RESUMO
Grain boundary (GB) oxidation of proton-irradiated 304 nuclear grade stainless steel in primary water of pressurized water reactor was investigated. The investigation was conducted by studying microstructure of the oxide and oxide precursor formed at GB on an "atom-by-atom" basis by a combination of atom-probe tomography and transmission electron microscope. The results revealed that increasing irradiation dose promoted the GB oxidation, in correspondence with a different oxide and oxide precursor formed at the GB. Correlation of the oxide and oxide precursor with the GB oxidation behavior has been discussed in detail.
RESUMO
308L welding duplex stainless steel has been irradiated at 360 °C with 2 MeV protons, corresponding to a dose of 3 dpa at the maximum depth of 20 µm. Microhardness of the δ-ferrite and austenite phases was studied before and after proton irradiation using in situ nanomechanical test system (ISNTS). The locations of the phases for indentations placement were obtained by scanning probe microscopy from the ISNTS. The hardness of the δ-ferrite had a close relationship with the vacancy distribution obtained from the Stopping and Range of Ions in Matter (SRIM) Monte Carlo simulation code. However, the hardness of the austenite phase in the maximum damage region (17â»20 µm depth) from the SRIM simulation was decreasing sharply, and a hardness transition region (>20 µm and <55 µm depth) was found between the maximum damage region (17â»20 µm depth) and the unirradiated region (>20 µm depth). However, the δ-ferrite hardness behavior was different. A hardness of the two phases increased on the irradiated surface and the interior due to different hardening mechanisms in the austenite and δ-ferrite phases after a long time high-temperature irradiation. A transition region (>20 µm and <55 µm depth) of the Volta potential was also found, which was caused by the deeper transfer of implanted protons measured by scanning Kelvin probe force microscopy.