Advancements in Polyethylene Oxide (PEO)-Active Filler Composite Polymer Electrolytes for Lithium-Ion Batteries: A Comprehensive Review and Prospects.

Polyethylene oxide (PEO) has become a highly sought-after polymer electrolyte for lithium-ion batteries (LIBs) due to its high ionic conductivity, strong mechanical properties, and broad electrochemical stability range. However, its usefulness is hindered by its limited ionic conductivity at typical temperatures (<60 °C). Many researchers have delved into the integration of active fillers into the PEO matrix to improve the ionic conductivity and overall efficiency of composite polymer electrolytes (CPEs) for LIBs. This review delves deeply into the latest developments and insights in CPEs for LIBs, focusing on the role of PEO-active filler composites. It explores the impact of different types and morphologies of active fillers on the electrochemical behavior of CPEs. Additionally, it explores the mechanisms that contribute to the improved ionic conductivity and Li-ion transport in PEO-based CPEs. This paper also emphasizes the present obstacles and prospects in the advancement of CPEs containing PEO-active filler composites for LIBs. It serves as a valuable reference for scientists and engineers engaged in the domain of advanced energy storage systems, offering insights for the forthcoming development and enhancement of CPEs to achieve superior performance in LIBs.

The Combined Effects of the Membrane and Flow Channel Development on the Performance and Energy Footprint of Oil/Water Emulsion Filtration.

Membrane filtration is a promising technology for oil/water emulsion filtration due to its excellent removal efficiency of microdroplets of oil in water. However, its performance is highly limited due to the fouling-prone nature of oil droplets on hydrophobic membranes. Membrane filtration typically suffers from a low flux and high pumping energy. This study reports a combined approach to tackling the membrane fouling challenge in oil/water emulsion filtration via a membrane and a flow channel development. Two polysulfone (PSF)-based lab-made membranes, namely PSF- PSF-Nonsolvent induced phase separation (NIPS) and PSF-Vapor-induced phase separation (VIPS), were selected, and the flow channel was modified into a wavy path. They were assessed for the filtration of a synthetic oil/water emulsion. The results showed that the combined membrane and flow channel developments enhanced the clean water permeability with a combined increment of 105%, of which 34% was attributed to the increased effective filtration area due to the wavy flow channel. When evaluated for the filtration of an oil/water emulsion, a 355% permeability increment was achieved from 43 for the PSF-NIPS in the straight flow channel to 198 L m-2 h-1 bar-1 for the PSF-VIPS in the wavy flow channel. This remarkable performance increment was achieved thanks to the antifouling attribute of the developed membrane and enhanced local mixing by the wavy flow channel to limit the membrane fouling. The increase in the filtration performance was translated into up to 78.4% (0.00133 vs. 0.00615 kWh m-3) lower in pumping energy. The overall findings demonstrate a significant improvement by adopting multi-pronged approaches in tackling the challenge of membrane fouling for oil/water emulsion filtration, suggesting the potential of this approach to be applied for other feeds.

Altering substrate properties of thin film nanocomposite membrane by Al2O3 nanoparticles for engineered osmosis process.

The scarcity of energy and water resources is a major challenge for humanity in the twenty-first century. Engineered osmosis (EO) technologies are extensively researched as a means of producing sustainable water and energy. This study focuses on the modification of substrate properties of thin film nanocomposite (TFN) membrane using aluminium oxide (Al2O3) nanoparticles and further evaluates the performance of resultant membranes for EO process. Different Al2O3 loading ranging from zero to 0.10 wt% was incorporated into the substrate and the results showed that the hydrophilicity of substrate was increased with contact angle reduced from 74.81° to 66.17° upon the Al2O3 incorporation. Furthermore, the addition of Al2O3 resulted in the formation of larger porous structure on the bottom part of substrate which reduced water transport resistance. Using the substrate modified by 0.02 wt% Al2O3, we could produce the TFN membrane that exhibited the highest water permeability (1.32 L/m2.h.bar, DI water as a feed solution at 15 bar), decent salt rejection (96.89%), low structural parameter (532.44 µm) and relatively good pressure withstandability (>25 bar).

SVM and ANN Modelling Approach for the Optimization of Membrane Permeability of a Membrane Rotating Biological Contactor for Wastewater Treatment.

Membrane fouling significantly hinders the widespread application of membrane technology. In the current study, a support vector machine (SVM) and artificial neural networks (ANN) modelling approach was adopted to optimize the membrane permeability in a novel membrane rotating biological contactor (MRBC). The MRBC utilizes the disk rotation mechanism to generate a shear rate at the membrane surface to scour off the foulants. The effect of operational parameters (disk rotational speed, hydraulic retention time (HRT), and sludge retention time (SRT)) was studied on the membrane permeability. ANN and SVM are machine learning algorithms that aim to predict the model based on the trained data sets. The implementation and efficacy of machine learning and statistical approaches have been demonstrated through real-time experimental results. Feed-forward ANN with the back-propagation algorithm and SVN regression models for various kernel functions were trained to augment the membrane permeability. An overall comparison of predictive models for the test data sets reveals the model's significance. ANN modelling with 13 hidden layers gives the highest R2 value of >0.99, and the SVM model with the Bayesian optimizer approach results in R2 values higher than 0.99. The MRBC is a promising substitute for traditional suspended growth processes, which aligns with the stipulations of ecological evolution and environmentally friendly treatment.

Controlling Air Bubble Formation Using Hydrophilic Microfiltration Diffuser for C. vulgaris Cultivation.

In this project, a commercial polytetrafluoroethylene (PTFE) membrane was coated with a thin layer of polyether block amide (PEBAX) via vacuum filtration to improve hydrophilicity and to study the bubble formation. Two parameters, namely PEBAX concentration (of 0-1.5 wt%) and air flow rate (of 0.1-50 mL/s), were varied and their effects on the bubble size formation were investigated. The results show that the PEBAX coating reduced the minimum membrane pore size from 0.46 µm without coating (hereafter called PEBAX0) to 0.25 µm for the membrane coated with 1.5wt% of PEBAX (hereafter called PEBAX1.5). The presence of polar functional groups (N-H and C=O) in PEBAX greatly improved the membrane hydrophilicity from 118° for PEBAX0 to 43.66° for PEBAX1.5. At an air flow rate of 43 mL/s, the equivalent bubble diameter size decreased from 2.71 ± 0.14 cm for PEBAX0 to 1.51 ± 0.02 cm for PEBAX1.5. At the same air flow rate, the frequency of bubble formation increased six times while the effective gas-liquid contact area increased from 47.96 cm2/s to 85.6 cm2/s. The improved growth of C. vulgaris from 0.6 g/L to 1.3 g/L for PEBAX1.5 also shows the potential of the PEBAX surface coating porous membrane as an air sparger.

Response Surface Methodology for Optimization of Rotating Biological Contactor Combined with External Membrane Filtration for Wastewater Treatment.

A large amount of wastewater is directly discharged into water bodies without treatment, causing surface water contamination. A rotating biological contactor (RBC) is an attached biological wastewater treatment process that offers a low energy footprint. However, its unstable removal efficiency makes it less popular. This study optimized operating parameters in RBC combined with external membrane filtration (RBC-ME), in which the latter acted as a post-treatment step to stabilize the biological performance. Response surface methodology (RSM) was employed to optimize the biological and filtration performance by exploiting three parameters, namely disk rotation, hydraulic retention time (HRT), and sludge retention time (SRT). Results show that the RBC-ME exhibited superior biological treatment capacity and higher effluent quality compared to stand-alone RBC. It attained 87.9 ± 3.2% of chemical oxygen demand, 45.2 ± 0.7% total nitrogen, 97.9 ± 0.1% turbidity, and 98.9 ± 1.1% ammonia removals. The RSM showed a good agreement between the model and the experimental data. The maximum permeability of 144.6 L/m2 h bar could be achieved under the optimum parameters of 36.1 rpm disk rotation, 18 h HRT, and 14.9 d SRT. This work demonstrated the effective use of statistical modeling to enhance RBC-ME system performance to obtain a sustainable and energy-efficient condition.

Effect of Membrane Materials and Operational Parameters on Performance and Energy Consumption of Oil/Water Emulsion Filtration.

Membrane technology is one of reliable options for treatment of oil/water emulsion. It is highly attractive because of its effectiveness in separating fine oil droplets of <2 µm sizes, which is highly challenging for other processes. However, the progress for its widespread implementations is still highly restricted by membrane fouling. Most of the earlier studies have demonstrated the promise of achieving more sustained filtration via membrane material developments. This study addresses issues beyond membrane development by assessing the impact of membrane material (blend of polysulfone, PSF and polyethylene glycol, PEG), operational pressure, and crude oil concentration on the filtration performance of oil/water emulsion. The filtration data were then used to project the pumping energy for a full-scale system. Results show that fouling resistant membrane offered high oil/water emulsion permeability, which translated into a low energy consumption. The oil/water emulsion permeability was improved by three-fold from 45 ± 0 to 139 ± 1 L/(m2 h bar) for PSF/PEG-0 membrane in comparison to the most optimum one of PSF/PEG-60. It corresponded to an energy saving of up to ~66%. The pumping energy could further be reduced from 27.0 to 7.6 Wh/m3 by operation under ultra-low pressure from 0.2 to 0.05 bar. Sustainable permeability could be achieved when treating 1000 ppm oil/water emulsion, but severe membrane fouling was observed when treating emulsion containing crude oils of >3000 ppm to a point of no flux.

Development of Polyvinylidene Fluoride Membrane via Assembly of Tannic Acid and Polyvinylpyrrolidone for Filtration of Oil/Water Emulsion.

Wastewater containing oil/water emulsion has a serious ecological impact and threatens human health. The impact worsens as its volume increases. Oil/water emulsion needs to be treated before it is discharged or reused again for processing. A membrane-based process is considered attractive in effectively treating oil/water emulsion, but progress has been dampened by the membrane fouling issue. The objective of this study is to develop polyvinylidene fluoride (PVDF) membranes customized for oil/water emulsion separation by incorporating assembly of tannic acid (TA) and polyvinylpyrrolidone (PVP) in the polymer matrix. The results show that the assembly of TA/PVP complexation was achieved as observed from the change in colour during the phase inversion and as also proven from the characterization analyses. Incorporation of the TA/PVP assembly leads to enhanced surface hydrophilicity by lowering the contact angle from 82° to 47°. In situ assembly of the TA/PVP complex also leads to enhanced clean water permeability by a factor of four as a result of enhanced mean flow pore size from 0.2 to 0.9 µm. Owing to enhanced surface chemistry and structural advantages, the optimum hydrophilic PVDF/TA/PVP membrane poses permeability of 540.18 L/(m2 h bar) for oil/water emulsion filtration, three times higher than the pristine PVDF membrane used as the reference.

Performance of Polymer Electrolyte Membrane for Direct Methanol Fuel Cell Application: Perspective on Morphological Structure.

Membrane morphology plays a great role in determining the performance of polymer electrolyte membranes (PEMs), especially for direct methanol fuel cell (DMFC) applications. Membrane morphology can be divided into two types, which are dense and porous structures. Membrane fabrication methods have different configurations, including dense, thin and thick, layered, sandwiched and pore-filling membranes. All these types of membranes possess the same densely packed structural morphology, which limits the transportation of protons, even at a low methanol crossover. This paper summarizes our work on the development of PEMs with various structures and architecture that can affect the membrane's performance, in terms of microstructures and morphologies, for potential applications in DMFCs. An understanding of the transport behavior of protons and methanol within the pores' limits could give some perspective in the delivery of new porous electrolyte membranes for DMFC applications.