Photonic crystal enhanced silicon cell based thermophotovoltaic systems.

We report the design, optimization, and experimental results of large area commercial silicon solar cell based thermophotovoltaic (TPV) energy conversion systems. Using global non-linear optimization tools, we demonstrate theoretically a maximum radiative heat-to-electricity efficiency of 6.4% and a corresponding output electrical power density of 0.39 W cm(-2) at temperature T = 1660 K when implementing both the optimized two-dimensional (2D) tantalum photonic crystal (PhC) selective emitter, and the optimized 1D tantalum pentoxide - silicon dioxide PhC cold-side selective filter. In addition, we have developed an experimental large area TPV test setup that enables accurate measurement of radiative heat-to-electricity efficiency for any emitter-filter-TPV cell combination of interest. In fact, the experimental results match extremely well with predictions of our numerical models. Our experimental setup achieved a maximum output electrical power density of 0.10W cm(-2) and radiative heat-to-electricity efficiency of 1.18% at T = 1380 K using commercial wafer size back-contacted silicon solar cells.

Superlattice photonic crystal as broadband solar absorber for high temperature operation.

A high performance solar absorber using a 2D tantalum superlattice photonic crystal (PhC) is proposed and its design is optimized for high-temperature energy conversion. In contrast to the simple lattice PhC, which is limited by diffraction in the short wavelength range, the superlattice PhC achieves solar absorption over broadband spectral range due to the contribution from two superposed lattices with different cavity radii. The superlattice PhC geometry is tailored to achieve maximum thermal transfer efficiency for a low concentration system of 250 suns at 1500 K reaching 85.0% solar absorptivity. In the high concentration case of 1000 suns, the superlattice PhC absorber achieves a solar absorptivity of 96.2% and a thermal transfer efficiency of 82.9% at 1500 K, amounting to an improvement of 10% and 5%, respectively, versus the simple square lattice PhC absorber. In addition, the performance of the superlattice PhC absorber is studied in a solar thermophotovoltaic system which is optimized to minimize absorber re-emission by reducing the absorber-to-emitter area ratio and using a highly reflective silver aperture.

Global optimization of omnidirectional wavelength selective emitters/absorbers based on dielectric-filled anti-reflection coated two-dimensional metallic photonic crystals.

We report the design of dielectric-filled anti-reflection coated (ARC) two-dimensional (2D) metallic photonic crystals (MPhCs) capable of omnidirectional, polarization insensitive, wavelength selective emission/absorption. Using non-linear global optimization methods, optimized hafnium oxide (HfO2)-filled ARC 2D Tantalum (Ta) PhC designs exhibiting up to 26% improvement in emittance/absorptance at wavelengths λ below a cutoff wavelength λc over the unfilled 2D TaPhCs are demonstrated. The optimized designs possess high hemispherically average emittance/absorptance εH of 0.86 at λ < λc and low εH of 0.12 at λ > λc.

Design of wide-angle selective absorbers/emitters with dielectric filled metallic photonic crystals for energy applications.

The design and simulation of a wide angle, spectrally selective absorber/emitter metallic photonic crystal (MPhC) is presented. By using dielectric filled cavities, the angular, spectrally selective absorption/emission of the MPhC is dramatically enhanced over an air filled design by minimizing diffraction losses. Theoretical analysis is performed and verified via rigorous coupled wave analysis (RCWA) based simulations. An efficiency comparison of the dielectric filled designs for solar thermophotovoltaic applications is performed for the absorber and emitter which yields a 7% and 15.7% efficiency improvement, respectively, compared to air filled designs. The converted power output density is also improved by 33.5%.

Performance analysis of experimentally viable photonic crystal enhanced thermophotovoltaic systems.

One of the keys towards high efficiency thermophotovoltaic (TPV) energy conversion systems lies in spectral control. Here, we present detailed performance predictions of realistic TPV systems incorporating experimentally demonstrated advanced spectral control components. Compared to the blackbody emitter, the optimized two-dimensional (2D) tantalum (Ta) photonic crystal (PhC) selective emitter enables up to 100% improvement in system efficiency. When combined with the well characterized cold side tandem filter and the latest InGaAs TPV cells, a TPV energy conversion system with radiant heat-to-electricity efficiency of 25% and power density of 0.68 W cm(-2) is achievable today even at a relatively low temperature of 1320 K. The efficiency could be increased to ∼ 40% (the theoretical 0.62 eV single bandgap TPV thermodynamic limit at 1320 K is 55%) as future implementation of more optimized TPV cells approach their theoretical thermodynamic limit.

High-temperature stability and selective thermal emission of polycrystalline tantalum photonic crystals.

We present the results of extensive characterization of selective emitters at high temperatures, including thermal emission measurements and thermal stability testing at 1000 °C for 1h and 900 °C for up to 144 h. The selective emitters were fabricated as 2D photonic crystals (PhCs) on polycrystalline tantalum (Ta), targeting large-area applications in solid-state heat-to-electricity conversion. We characterized spectral emission as a function of temperature, observing very good selectivity of the emission as compared to flat Ta, with the emission of the PhC approaching the blackbody limit below the target cut-off wavelength of 2 µm, and a steep cut-off to low emission at longer wavelengths. In addition, we study the use of a thin, conformal layer (20 nm) of HfO(2) deposited by atomic layer deposition (ALD) as a surface protective coating, and confirm experimentally that it acts as a diffusion inhibitor and thermal barrier coating, and prevents the formation of Ta carbide on the surface. Furthermore, we tested the thermal stability of the nanostructured emitters and their optical properties before and after annealing, observing no degradation even after 144 h (6 days) at 900 °C, which demonstrates the suitability of these selective emitters for high-temperature applications.

Enabling ideal selective solar absorption with 2D metallic dielectric photonic crystals.

A metallic dielectric photonic crystal with solar broadband, omni-directional, and tunable selective absorption with high temperature stable (1000 °C, 24 hrs) properties is fabricated on a 6" silicon wafer. The broadband absorption is due to a high density of optical cavity modes overlapped with an anti-reflection coating. Results allow for large-scale, low cost, and efficient solar-thermal energy conversion.