Development of highly permselective Mixed Matrix Membranes comprising of polyimide and Ln-MOF for CO2 capture.

Mixed Matrix Membranes (MMMs) with hybrid organic-inorganic characteristics offer a strong alternative to traditional polymer-based membranes to reduce the trade-off between gas permeability and selectivity. This work incorporated lanthanum-Metal Organic Frameworks in the Matrimid to fabricate MMMs. To understand the effects of nano-filler on membranes' morphology, porosity, thermal stability, and chemical composition, MMMs were fabricated with three different loadings of nano-filler, i.e., 10, 20 and 30 wt%. The selectivity and permeability of CH4, CO2, and N2 gases through MMMs were investigated at 10 bar pressure and temperatures ranging from 25 to 55 °C. All MMMs exhibited enhanced CO2 permeation with increased nano-filler loading because the porous nano-filler provided additional channels and fractional free volume in the polymer matrix. The 30 wt% loaded membrane showed a 183% increase in permeability of CO2 than neat membrane. With increasing nano-filler loading, the selectivity of MMMs increased from 34.1 to 48.45 for CO2/N2 and from 36.2 to 54.67 for CO2/CH4, confirming the absence of membrane defects, improved filler/polymer interface, and excellent dispersion of nano-filler in the polymer matrix. The results proved that these membranes could be further used for gas separation industrial applications.

Polymeric membranes for environmental remediation: A product space model perspective.

The development of polymeric membranes from polymers such as polystyrene (PS), polyvinylchloride (PVC), and their associated family has brought great momentum to the environmental remediation universe, mainly due to their surprisingly diverse and multi-purpose nature. Their usage has surged 20 times in the last half-century and is likely to double again in the coming 20 years. As a result, the polymeric materials economy and commercialization of research become increasingly important as a possible option for a country to boost prosperity while decreasing its reliance on limited raw resources and mitigating negative externalities. This transformation demands a systematic strategy, which involves progress beyond improving the existing models and building new avenues for collaboration. In this work, a sophisticated system, i.e., product space model (PSM), has been presented, explicitly appraising the opportunity space for United Kingdom, Italy, Poland, India, Canada, Indonesia, Brazil, Saudi Arabia, Russia and Colombia for their potential future industrialization and commercialization of polymeric membranes for environmental remediation. The results revealed that UK, Italy, Poland and India are at advantageous positions owing to their close proximity of (distance<2) and their placement in Parsimonious policy, which is the most desired quadrant of Policy Map of PSM, Canada and Indonesia have medium level opportunities, while Russia and Saudi Arabia have opportunities with more challenges to fully exploit the unexploited polymers products in terms of membranes for environmental remediation and prove favorable for export diversification, sustainable economic growth, and commercialization.