Effects of Secondary Dopant Anions on Emissivity and Related Properties of Poly(3,4-ethylenedioxythiophene).

Smart materials that are energy efficient and take up less space are crucial in the development of new technologies. Electrochromic polymers (ECPs) are one such class of materials that actively change their optical behavior in both visible and infrared parts of the electromagnetic spectrum. They show promise in a wide range of applications, from active camouflage to smart displays/windows. The full capabilities of ECPs are still yet to be explored, for while their electrochromic properties are well established, their Infrared (IR) modulation is less reported on. This study addresses the potential of ECPs in active IR modulating devices by optimization of Vapor Phase Polymerized poly(3,4-ethylenedioxythiophene) (PEDOT) thin films via the substitution of its dopant anion. Dynamic ranges denoting emissivity changes between reduced and oxidized states of PEDOT are found across dopants of tosylate, bromide, sulfate, chloride, perchlorate, and nitrate. Relative to the emissivity of reduced (neutral) PEDOT, a range of ±15% is achieved from the doped PEDOT films, and a maximum dynamic range of 0.11 across a 34% change is recorded for PEDOT doped with perchlorate.

Recent advances in the aqueous applications of PEDOT.

Water is ubiquitous in life - from making up the majority of the Earth's surface (by area) to over half of the human body (by weight). It stands to reason that materials are likely to contact water at some point during their lifetime. In the specific case of sensors however, there is a need to consider materials that display stable function while immersed in aqueous applications. This mini-review will discuss the most recent advances (2018 to 2021) in the application of the conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) in aqueous environments. At its heart, the use of PEDOT in aqueous applications relies on nanoscale understanding and/or nanoengineered structures and properties. This enables their use in water-based settings such as within the human body or buried in agricultural soils.

Charge transport and structure in semimetallic polymers.

Owing to changes in their chemistry and structure, polymers can be fabricated to demonstrate vastly different electrical conductivities over many orders of magnitude. At the high end of conductivity is the class of conducting polymers, which are ideal candidates for many applications in low-cost electronics. Here, we report the influence of the nature of the doping anion at high doping levels within the semi-metallic conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) on its electronic transport properties. Hall effect measurements on a variety of PEDOT samples show that the choice of doping anion can lead to an order of magnitude enhancement in the charge carrier mobility > 3 cm2/Vs at conductivities approaching 3000 S/cm under ambient conditions. Grazing Incidence Wide Angle X-ray Scattering, Density Functional Theory calculations, and Molecular Dynamics simulations indicate that the chosen doping anion modifies the way PEDOT chains stack together. This link between structure and specific anion doping at high doping levels has ramifications for the fabrication of conducting polymer-based devices. © 2017 The Authors. Journal of Polymer Science Part B: Polymer Physics Published by Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2018, 56, 97-104.

Macroscopic Electrical Wires from Vapor Deposited Poly(3,4-ethylenedioxythiophene).

Conducting polymers represent a field of materials innovation that bridges the properties of metals (electrical conduction) with those of traditional polymers (mechanical flexibility). Although electronic properties have been studied, minimal attention is given to their mechanical properties such as tensile strength. This study presents macroscopic wires made from the vapor phase polymerization of poly(3,4-ethylenedioxythiophene) using triblock copolymers as a molecular template. These macroscopic wires are conductive (up to 5 × 104 S/m), and possess tensile properties (Young's modulus ∼1.1 GPa; tensile strength ∼90 MPa) comparable to commercially available polymers (Nylon-6 and poly(methyl methacrylate)), without need for nonconductive mechanical fillers.

Selective uptake and sensing of nitrate in poly(3,4-ethylenedioxythiophene).

Nitrogen (N) as a nutrient, in the form of nitrate (NO3-), is essential for plant growth. Chemical fertilizers are used to increase crop yields, but overuse can lead to forms of environmental pollution necessitating methods to detect and monitor the level of NO3- in-situ in agricultural soils. Herein we report for the first time the NO3- selectivity of the inherently conducting polymer poly (3,4-ethylenedioxythiophene) (PEDOT). This selectivity occurs when PEDOT thin films are exposed to an aqueous environment containing not only NO3-, but a mixture of other ions present in concentrations (ppm) typical of real agricultural soil. The PEDOT sensitivity to absorb NO3- from solution is determined to be <1 ppm.