Traces of black carbon sources before and after the Covid-19 outbreak in Tehran, Iran.

The concentration of black carbon was measured in four sites of the industrial and high-traffic metropolis of Tehran with different land uses. Then, the contribution of biomass and fossil fuels in the emission of this pollutant was modeled using the Aethalometer model. The possible locations of important sources of black carbon dissemination were projected using PSCF and CWT models, and the results were compared in the two periods before and after the Covid-19 outbreak. Temporal variations of black carbon illustrated that BC concentration decreased in the period after the onset of the pandemic in all studied areas, and this decline was more explicit in the traffic intersection of the city. Diurnal changes of BC concentration indicated the significant impact of the application of the law banning night traffic of motor vehicles in reducing the BC concentration in this period, and probably the reduction of HDDV traffic has played the most important role in this reduction. The results related to the share of BC sources indicated that black carbon emissions are affected by an average of about 80% of fossil fuel combustion and wood combustion interferes with about 20% of BC emissions. Finally, speculations were made about the possible sources of BC emission and its urban scale transport using PSCF and CWT models, which indicated the superiority of the CWT model in terms of source segregation. The results of this analysis were further utilized to surmise black carbon emission sources based on the land use of receptor points.

Characterization of microplastics in the atmosphere of megacity Tehran (Iran).

In this study, the characteristics of ambient airborne microplastics were investigated in Tehran to obtain insights into their origins. For this purpose, sampling operations took place at locations with different backgrounds in summer and autumn by using TSP and PM10 high-volume samplers. As a result of microscopic analysis and Raman spectroscopy, the color, shape, number, size, and type of microplastic particles were investigated. Seven types of chemical structures were identified in the particles, among which polypropylene (18.7%) in summer and polystyrene (20%) in autumn had the dominant share. The average number of particles collected using the TSP and PM10 samplers were 1165 ± 147.64 and 1006.5 ± 147.64, respectively. The size of microplastic particles in different stations varied between 4 and 3094 µm. In the seasonal examination of the identified colors, black (38-43%), red (17-19%), gold (13-14%), brown (12% in both seasons), blue (7-10%), yellow (3-5%), and green (2-5%) had the largest proportions, respectively. The examined microplastics were in three forms: fiber, bead, and fragment, among which the predominant form was fiber, and the most infrequent particles were fragments. Statistical comparisons showed that the sampling location does not have a significant effect on the number and size of particles (p value > 0.05). The season was not identified as a determining parameter for particle size (p value > 0.05). On the other hand, seasonal changes can have a tremendous effect on the microplastic particle number (p value < 0.05). Lastly, to obtain more detailed information about the origin of these particles, continuous and long-term monitoring near known industries and suspected sources of plastic materials and source apportionment studies were suggested.

The effect of airtightness required in building energy conservation regulations on indoor and outdoor originated pollutants.

The contradiction of indoor air quality (IAQ) and energy conservation by isolating the indoor environment from the outdoor through airtightness is one of the challenges of the building sector. The key issue is, what are the optimum airtightness limits that can ensure IAQ in naturally ventilated buildings, taking into account the paradoxical effect of house leakages on the infiltration of outdoor pollutants and accumulation of indoor-generated pollutants? For this purpose, the effect of different levels of airtightness required in energy-compliant, low-energy, and very low-energy buildings on the concentration of two pollutants with outdoor and indoor origin, PM2.5 and formaldehyde, respectively, were studied. This study used a multizone model, CONTAM(W), which was validated using measured data to study the distribution of selected pollutants in a typical relatively old dwelling, to investigate the situation in Iran. Subsequently, we conducted simulations based on different combinations of scenarios for airtightness, user behavior, source strength, and meteorological parameters. The results showed that increasing the airtightness from the baseline scenario (ACH50 = 11.11/h) to 3, 1.5, and 0.75 in closed window conditions reduced the PM2.5 by 15%, 38%, and 58%, respectively, and elevated formaldehyde by 23%, 77%, and 169%, correspondingly. Under normal outdoor PM2.5 pollution, indoor formaldehyde levels exceeded the permissible limit only in closed window conditions, and IAQ remained acceptable in other scenarios. However, there is no indication that IAQ can be ensured by any degree of airtightness under severe outdoor air pollution, demanding specific solutions, such as those proposed in this work.

Particulate matter concentrations and characterization in urban subway system-case study Tehran, Iran.

The present work aims to evaluate the indoor and outdoor air quality in the stations of the Tehran subway system. In this study, the particulate sampling of the four Tehran subway stations was conducted in March-July 2018 during different seasons to determine indoor and outdoor PM10 and PM2.5 concentrations and elemental composition. The samples were analyzed to determine 11 elements such as Pb(Lead), Cd(Cadmium), Ni(Nickel), Co(Cobalt), Mn(Manganese), Zn(Zink), Fe(Iron), Cu(Copper), As(Arsenic), Al(Aluminum) and Cr(Chromium) qualitatively. The experimental results indicated that the average concentrations of both PM10 and PM2.5 in indoor stations (platforms) were approximately 2-5 times higher than those in the outdoors (ambient air). In addition, PM10 and PM2.5 concentrations exceeded the daily-standard values (US-EPA; PM10 = 50 µg.m-3, PM2.5 = 25 µg.m-3) in 100% indoor measurements and 84% outdoor measurements. Moreover, the average indoor PM10 and PM2.5 concentrations in weekday values were 1.4 and 1.5 times higher than those measured on weekends, which may be related to the lower frequency of trains. Further, indoor and outdoor correlation of PM10 concentrations (Pearson r = 0.6) was more than that of PM2.5 concentrations (Pearson r = 0.2), indicating the additional sources for PM2.5 in indoor stations. Additionally, the average PM2.5 / PM10 ratio was 0.52 for indoor measurements and 0.34 for outdoors, indicating that PM10 particles were the dominant particle type in both sampling areas and passengers in indoor stations exposed to higher PM2.5 concentrations than those in outdoor stations. Finally, based on elemental analysis, Fe was the most enriched element in indoor and outdoor PM10 and PM2.5 samples. The concentration of Fe ranged from 16 to 81 µg.m-3 in indoor stations and 0.6 to 2.5 µg.m-3 in outdoors. Other enriched elements were Al, Cu, Zn, and Mn, respectively.

Meteorological dependence, source identification, and carcinogenic risk assessment of PM2.5-bound Polycyclic Aromatic Hydrocarbons (PAHs) in high-traffic roadside, urban background, and remote suburban area.

The Polycyclic Aromatic Hydrocarbons (PAHs) bound to ambient fine Particular Matter (PM2.5) are currently drawing a lot of attention due to their adverse health effects increasing lung cancer risk in humans. In this study, The PM2.5 samples were collected by high volume air samplers simultaneously from three different sites (high-traffic roadside, urban background, and remote suburban) in Tehran, Iran during warm and cold seasons (from July 2018 to March 2019), and 16 PAHs were analyzed using Gas Chromatography-Mass Spectrometry (GC-MS). Unlike previous studies, a remote suburban area was chosen so as to observe the spatial differentiation in PM2.5-bound PAH characteristics. In high-traffic roadside site, the average concentration of total PM2.5-bound PAHs (Æ©PAHs) was 3.7 times the concentration value in remote suburban area. Average (Æ©PAHs) ranged from 5.54 ng/m3 for remote suburban area to 20.67 ng/m3 for high-traffic roadside site. In all sites, seasonal trends of PAH concentrations elucidated high concentrations in the cold season and low concentrations in the warm season. Correlation analysis between Æ©PAHs and atmospheric factors (meteorology parameters and criteria air pollutants) indicated the heterogeneous processes play an important role in the level of PAHs. The results of diagnostic ratio (DR) analysis disclosed that the dominant source of PM2.5-bound PAHs was the combustion of liquid fossil fuels. Despite the fact that incremental lifetime cancer risk (ILCR) via inhaling PM2.5-bound PAHs varied significantly in high-traffic roadside site and remote suburban site, its value was beyond the acceptable risk level in both sites. Our results suggested that effective regulations are needed to monitor PAHs concentrations and reduce PAHs emissions from liquid fossil fuel combustion so as to mitigate the potential carcinogenic risk of PAHs in ambient air. Supplementary Information: The online version contains supplementary material available at 10.1007/s40201-022-00821-2.

Wet deposition of hydrocarbons in the city of Tehran-Iran.

Air pollution in the city of Tehran has been a major problem for the past three decades. The direct effects of hydrocarbon contaminants in the air are particularly important such as their carcinogenic, mutagenic, and teratogenic effects which can be transported to other environments via dry and wet deposition. In the present study, rainwater samples were collected and analyzed for 16 polycyclic aromatic hydrocarbons (PAHs), benzene, toluene, ethyl benzene, and xylene (BTEX) as well as fuel fingerprints in two ranges of gasoline (C5-C11) and diesel fuel (C12-C20) using a gas chromatograph equipped with a flame ionization detector (GC/FID). Mean concentrations of summation operator16 PAHs varied between 372 and 527 microg/L and for BTEX was between 87 and 188 microg/L with maximum of 36 microg/L for toluene. Both gasoline range hydrocarbons (GRH) and diesel range hydrocarbons (DRH) were also present in the collected rainwater at concentrations of 190 and 950 microg/L, respectively. Hydrocarbon transports from air to soil were determined in this wet deposition. Average hydrocarbon transportation for summation operatorPAHs, BTEX, GRH, and DRH was 2,747, 627, 1,152, and 5,733 microg/m(2), respectively.