Reversible degradation of inverted organic solar cells by concentrated sunlight.

Concentrated sunlight was used to study the performance response of inverted P3HT:PCBM organic solar cells after exposure to high intensity sunlight. Correlations of efficiency as a function of solar intensity were established in the range of 0.5-15 suns at three different stages: for a pristine cell, after 30 min exposure at 5 suns and after 30 min of rest in the dark. High intensity exposure introduced a major performance decrease for all solar intensities, followed by a partial recovery of the lost performance over time: at 1 sun only 6% of the initial performance was conserved after the high intensity exposure, while after rest the performance had recovered to 60% of the initial value. The timescale of the recovery effect was studied by monitoring the cell performance at 1 sun after high intensity exposure. This showed that cell performance was almost completely restored after 180 min. The transient state is believed to be a result of the breakdown of the diode behaviour of the ZnO electron transport layer by O(2) desorption, increasing the hole conductivity. These results imply that accelerated degradation of organic solar cells by concentrated sunlight is not a straightforward process, and care has to be taken to allow for a sound accelerated lifetime assessment based on concentrated sunlight.

Luminescent Solar Power-PV/Thermal Hybrid Electricity Generation for Cost-Effective Dispatchable Solar Energy.

The challenge in solar energy today is not the cost of photovoltaic (PV) electricity generation, already competing with fossil fuel prices, but rather utility-scale energy storage and flexibility in supply. Low-cost thermal energy storage (TES) exists but relies on expensive heat engines. Here, we introduce the concept of luminescent solar power (LSP), where sunlight is absorbed in a photoluminescent (PL) absorber, followed by red-shifted PL emission matched to an adjacent PV cell's band edge. This way the PV cell operates nearly as efficiently as under direct illumination but with minimal excessive heat. The PL absorber temperature rises because of thermalization, allowing it to store the excessive heat, which can later be converted into electricity. Tailored luminescent materials that support an additional 1.5 kW h PV electricity for every 1 kW h of (virtual) heat engine electricity with a dynamic shift between the two sources are experimentally demonstrated. Such an ideal hybrid system may lead to a potential reduction in the cost of electricity for a base-load solution.

Thermally enhanced photoluminescence for heat harvesting in photovoltaics.

The maximal Shockley-Queisser efficiency limit of 41% for single-junction photovoltaics is primarily caused by heat dissipation following energetic-photon absorption. Solar-thermophotovoltaics concepts attempt to harvest this heat loss, but the required high temperatures (T>2,000 K) hinder device realization. Conversely, we have recently demonstrated how thermally enhanced photoluminescence is an efficient optical heat-pump that operates in comparably low temperatures. Here we theoretically and experimentally demonstrate such a thermally enhanced photoluminescence based solar-energy converter. Here heat is harvested by a low bandgap photoluminescent absorber that emits thermally enhanced photoluminescence towards a higher bandgap photovoltaic cell, resulting in a maximum theoretical efficiency of 70% at a temperature of 1,140 K. We experimentally demonstrate the key feature of sub-bandgap photon thermal upconversion with an efficiency of 1.4% at only 600 K. Experiments on white light excitation of a tailored Cr:Nd:Yb glass absorber suggest that conversion efficiencies as high as 48% at 1,500 K are in reach.