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1.
Chemosphere ; 314: 137602, 2023 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-36563719

RESUMO

Present study has been focused on the bio-energy potential of waste biomass (water hyacinth leaves and its stem). Pyrolysis of both biomasses were investigated at five different heating rates (5-25 °C/min) using thermogravimetric analyzer. For both biomasses, maximum thermal degradation occurred within the temperature range of 200-400 °C, which is the active pyrolytic zone. Three non-iso-conversional (degradation models) including the Kissinger-Akahira-Sunose, Flynn-Wall-Ozawa, and Starink were used to calculate the activation energy of both biomasses. The activation energy was around 92-98 kJ/mol for water hyacinth leaves and 151-153 kJ/mol for water hyacinth stems. The results suggest that these low-cost abundantly available biomasses have a good potential for the production of solid bio-fuel.


Assuntos
Eichhornia , Poluentes Ambientais , Pirólise , Termogravimetria , Cinética , Biomassa
2.
Bioresour Technol ; 345: 126441, 2022 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-34852282

RESUMO

The present study explores thermo-chemical potential of two biomasses namely; Phoenix dactylifera seed (PDS) and Aegle marmelos L core (AMP). These biomasses contain high amount of cellulose and exhibit heating value of 3-18 MJ/kg. The thermal kinetic of both the biomasses have been extensively studied using thermogravimetric analysis (TGA) at four different heating rates 5, 10, 15, and 20 °C/min. Kinetic analysis was carried out using three model-free techniques including Flynn-Wall-Ozawa (FWO), Kissinger-Akahira-Sunose (KAS) and Starink. The average activation energy has been found to be 173.75, 172.94 and 170.71 kJ/mol, for PDS whereas 170.26, 167.24 and 164.80 kJ/mol, for AMP analyzed through KAS, FWO and Starink methods, respectively. Further, among all these models, the Starink model exhibits better result for the biofuels potential point of view.


Assuntos
Aegle , Phoeniceae , Biomassa , Frutas , Cinética , Resíduos Sólidos , Termogravimetria
3.
Bioresour Technol ; 358: 127391, 2022 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-35636675

RESUMO

Present study of the biofuel potential of rice straw (RS) waste biomass materials. The average activation energy of rice straw was determined from KAS, FWO and Starink are 84.11, 89.62 and 84.52 kJ/mol, respectively. The characterized rice straw biomass has been tested for biogas potential under co-digestion mode of rice straw and cow dung in ratio 1/2. The maximum 339 ml/g Vs of biogas has been recorded in 35 days with CH4 concentration of 58.3%. The rest being CO2 as well as H2S has been found in trace amounts with observed 85% total solids and 74% volatile solids, present in rice straw.


Assuntos
Biocombustíveis , Oryza , Anaerobiose , Biocombustíveis/análise , Biomassa , Digestão , Cinética , Metano
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