RESUMO
This paper focuses on exploring the potential solution and opportunity in the development of the Malaysian Army Transformation Plan by using the concept of Cognitive Readiness (CR). Here, the concept of CR equipped the military personnel to be cognitively ready to perform their role in military operations. The main aim of the paper is to highlight the fundamental discourse of 'what is cognitive readiness' in discovering the potential solution and opportunity in the development of the Malaysian Army Transformation Plan. The paper suggests that the strategy for transformation may start at the tactical level by focusing on enhancing the military personnel's CR. The study proposed that the Malaysian Army Organization prepare the military personnel with Knowledge, Skills and Abilities (KSA). KSA are important to boost the military personnel to have a distinctive character such as thinking critically, problem-solving and decision-making to perform effectively during military operations. In this preliminary study, the paper proposed a Framework for Tactical Cognitive Readiness (TCR) as a potential solution and opportunity for the Malaysian Army.
RESUMO
Bacterial Cellulose (BC) derived from local market or symbiotic culture of bacteria and yeast (SCOBY) was employed as the polymer matrix for hydroxyl multi-walled carbon nanotube (MWCNT-OH)-based electrochemical double-layer capacitor (EDLC). Chitosan (CS)-sodium iodide (NaI)-glycerol (Gly) electrolyte systems were used as the polymer electrolyte. CS-NaI-Gly electrolyte possesses conductivity, potential stability and ionic transference number of (1.20 ± 0.26) × 10-3 S cm-2, 2.5 V and 0.99, respectively. For the electrodes, MWCNT-OH was observed to be well dispersed in the matrix of BC which was obtained via FESEM analysis. The inclusion of MWCNT-OH reduced the crystallinity of the BC polymeric structure. From EIS measurement, it was verified that the presence of MWCNT-OH decreased the electron transfer resistance of BC-based electrodes. Cyclic voltammetry (CV) showed that the shape of the CV plots changed to a rectangular-like shape plot as more MWCNT were added, thus verifying the capacitive behavior. Various amount of MWCNT-OH was used in the fabrication of the EDLC where it was discovered that more MWCNT-OH leads to a better EDLC performance. The EDLC was tested for 5000 complete charge-discharge cycles. The optimum performance of this low voltage EDLC was obtained with 0.1 g MWCNT where the average specific capacitance was 8.80 F g-1. The maximum power and energy density of the fabricated EDLC were 300 W kg-1 and 1.6 W h kg-1, respectively.
RESUMO
In this work, bacterial cellulose (BC)-based polymer derived from a symbiotic culture of bacteria and yeast (SCOBY) are optimized as both electrodes and electrolytes to fabricate a flexible and free-standing supercapacitor. BC is a multifunction and versatile polymer. Montmorillonite (MMT) and sodium bromide (NaBr) are used to improve mechanical strength and as the ionic source, respectively. From XRD analysis, it is found that the addition of MMT and NaBr has reduced the crystallinity of the electrolyte. Most interaction within the electrolyte happens in the region of the OH band, as verified using FTIR analysis. A maximum room temperature conductivity of (1.09 ± 0.02) × 10-3 S/cm is achieved with 30 wt.% NaBr. The highest conducting SCOBY-based electrolytes have a decompose voltage and ionic transference number of 1.48 V and 0.97, respectively. The multiwalled carbon nanotube is employed as the active material held by the fibrous network of BC. Cyclic voltammetry shows a rectangular shape CV plot with the absence of a redox peak. The supercapacitor is charged and discharged in a zig-zag-shaped Perspex plate for 1000 cycles with a decent performance.