Light-Triggered Reversible Tuning of Second-Harmonic Generation in a Photoactive Plasmonic Molecular Nanocavity.

The ultrasmall mode volume and ultralarge local field enhancement of compact plasmonic nanocavities have been widely explored to amplify a variety of optical phenomena at the nanoscale. Other than passively generating near-field enhancements, dynamic tuning of their intensity and associated nonlinear optical processes such as second-harmonic generation (SHG) play vital roles in the field of active nanophotonics. Here we apply a host-guest molecular complex to construct a photoswitchable molecule-sandwiched metallic particle-on-film nanocavity (MPoFN) and demonstrate both light-controlled linear and nonlinear optical tuning. Under alternating illumination of ultraviolet (UV) and visible light, the photoactive plasmonic molecular nanocavity shows reversible switching of both surface-enhanced Raman scattering (SERS) and plasmon resonance. Surprisingly, we observe more significant modulation of SHG from this photoactive MPoFN, which can be explained qualitatively by the quantum conductivity theory (QCT). Our study could pave the way for developing miniaturized integrated optical circuits for ultrafast all-optical information processing and communication.

Tunable near-perfect nonreciprocal radiation with a Weyl semimetal and graphene.

A tunable near-perfect nonreciprocal thermal emitter, consisting of a dielectric plane and a monolayer graphene sandwiched between a subwavelength grating and a Weyl semimetal plane, is proposed and investigated. Near-complete nonreciprocal radiation can be achieved at resonance, breaking the traditional Kirchhoff's law. The underlying physical mechanism, resulting from a guided mode resonance, is disclosed by illustrating the magnetic field distribution. Moreover, the strong nonreciprocity remains well within a wide range of geometrical parameters. What's more, the performance of the near-perfect spectral nonreciprocity can be flexibly controlled in a wide spectral range through varying the Fermi level of graphene and the axial vector of the Weyl semimetal, which reduces the cost and should be interesting for real application. The conclusions of this paper should prompt the further development of tunable nonreciprocal thermal emitters.

A multi-band nonreciprocal thermal emitter involving a Weyl semimetal with a Thue-Morse multilayer.

The giant enhancement of multi-band nonreciprocal radiation based on the Weyl semimetal-dielectric spacer-Thue-Morse multilayer-metallic mirror structure, is investigated. As an illustration, a novel dual-band nonreciprocal thermal emitter based on the proposed scheme is designed and studied. The results show that two pairs of nonoverlapping absorptivity and emissivity spectra could be realized, which results in the realization of strong dual-band nonreciprocal radiation. The physical origin behind this phenomenon is revealed by the amplitude distribution of the magnetic field and confirmed by impedance matching theory. The dependence of the nonreciprocal radiation properties on the incident angle and the structure dimensions is investigated, and it is shown that the nonreciprocal performance remains stable in a large range of dimensions, which lowers the costs of fabrication. In addition, a multi-band nonreciprocal thermal emitter with a band number larger than two can be easily achieved by increasing the generation of the Thue-Morse multilayer. It is believed that the proposed scheme will promote the development of novel multi-band nonreciprocal thermal emitters.

Strong dual-channel nonreciprocal radiation with guided mode resonances.

A dual-channel thermal emitter, which is composed of an InAs layer atop an aluminum grating backed with a continuous aluminum film, is proposed and studied. Two resonant absorption and emission peaks are achieved at different wavelengths, leading to the achievement of dual-channel strong nonreciprocal radiations at two different wavelengths for an applied magnetic field of 2 T when the angle of incidence is 17°. The physical origin is revealed through illustrating the electromagnetic field distributions at both resonances and also verified through impedance matching. In addition, the perfect nonreciprocity remains stable within a wide range of structure parameters, lowering the cost of manufacture. Moreover, the nonreciprocal radiations for different incident angles and different magnetic fields are also investigated in detail. The concept and conclusions proposed here will be interesting for the development of novel energy conversion and capture devices.

Strong coupling of excitons in patterned few-layer WS2 with guided mode and bound state in the continuum.

The strong coupling of excitons in few-layer transition-metal dichalcogenide (TMDC) with guided mode resonance (GMR) and bound state in the continuum (BIC) is investigated. It is shown that the strong coupling between excitons and GMR or BIC can enable a large Rabi splitting, where up to 155 meV or 162 meV Rabi splitting could be realized through changing the grating period, respectively. The physical origins behind this behavior are revealed by studying the electric field distributions at resonance. In addition, such behaviors are further theoretically verified according to the coupled-oscillator model. Moreover, the effect of the geometric dimensions on the strong coupling is also studied, which can be employed to guide real fabrication. The results will provide a new route for realization of few-layer TMDC-based light-matter interactions and may pave the way toward novel, compact, few-layer TMDC-based polaritonic devices.

Near-infrared absorption-induced switching effect via guided mode resonances in a graphene-based metamaterial.

Optical switches based on dielectric nanostructures are highly desired at present. To enhance the wavelength-selective light absorption, and achieve an absorption-induced switching effect, here we propose a graphene-based metamaterial absorber that consists of a dielectric grating, a graphene monolayer, and a photonic crystal. Numerical results reveal that the dual-band absorption with an ultranarrow spectrum of the system is enhanced greatly due to the critical coupling, which is enabled by the combined effects of guided mode resonances and photonic band gap. The quality factor of the absorber can achieve a high value (>500), which is basically consistent with the coupled mode theory. Slow light emerges within the absorption window. In addition, electrostatic gating of graphene in the proposed structure provides dynamic control of the absorption due to the change of the chemical potential of the graphene, resulting in an optional multichannel switching effect. Unlike other one-dimensional devices, these effects can be applied to another polarization without changing the structure parameters, and the quality factor is significantly enhanced (>1000). The tunable light absorption offered by the simple structure with an all-dielectric configuration will provide potential applications for graphene-based optoelectronic devices in the near-infrared range, such as narrowband selective filters, detectors, optical switches, modulators, slow optical devices, etc.

Flexible control of light trapping and localization in a hybrid Tamm plasmonic system.

A hybrid Tamm plasmonic system is proposed to investigate light manipulation at near-infrared frequency. The numerical results reveal that two remarkable absorption peaks are generated due to the different types of resonant modes excited in the structure, which can be well explained theoretically by guided-mode resonance (GMR) and Tamm plasmon polaritons. It is found that the electromagnetic energy can be easily trapped in different parts of the structure. More importantly, strong interaction between the two modes can be achieved by adjusting the structure period or incident angle, resulting in obvious mode hybridization and exhibiting unique energy-transfer characteristics. In addition, the active modulation of GMR-based absorption can be controlled in a continuous type by tuning the polarization angle or in a jump type by adjusting the chemical potential of graphene. This work should be useful for developing many high-performance optoelectronic devices, including sensors, modulators, detectors, etc.

Angle-insensitive dual-functional resonators combining cavity mode resonance and magnetic resonance.

An angle-insensitive dual-functional resonator composed of a compound metallic grating is proposed and characterized numerically. The resonator exhibits different response characteristics for TE and TM polarization, thus enabling two functions, corresponding to a high-sensitivity sensor and a low Q-factor absorber. For TE polarization, the Q-factor, refractive index sensitivity, and figure of merit of the resonator can reach 283.4, 2577.6 nm/RIU, and 181.5 RIU-1, respectively, due to the excitation of cavity mode resonance. For TM polarization, the resonator can be regarded as an absorber with high absorptivity (>97%) based on magnetic resonance. Accordingly, these two mechanisms can be explained well by the waveguide theory and inductor-capacitor circuit model. The electromagnetic fields in the system can be selectively concentrated in the cavity or slit by simply adjusting the polarization angle, exhibiting unique energy localization characteristics. The resonator can also exhibit polarization-sensitive behavior due to the different bandwidths for the same wavelength. This simple structure provides a good paradigm for designing high-performance multi-functional devices.

Tailoring anisotropic perfect absorption in monolayer black phosphorus by critical coupling at terahertz frequencies.

A metamaterial perfect absorber composed of a black phosphorus (BP) monolayer, a photonic crystal, and a metallic mirror is designed and investigated to enhance light absorption at terahertz frequencies. Numerical results reveal that the absorption is enhanced greatly with narrow spectra due to critical coupling, which is enabled by guided resonances. Intriguingly, the structure manifests the unusual polarization-dependent feature attributable to the anisotropy of black phosphorus. The quality factor of the absorber can be as high as 95.1 for one polarization while 63.5 for another polarization, which is consistent with the coupled wave theory. The absorption is tunable by varying key parameters, such as period, radius, slab thickness, incident angle, and polarization angle. Furthermore, the state of the system (i.e., critical coupling, over coupling, and under coupling) can be tuned by changing the electron doping of BP, thus achieving various applications. This work offers a paradigm to enhance the light-matter interaction in monolayer BP without plasmonic response, and this easy-to-fabricate structure will provide potential applications in BP-based devices.

Strong coupling between magnetic plasmons and surface plasmons in a black phosphorus-spacer-metallic grating hybrid system.

We propose a black phosphorus-spacer-metallic grating hybrid system to investigate the strong coupling between black phosphorus surface plasmons (BPSP) and magnetic plasmons (MP) at far-infrared frequencies. We theoretically and numerically illustrate interactions between the BPSP mode and MP mode in the coupling regime, which leads to a prominent Rabi splitting and the formation of multiple hybrid modes. Since the mechanisms of the two resonance modes are completely different, the fields in the system can be selectively localized in the spacer layer or metallic slits by regulating the coupling between such modes. Due to the strong anisotropic in-plane properties of black phosphorus (BP), the coupling between BPSP and MP modes in both armchair and zigzag directions is quite different. This work offers a new paradigm to enhance the light-matter interaction through the coupling of multiple resonance modes, and the proposed device will provide potential applications in constructing easy-to-fabricate BP-based plasmonic devices.