Novel P-T Phase Diagram of the Multiorbital Mott Insulator Sr2VO4.

The electrical and optical properties of the Mott insulator Sr2VO4 are investigated under high pressure on a phase pure polycrystalline sample. The system undergoes a pressure-driven insulator to metal transition (IMT) with a crossover between 20 and 24 GPa. The effect of pressure on the thermally driven electronic changes resulting from spin-orbital ordering transitions is studied. A multiorbital analysis of the low frequency optical conductivity spectra suggests a bandwidth-controlled and orbital selective nature of the Mott IMT transition. Dramatic enhancement of the low energy spectral weight in the high pressure correlated metallic phase is explained in terms of the formation of a quasiparticle peak in the spectral function of the narrow and degenerate d(yz,zx) orbitals. Our results overall establish a novel electronic phase diagram of tetragonal Sr2VO4.

Structural and optical investigations of Fe1.03Se0.5Te0.5 under high pressure.

Optimally doped iron-chalcogenide superconductor Fe1.03Se0.5Te0.5 has been investigated under high pressures using synchrotron-based x-ray diffraction and mid-infrared reflectance measurements at room temperature. The superconducting transition temperature (Tc) of the same sample has been determined by temperature-dependent resistance measurements up to 10 GPa. The tetragonal phase (P4/nmm) is found to exist in phase-separated states where both the phases have remarkably high compressibility. A first-order structural transition to the orthorhombic phase (Pbnm) is reported above 10 GPa. For the tetragonal phase, a strong correlation is observed between the Fe(Se,Te)4 tetrahedral deformation and the sharp rise of Tc up to ∼ 4 GPa, above which Tc shows marginal pressure dependence at least up to 10 GPa. The evolution with pressure of the optical conductivity shows that with increasing pressure the tetragonal phase approaches towards a conventional metallic state. Above ∼ 6 GPa, the Drude term reduces drastically, indicating poor metallic character of the high-pressure orthorhombic phase.

High pressure structural and vibrational properties of the spin-gap system Cu2PO4(OH).

The structural and vibrational properties of the spin-gapped system Cu(2)PO(4)(OH) have been investigated at room temperature under high pressure up to ~20 GPa by Raman scattering and synchrotron-based x-ray diffraction and infrared (IR) spectroscopic measurements. The orthorhombic phase (space group Pnnm, z = 4) remains stable up to at least 7 GPa where it undergoes a weakly first order structural transition (with negligible volume drop) to a monoclinic phase (space group P2(1)/n, z = 4) with an abrupt monoclinic distortion. Refinement of atomic positions has been performed for the low pressure phase. The conspicuous changes in the vibrational spectra (Raman as well as far-IR) confirm this phase transition. At further higher pressures the monoclinic angle increases rapidly and the system transforms irreversibly into a disordered phase. Detailed vibrational analyses have been performed in the orthorhombic phase and pressure-induced structural evolution has been correlated with the vibrational modes corresponding to the Cu-O bonds. A strong negative pressure dependence of hydroxyl mode frequencies (as observed from the mid-IR absorption spectra) supports the pressure-induced structural disordering at higher pressures.