surface and are expected to promote its further application in more complex conditions.

An Experimental Study on the Dynamic Mechanical Properties of Epoxy Polymer Concrete under Ultraviolet Aging.

Epoxy polymer concrete (EPC) is widely applied in engineering for its excellent mechanical properties. The impact loads and severe climatic conditions such as ultraviolet radiation, temperature change and rain erosion are in general for its engineering practice, potentially degrading the performance of EPC. In this paper, a procedure of accelerated aging for EPC, imitating the aging effect of ultraviolet radiation and hygrothermal conditions based on the meteorological statistics of Guangzhou city, was designed. After various periods of accelerated aging, the dynamic behaviors of EPC were studied by using a Split Hopkinson Pressure Bar (SHPB). The verification of the experimental data was performed. The two-stage dynamic compression stress-strain curves were obtained: (a) linear growth stage following by strain hardening stage at impact velocity 12.2 m/s and 18.8 m/s, (b) linear growth stage and then a horizontal stage when impact velocity is 25.0 m/s, (c) linear growth stage following by strain softening stage at impact velocity 29.2 m/s. The experimental results show that the specimens after longer accelerated aging tend to be more easily broken, especially at impact velocity 12.2 m/s and 18.8 m/s, while the strain rate is the main factor affecting the compression strength and stiffness. Ultimately the influence of strain rate and equivalent aging time on dynamic increase factor was revealed by a fitting surface.

Promoting Energy Efficiency via a Self-Adaptive Evaporative Cooling Hydrogel.

High temperature brings adverse impacts on the energy efficiency, and even destroys a semiconductor device. Here, a novel and cost-effective strategy is proposed to boost the energy efficiency of semiconductor devices by using the self-adaptive evaporative cooling of a lithium- and bromine-enriched polyacrylamide hydrogel. Water inside the hydrogel can quickly evaporate to dissipate the waste heat generated by the nugatory carrier transport in the P-N junction. In dormancy, the hydrogel harvests water molecules from the surrounding air to regenerate itself. The hydrogel is demonstrated to low down the operating temperature of a commercial polycrystalline silicon solar cell by 17 °C under one sun condition and enhances its efficiency from 14.5% to 15.5%. It is also capable of increasing the maximum power of a simulated chip by 45% at a fixed operating temperature. The hydrogel is expected to be widely adopted in current semiconductor industry to improve its energy efficiency.