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1.
Eur Phys J E Soft Matter ; 29(1): 51-60, 2009 May.
Artigo em Inglês | MEDLINE | ID: mdl-19412707

RESUMO

We define a creep-flow-based measurement procedure to allow reliable and reproducible results on aging and yielding materials to be obtained. Investigation of the effects of different parameter such as the pre-shear time, the recovery time and the applied stress magnitude on the viscoelastic properties of a lyotropic liquid crystal phase is reported. Cryo-TEM observations indicate the formation of multiconnected bilayers at rest. Shearing the investigated material shows a propensity to acquire all the macroscopic properties of "soft jammed systems". These properties are then interpreted in terms of shear-induced structural rearrangement on the basis of cryofracture observation obtained at different times after the preshear imposed.


Assuntos
Ácido Dioctil Sulfossuccínico/química , Octanos/química , Transição de Fase , Água/química , Reprodutibilidade dos Testes , Fatores de Tempo
2.
J Colloid Interface Sci ; 277(2): 424-36, 2004 Sep 15.
Artigo em Inglês | MEDLINE | ID: mdl-15341855

RESUMO

The impact of a water droplet on a glass surface is studied experimentally using a high-speed video camera which can catch up to 60,000 images per second with an exposure time of 10 micros. A wide range of impact velocities are studied by varying the fall height, showing different spreading regimes. Particular attention is given to the dynamics of the contact angle and its relation to the maximum expanding radius and capillary number. A linear relation between the contact line velocity and the impact velocity is found experimentally. Using acoustic analysis, an evaluation of the pressure at the contact line is given. We also confront predicted and experimental jetting times. This work shows that descriptions of drop impact based purely on conservation of energy are inadequate to describe the dynamics of the event. The different shapes taken by the drops between the initial impact and the maximum radius determine the final outcome.


Assuntos
Vidro/química , Fenômenos Químicos , Físico-Química , Propriedades de Superfície , Água/química , Molhabilidade
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