Comparative study of polyphenol extraction using physical techniques and water as a solvent: a sustainable approach for the valorization of apple pomace.

Apples are among the most commonly cultivated fruits globally. Approximately 65% of annual apple production is transformed into apple juice concentrate generating a large amount of waste material named apple pomace, which includes seeds, skin, and other components. Disposing of apple by-products directly into the environment constitutes a source of environmental pollution due to its high-water content and easily fermentable nature. Apple pomace is rich in polyphenols that can be utilized as active components in cosmetic, nutraceutical, or pharmaceutical products. The present study aims to describe and compare different physical methods for the extraction of polyphenols from apple pomace. Water was used as the extraction solvent in thermal-stirred extraction (TSE), ultrasound-assisted extraction (UAE), and microwave-assisted extraction (MAE). The best extraction conditions were identified in terms of solid to solvent ratio, temperature, power, and time through a kinetic study. The best extraction parameters were compared environmentally on a pilot scale through a life cycle assessment (LCA). All the results demonstrated the MAE is the best technique to extract polyphenol from apple pomace in terms yield and environmental impact proving that it is possible to transform waste into a sustainable source of bioactive ingredients.

Modeling landslide activity and sediment connectivity after eruptions: Insights from the Blanco River (Chile).

Volcanic eruptions can disrupt entire river basins by affecting the hydro-geomorphic characteristics of channel networks and hillslopes. Reports suggest a pulsed and delayed increase in landslide activity following the eruptions, which, depending on the degree of linkage between hillslopes and channels, i.e. sediment connectivity, can represent a massive source of sediment input for the fluvial system. Therefore, predicting landslide occurrence and sediment connectivity is fundamental for management risk strategies, especially in such dynamic and complex environments. The aim of this work is to develop and offer a more reliable approach to map the areas susceptible to landslides and connected to the active channel in a catchment impacted by volcanic eruption. The analyses were carried out in the Blanco River catchment in southern Chile, affected by the Chaitén eruption (2008-09). A combined approach is presented, based on landslide susceptibility models, carried out multi-temporally (from 2010 to 2019), and a threshold-based sediment connectivity map. The results showed that the highest landslide occurrence was reported 4 years after the eruption, whereas the faster increase in the overall area affected was observed only after 7 years. Landslide susceptibility models showed high accuracy when applied in the same year, but were less accurate in predicting future occurrences. This result is ascribed to the dynamic conditions of the vegetation, regenerating quickly after the mass movements. Nevertheless, considering the potential sources of error, the combined landslide susceptibility-connectivity map for the year 2019 well-identified relevant areas for catchment management. The largest part of the catchment was found non-susceptible and disconnected, while areas classified as susceptible and connected represent only 3.1 %. The application of this novel approach allowed to unravel the geomorphic trajectory of the study area and, more importantly, can represent a benchmark for future applications in other catchments affected by large disturbances.

Phyllotaxis transition over the lifespan of a palm tree using Magnetic Resonance Imaging (MRI) and Terrestrial Laser Scanning (TLS): the case of Jubaea chilensis.

BACKGROUND: Jubaea chilensis (Molina) Baillon, is a uniquely large palm species endemic to Chile. It is under threatened status despite its use as an ornamental species throughout the world. This research seeks to identify the phyllotaxis of the species based on an original combination of non-destructive data acquisition technologies, namely Magnetic Resonance Imaging (MRI) in saplings and young individuals and Terrestrial Laser Scanning (TLS) in standing specimens, and a novel analysis methodology. RESULTS: Two phyllotaxis parameters, parastichy pairs and divergence angle, were determined by analyzing specimens at different developmental stages. Spiral phyllotaxis patterns of J. chilensis progressed in complexity from parastichy pairs (3,2) and (3,5) in juvenile specimens and (5,3), (8,5) and (8,13) for adult specimens. Divergence angle was invariable and averaged 136.9°, close to the golden angle. Phyllotactic pattern changes associated with establishment phase, the adult vegetative and the adult reproductive phases were observed. Both technologies, MRI and TLS proved to be adequate for the proposed analysis. CONCLUSIONS: Understanding phyllotactic transitions may assist identification of developmental stages of wild J. chilensis specimens. The proposed methodology may also be useful for the study of other palm species.

The morphological response of the Tegnas alpine catchment (Northeast Italy) to a Large Infrequent Disturbance.

A recent storm (27th-30th October 2018), named Vaia, hit most part of the Northeast of Italy affecting the geomorphic aspect of almost all mountain catchments of the area. The event triggered new instabilities such as windthrows, landslides and debris flows. At present, few studies dealt with the analysis of the impact of a Large Infrequent Disturbance at large catchment scale. This work provides a focus on the Tegnas Torrent Basin (Belluno Province) and aims at detecting how, where, and how much this storm affected the basin. Moreover, it integrates two different approaches considering both the dynamic and static aspects of the sediment, via DEM of Difference (DoD) and Index of Connectivity (IC), respectively. The Tegnas sub-basins responded contrastingly: the Bordina (volcanic origin and covered by pastures and spruce forests) was mainly affected by windthrows (7% of the sub-basin area) and landslides (0.5%), while the Angheraz (outcropping dolomite rocks), was stricken only by debris flows (1.0%). Morphological changes were clear along the entire channel network, with predominant erosion in the steepest upstream parts (over 2 m of the channel elevation), and deposition in the lower main valley floor (over 3 m of the channel elevation). The IC analysis along the instabilities highlighted that the windthrows occurred mainly in areas of high connectivity, which may be important for future management strategies. Moreover, the proposed integrated approach, based on the combination IC-DoD, permitted a detailed identification of sediment routing and a contemporary estimation of erosion and deposition volumes generated by a high magnitude low-frequency event. Based on these results, cascading processes are expected and further analysis are required to fully consider the impact of a Large Infrequent Disturbance.

Assessing the effect of fire severity on sediment connectivity in central Chile.

Chilean territory is recurrently affected by severe wildfires, which drastically reduce the forest cover and promote runoff, soil erosion and slope instabilities. To understand how the geomorphic system responds to wildfires in terms of sediment dynamics, the assessment of sediment connectivity, i.e. the property describing the relationships between compartments of a geomorphic system, is crucial. This study aims to quantify the spatial linkages between fire severity and sediment connectivity to identify common patterns and driving factors. The compound use of field data and open-source satellite imagery helped to apply the Relative differenced Normalized Burn Ratio (RdNBR) and the Index of Connectivity (IC) in the context of two consecutive wildfires, occurred in 2002 and 2015, in the Rio Toro catchment (Chile). The fire severity assessment showed that the 2002 event affected 90% of the catchment, with high severity areas representing around 70%. The 2015 wildfire instead, affected 76% of the catchment with moderate severity around 42%. Accordingly, as result of the sudden reduction in forest cover in severely affected areas, the IC changed after both wildfires with an overall increase of 1.07 and 0.54, respectively. However, only for the second disturbance, it was possible to observe a clear relationship between the RdNBR and the IC variations. The different degree of vegetation cover heterogeneity between the two pre-wildfire scenarios contributed to different fire severity and IC variability between the two disturbances. The use of open-source satellite data and the development of a weighting factor (W), to be used in IC and able to capture the land cover change driven by the wildfires, could make the application of this approach straightforward, promoting its reproducibility in other catchments for land management and risk mitigation purposes.

Sediment connectivity changes in an Andean catchment affected by volcanic eruption.

River systems are continuously affected by multiple natural and anthropogenic phenomena. Among major natural disturbances, volcanic eruptions have the capability to overthrow the forms and to modify dramatically the morphological setting and sediment connectivity of the system. Moreover, the input of sediments in the channel network can lead to active channel widening, bed aggradation and river scouring, which in turn may affect downstream human settlements. In this context, the present research aims to investigate sediment connectivity by means of a geomorphometric index in a catchment affected by an explosive volcanic eruption in order to assess its variation before and after the disturbance. We developed a workflow exploiting the use of open source data (i.e., Global Digital Elevation Models, satellite imagery) to represent the impedance to the sediment fluxes and to apply the Index of Connectivity (IC) in this context characterized by the lack of high-resolution topographic data. The study area is the Blanco River basin, southern Chile, which was heavily affected by the eruption of Chaitén volcano (2008-2009) that caused the partial destruction of the forest and the profound alteration of Blanco River's morphology. The application of the IC on different land cover scenarios, derived by combining field observations and satellite image classification techniques, showed an increase in sediment connectivity after the volcanic eruption. In addition, the results highlighted different patterns of connectivity according to the expansion of the active channel induced by the massive input of pyroclastic material. The approach proposed in this study case offers a methodology to investigate sediment connectivity in a river catchment affected by natural disturbance where high-resolution data are not available. The results of the study help to improve knowledge on the effect of volcanic eruptions in the hydrologic catchment and to improve watershed management strategies in such kind of environment.