Component analysis of fat, oil and grease in wastewater: challenges and opportunities.

The presence of fat, oil and grease can lead to blockages in sewer lines, pumps, and treatment plant operations, thereby creating health risks and environmental hazards. These deposits primarily consist of fatty acids, triglycerides and soap, among other components. These three main components are hydrophobic and insoluble in water. The composition of FOG can vary significantly depending on the source, such as food service establishments, households, or industrial processes. Several analytical methods, such as chromatographic, gravimetric, chemical and spectroscopic analysis, are used to measure different FOG components. AOAC, Gerber and APHA are the most commonly utilized standardized analytical methods for measuring FOG components. The AOAC and Gerber methods, which use gas chromatography, tend to provide more accurate results compared to other methods. This can be attributed to GC's ability to measure individual fatty acids in FOG samples by separating and quantifying each compound based on its unique chemical properties, such as volatility, polarity and molecular weight. Similarly, high-performance liquid chromatography is capable of measuring glycerides by separating and quantifying them based on their polarity and molecular weight. This article delves into the challenge of accurately measuring FOG concentrations and evaluates various FOG measurement technologies. The study also discusses the need for standardized methods for FOG measurement, highlighting the importance of understanding FOG deposits and the performance of grease interceptors.

A Comprehensive Review of the Current Progress of Chromium Removal Methods from Aqueous Solution.

Chromium (Cr) exists in aqueous solution as trivalent (Cr3+) and hexavalent (Cr6+) forms. Cr3+ is an essential trace element while Cr6+ is a dangerous and carcinogenic element, which is of great concern globally due to its extensive applications in various industrial processes such as textiles, manufacturing of inks, dyes, paints, and pigments, electroplating, stainless steel, leather, tanning, and wood preservation, among others. Cr3+ in wastewater can be transformed into Cr6+ when it enters the environment. Therefore, research on Cr remediation from water has attracted much attention recently. A number of methods such as adsorption, electrochemical treatment, physico-chemical methods, biological removal, and membrane filtration have been devised for efficient Cr removal from water. This review comprehensively demonstrated the Cr removal technologies in the literature to date. The advantages and disadvantages of Cr removal methods were also described. Future research directions are suggested and provide the application of adsorbents for Cr removal from waters.

Generation and consequence of nano/microplastics from medical waste and household plastic during the COVID-19 pandemic.

Since the end of 2019, the world has faced a major crisis because of the outbreak of COVID-19 disease which has created a severe threat to humanity. To control this pandemic, the World Health Organization gave some guidelines like wearing PPE (personal protective equipment) (e.g., face masks, overshoes, gloves), social distancing, hand hygiene and shutting down all modes of public transport services. During this pandemic, plastic products (e.g., household plastics, PPE and sanitizer bottles) have substantially prevented the spread of this virus. Since the outbreak, approximately 1.6 million tons of plastic waste have been generated daily. However, single-use PPE like face masks (N95), surgical masks and hand gloves contain many non-biodegradable plastics materials. These abandoned products have created a huge number of plastic debris which ended up as microplastics (MPs) followed by nanoplastics (NPs) in nature that are hazardous to the eco-system. These MPs and NPs also act as vectors for the various pathogenic contaminants. The goal of this review is to offer an extensive discussion on the formation of NPs and MPs from all of these abandoned plastics and their long-term impact on the environment as well as human health. This review paper also attempts to assess the present global scenario and the main challenge of waste management to reduce the potential NP/MPs pollution to improve the eco-systems.

Nano/microplastics: Fragmentation, interaction with co-existing pollutants and their removal from wastewater using membrane processes.

NANO: and microplastic (NP/MP) is one of the most challenging types of micropollutants, coming from either direct release or degradation of plastic items into ecosystems. NP/MP can adsorb hazardous pollutants (such as heavy metals and pharmaceutical compounds) and pathogens onto their surface that are consumed by humans, animals, and aquatic living organisms. This paper presents the interaction of NP/MP with other pollutants in the water environment and mechanisms involved to enable the ultimate fate of NP/MP as well as the effectiveness of metal-organic frame (MOF)-based membrane over conventional membrane processes for NP/MP removal. It is found that conventional membranes could remove MPs when their size is usually more than 1000 nm, but they are ineffective in removing NPs. These NPs have potentially greater health impacts due to their greater surface area. MOF-based membrane could effectively remove both NP and MP due to its large porous structure, high adsorption capacity, and low density. This paper also discusses some challenges associated with MOF-based membranes for NP/MP removal. Finally, we conclude a specific MOF-based ultrafiltration membrane (ED-MIL-101 (Cr)) that can potentially remove both negative and positive charged NP/MP from wastewater by electrostatic attraction and repulsion force with efficient water permeability.

Understanding the fate of nano-plastics in wastewater treatment plants and their removal using membrane processes.

Nanoplastics (NPs) have become a major environmental issue due to their adverse effect on the water environment. Wastewater treatment plant (WWTP) is considered as one of the main sources for breaking down of larger-sized plastic debris and microplastics (MPs) into NPs. This study aims to provide a comprehensive understanding of NPs generation in the WWTPs, their physiochemical characteristics and interaction with the WWTPs. It is found that cracking is the major mechanism of plastics fragmentation in the WWTPs. This review also discusses the current membrane process used for NPs removal. It is found that conventional membrane processes are ineffective as they are not designed for NPs removal and fouling is a major obstacle for its application. Therefore, this study concludes by providing an outlook of developing a bio-nanofiltration process that can be used as a tertiary treatment for removing NPs and other components present in water. Such a process can produce NPs-free water for non-potable use or safe discharge into open waterways.