Confining barriers for surface state electrons tailored by monatomic Fe rows on vicinal Au111 surfaces.

We fabricated monatomic Fe wires on vicinal Au(111) surfaces and found that decoration of step edges with Fe adatoms has a significant influence on the behavior of surface state electrons confined between regularly arranged steps. On a surface with Fe monatomic rows, angle-resolved photoemission spectra measured in the direction perpendicular to the steps shows parabolic dispersion, in contrast to one-dimensional quantum-well levels observed on a clean surface. Simple analysis using a one-dimensional Kronig-Penney model reveals potential barrier reduction from 20 to 4.6 eV A, suggesting an attractive nature of the Fe adatoms as scatterers.