Ink-jet printed, blended polymer-based microdisk resonators for controlling non-specific adsorption of biomolecules: publisher's note.

This publisher's note contains corrections to Opt. Lett.46, 262 (2021).OPLEDP0146-959210.1364/OL.412993.

Ink-jet printed, blended polymer-based microdisk resonators for controlling non-specific adsorption of biomolecules.

A blended FC-V-50 and TZ-001 polymer-based microdisk laser was fabricated by the ink-jet printing method and used for biosensing applications. The FC-V-50 polymer has a negative charge due to the presence of carboxyl functional groups, and the TZ-001 polymer has a positive charge due to the tertiary amine group at a pH of seven. In biosensing applications, non-specific adsorption due to opposite charges of biomolecules and microdisk surfaces can adversely affect the performance of the biosensor. By mixing FC-V-50 and TZ-001 polymers in different ratios, the microdisk surface charge was controlled, and the non-specific adsorption of bovine serum albumin and lysozyme was studied. In addition, the label-free biosensing of streptavidin was demonstrated using a blended polymer-based microdisk laser. This work reports, to the best of our knowledge, the first demonstration of a blended polymer microdisk laser for controlling the non-specific adsorption of biomolecules.

On-demand inkjet-printed microdisk laser with air cladding by liquid flow microetching.

We have novelly, to the best of our knowledge, developed the liquid flow microetching method that can treat a single microdisk in a microregion with precise position control for inkjet-printed microdisk lasers. The injection-drain wet etching setup consisted of two microneedles that successfully performed a formation of a fine undercut structure of an inkjet-printed microdisk on a pre-pedestal layer through the individual wet etching process. Then measurement of the undercut structure using scanning electron microscopy and lasing characteristics with whispering gallery modes were carried out to demonstrate performance of the etched microdisks. The measured lasing threshold decreased by half compared with that of the unetched microdisk directly printed on a fluorine-type film. A point to note is that this etching method exhibits an excellent undercut and lasing characteristics even when using a clad pre-pedestal layer having a refractive index higher than that of core microdisks. This technique, combined with inkjet printing, offers a powerful tool for individually designing a microdisk and can help develop novel devices that comprise several inkjet-printed microdisks being evanescently coupled.

Organic-inorganic hybrid microdisk laser with dye and silica mixed doping prepared by ink-jet printing method.

We developed an ink-jet printing method for fabricating inorganic microdisks at room temperature, which is much lower than the melting point of solid-state inorganic oxide, and have fabricated an organic-inorganic hybrid microdisk laser. Silica was used as the inorganic disk material, and microdisk-shaped aggregates were formed by the ink-jet printing method using a solution in which nanosilica particles were dispersed in propylene glycol monomethylether (PGME) solvent. Then, a microdisk capable of laser oscillation was also prepared by preliminarily adding the laser dye rhodamine 6G to the ink to form a mixed organic material. The structural evaluation of the printed microdisk was first conducted using an optical microscope, a scanning electron microscope (SEM), and an atomic force microscope (AFM). The results of laser oscillation evaluation by optical excitation showed that the printed microdisk sufficiently functions as an optical resonator with a low optical loss. In these evaluations, excellent values such as a surface roughness of 5.83 nm from root mean square (R. M. S.) which is one forth smaller than the particle diameter, and a laser oscillation threshold of 4.76 µJ/mm2 at a wavelength of 601.4 nm were obtained. To the best of our knowledge, this is the first time that an inorganic microdisk has been fabricated at room temperature to realize an organic-inorganic hybrid microdisk laser.