PVDF-HFP@Nafion-based quasisolid polymer electrolyte for high migration number in working rechargeable Na-O2 batteries.

Rechargeable sodium-oxygen (Na-O2) battery is deemed as a promising high-energy storage device due to the abundant sodium resources and high theoretical energy density (1,108 Wh kg-1). A series of quasisolid electrolytes are constantly being designed to restrain the dendrites growth, the volatile and leaking risks of liquid electrolytes due to the open system of Na-O2 batteries. However, the ticklish problem about low operating current density for quasisolid electrolytes still hasn't been conquered. Herein, we report a rechargeable Na-O2 battery with polyvinylidene fluoride-hexafluoropropylene recombination Nafion (PVDF-HFP@Nafion) based quasisolid polymer electrolyte (QPE) and MXene-based Na anode with gradient sodiophilic structure (M-GSS/Na). QPE displays good flame resistance, locking liquid and hydrophobic properties. The introduction of Nafion can lead to a high Na+ migration number (tNa+ = 0.68) by blocking the motion of anion and promote the formation of NaF-rich solid electrolyte interphase, resulting in excellent cycling stability at relatively high current density under quasisolid environment. In the meantime, the M-GSS/Na anode exhibits excellent dendrite inhibition ability and cycling stability. Therefore, with the synergistic effect of QPE and M-GSS/Na, constructed Na-O2 batteries run more stably and exhibit a low potential gap (0.166 V) after an initial 80 cycles at 1,000 mA g-1 and 1,000 mAh g-1. This work provides the reference basis for building quasisolid state Na-O2 batteries with long-term cycling stability.

High Efficiency Alkaline Iodine Batteries with Multi-Electron Transfer Enabled by Bi/Bi2O3 Redox Mediator.

The multi-electron transfer I-/IO3- redox couple is attractive for high energy aqueous batteries. Shifting from an acidic to an alkaline electrolyte significantly enhances the IO3- formation kinetics due to the spontaneous disproportionation reaction, while the alkaline environment also offers more favorable Zn anode compatibility. However, sluggish kinetics during the reduction of IO3- persists in both acidic and alkaline electrolytes, compromising the energy efficiency of this glorious redox couple. Here, we establish the fundamental redox mechanism of the I-/IO3- couple in alkaline electrolytes for the first time and propose that Bi/Bi2O3 acts as a redox mediator (RM) to "catalyze" the reduction of IO3-. This mediation significantly reduces the voltage gap between charge/discharge from 1.6 V to 1 V with improved conversion efficiency and rate capability. By pairing the Zn anode and the Bi/Bi2O3 RM cathode, the full battery with I-/IO3- redox mechanism achieves high areal capacity of 12 mAh cm-2 and stable operation at 5 mAh cm-2 for over 400 cycles.

Molting in early Cambrian armored lobopodians.

Lobopodians represent a key step in the early history of ecdysozoans since they were the first animals to evolve legs within this clade. Their Cambrian representatives share a similar body plan with a typically cylindrical annulated trunk and a series of non-jointed legs. However, they do not form a monophyletic group and likely include ancestors of the three extant panarthropod lineages (Tardigrada, Onychophora, Euarthropoda). Some species display astonishing protective devices such as cuticular plates and spines. We describe here the armor and molting process of Microdictyon from the early Cambrian of China. Microdictyon secreted ovoid paired cuticular sclerites that were duplicated in a non-synchronous way along the animal's body. The reticulated pattern and cuticular architecture of these sclerites have similarities to extant armored tardigrades that recently served in hypothesizing that tardigrades are possibly miniaturized lobopodians. Ecdysis and hard cuticular protection are now well documented in the whole spectrum of early Cambrian ecdysozoans such as soft-bodied scalidophorans, lobopodians and fully articulated euarthropods. We hypothesize that the secretion of sclerotized cuticular elements periodically renewed via ecdysis was a key innovation that opened large-scale evolutionary opportunities to invertebrate animal life, specifically ecdysozoans, both in terms of anatomical functionalities and ecological success.

Practical four-electron zinc-iodine aqueous batteries enabled by orbital hybridization induced adsorption-catalysis.

The successive I-/I0/I+ redox couples in the four-electron zinc-iodine aqueous battery (4eZIB) is plagued by the instability of the electrophilic I+ species, which could either be hydrolyzed or be neutralized by the I3- redox intermediates. We present an adsorption-catalysis approach that effectively suppresses the hydrolysis of ICl species and also provides an enhanced reaction kinetics to surpass the formation of triiodide ions. We elucidate that the improved stability is attributed to the pronounced orbital hybridization between the d orbitals of Fe-N4 moieties (atomic Fe supported on nitrogen doped carbon) and the p orbitals of iodine species (I2 and ICl). Such d-p orbital hybridization leads to enhanced adsorption for iodine species, increased energy barrier for proton detachment from the ICl·HOH intermediate during hydrolysis, and efficient catalysis of the iodine redox reactions with high conversion efficiency. The proposed 4eZIB demonstrates practical areal capacity (>3 mAh cm-2) with a near-unity coulombic efficiency, high energy density of 420 Wh kg-1 (based on cathode mass), and long-term stability (over 10,000 cycles). Even at -20 °C, the battery exhibits stable performance for over 1000 cycles with high iodine utilization ratio.

A twelve-electron conversion iodine cathode enabled by interhalogen chemistry in aqueous solution.

The battery chemistry aiming for high energy density calls for the redox couples that embrace multi-electron transfer with high redox potential. Here we report a twelve-electron transfer iodine electrode based on the conversion between iodide and iodate in aqueous electrolyte, which is six times than that of the conventional iodide/iodine redox couple. This is enabled by interhalogen chemistry between iodine (in the electrode) and bromide (in the acidic electrolyte), which provides an electrochemical-chemical loop (the bromide-iodate loop) that accelerates the kinetics and reversibility of the iodide/iodate electrode reaction. In the deliberately designed aqueous electrolyte, the twelve-electron iodine electrode delivers a high specific capacity of 1200 mAh g-1 with good reversibility, corresponding to a high energy density of 1357 Wh kg-1. The proposed iodine electrode is substantially promising for the design of future high energy density aqueous batteries, as validated by the zinc-iodine full battery and the acid-alkaline decoupling battery.

[Studies on the degradation of paracetamol in sono-electrochemical oxidation].

A novel lead dioxide electrodes co-doped with rare earth and polytetrafluoroethylene (PTFE) were prepared by the electrode position method and applied as anodes in sono-electrochemical oxidation for pharmaceutical wastewater degradation. The results showed that the APAP removal and the mineralization efficiency reached an obvious increase, which meant that the catalytic efficiency showed a significant improvement in the use of rare-earth doped electrode. The effects of process factors showed that the condition of the electrode had the best degradation efficiency with doped with Ce2O3 under electrolyte concentration of 14.2 g x L(-1), 49.58 W x cm(-2), 50 Hz, pH = 3, 71.43 mA x cm(-2). The APAP of 500 mg x L(-1) removal rate reached 92.20% and its COD and TOC values declined to 79.95% and 58.04%, the current efficiency reached 45.83% after degradation process for 2.0 h. The intermediates were monitored by the methods of GC-MS, HPLC, and IC. The main intermediates of APAP were p-benzoquinone, benzoic acid, acetic acid, maleic acid, oxalic acid, formic acid etc, and the final products were carbon dioxide and water. The goal of completely degradation of pollutant was achieved and a possible degradation way was proposed.