Radiation-balanced lasing in Yb3+:YAG and Yb3+:KYW.

Radiation-balanced lasing and thermal profiling is reported in two Yb-doped laser crystals at room temperature. In 3% Yb3+:YAG a record efficiency of 30.5% was achieved by frequency-locking the laser cavity to the input light. Both the average excursion and axial temperature gradient of the gain medium were maintained within 0.1 K of room temperature at the radiation balance point. By including saturation of background impurity absorption in the analysis, quantitative agreement was obtained between theory and the experimentally measured laser threshold, radiation balance condition, output wavelength, and laser efficiency with only one free parameter. Radiation-balanced lasing was also achieved in 2% Yb3+:KYW with an efficiency of 2.2% despite high background impurity absorption, losses from Brewster end faces that were not parallel, and non-optimal output coupling. Our results confirm that relatively impure gain media can be operated as radiation-balanced lasers, contrary to earlier predictions which ignored background impurity properties.

Red Sm:KGd(WO4)2 laser at 649†nm.

We report on the first laser operation of a Sm3+-doped monoclinic KGd(WO4)2 double tungstate crystal in the red spectral range. Pumped by a frequency-doubled optically pumped semiconductor laser (2ω-OPSL) at 479.1 nm, the 0.8 at. % Sm:KGd(WO4)2 laser generated an output power up to 17.6 mW at 649.1 nm (the 4G5/2 → 6H9/2 transition) with a slope efficiency of 16.9%, a laser threshold down to 29 mW and a linear polarization. The laser exhibited a self-pulsing behavior, delivering µs-long pulses with a repetition rate of a few kHz. The polarized spectroscopic properties of Sm3+ ions were determined as well.

8.7-W average power, in-band pumped femtosecond Ho:CALGO laser at 2.1 µm.

We report on an in-band pumped SESAM mode-locked Ho:CALGO bulk laser with a record-high average power of 8.7 W and an optical-to-optical efficiency of 38.2% at a central wavelength of 2.1 µm. At this power level, the bulk laser generates pulses with a duration of 369 fs at an 84.4-MHz repetition rate, corresponding to a pulse energy of 103 nJ and a peak power of 246 kW. To the best of our knowledge, this is the highest average power and pulse energy directly generated from a mode-locked bulk laser in the 2-3 µm wavelength region. Our current results indicate that Ho:CALGO is a competitive candidate for average power scaling of 2-µm femtosecond lasers.

Watt-level europium laser at 703 nm.

We report on a watt-level highly efficient europium laser operating at the ${^5{\rm D}_0 \to {^7}{\rm F}_4}$ transition. It is based on the stoichiometric ${\rm KEu}{({\rm WO}_4)_2}$ crystal. Under pumping by a green laser at 532.1 nm, the ${\rm KEu}{({\rm WO}_4)_2}$ laser generated a maximum peak output power of 1.11 W at ${\sim}{703}\;{\rm nm}$ with a slope efficiency of 43.2% and a linear polarization ($E\|\;{N_m}$). A laser threshold as low as 64 mW was achieved. True continuous-wave operation was demonstrated. The polarized emission properties of monoclinic ${\rm KEu}{({\rm WO}_4)_2}$ were determined.

SESAM mode-locked Yb:YAB thin-disk oscillator delivering an average power of 19 W.

We report on a semiconductor saturable absorber mirror mode-locked thin-disk oscillator based on Yb:YAB delivering pulses with a duration of 462 fs at an average output power of 19.2 W and a pulse energy of 0.38 µJ.

Laser cooling of Yb3+:KYW.

We report the first observation of laser cooling in Yb3+:KYW and validate the results by comparison with experiments in the well-studied material Yb3+:YAG. Radiation from a single-mode Ti:Al2O3 laser was used to achieve cooling of 1.5 K/W in 1% Yb:KYW at 1025 nm, comparing well with the reference material 3% Yb:YAG which cooled by 3.5 K/W at 1030 nm under open lab conditions. Experimental results for KYW crystals mounted on aerogels and doped with 1-20% Yb were in excellent agreement with the theoretical dependence of cooling power on the Yb absorption spectrum. Elimination of thermal conduction through the sample support structure was found to permit the attainment of lower temperatures and to simplify modeling of radiation balance conditions in self-cooled lasers with longitudinal thermal gradients. Contrary to the notion that more coolant ions yield higher cooling power, concentrations of Yb over 1% caused re-absorption of luminescence in KYW crystals, leading to a progressive red shift in the optimal cooling wavelength and the prevention of laser cooling altogether in a 20% sample at room temperature. The prospect of attaining radiation-balanced lasing in commercially-available tungstate crystals is evaluated.

Sellmeier equations, group velocity dispersion, and thermo-optic dispersion formulas for CaLnAlO4 (Ln = Y, Gd) laser host crystals.

We studied the refractive index and dispersive properties of the tetragonal rare-earth calcium aluminates, CaLnAlO4 (Ln=Gd or Y). Sellmeier equations were derived for the spectral range of 0.35-2.1 µm. The group velocity dispersion (GVD) in CaGdAlO4 is positive at ∼1 µm, 95 fs2/mm and negative at ∼2 µm, -40 fs2/mm. The GVD values for CaYAlO4 are similar. In addition, thermo-optic coefficients, dn/dT, and thermal coefficients of the optical path were determined for CaYAlO4. dn/dT is negative at ∼1 µm, dno/dT=-7.8, and dne/dT=-8.7×10-6 K-1. Thermo-optic dispersion formulas were constructed. The obtained data are of key importance to the design of high-power mode-locked oscillators at ∼1 and ∼2 µm based on such laser hosts.

Cellular uptake and biocompatibility of bismuth ferrite harmonic advanced nanoparticles.

Bismuth Ferrite (BFO) nanoparticles (BFO-NP) display interesting optical (nonlinear response) and magnetic properties which make them amenable for bio-oriented diagnostic applications as intra- and extra membrane contrast agents. Due to the relatively recent availability of this material in well dispersed nanometric form, its biocompatibility was not known to date. In this study, we present a thorough assessment of the effects of in vitro exposure of human adenocarcinoma (A549), lung squamous carcinoma (NCI-H520), and acute monocytic leukemia (THP-1) cell lines to uncoated and poly(ethylene glycol)-coated BFO-NP in the form of cytotoxicity, haemolytic response and biocompatibility. Our results support the attractiveness of the functional-BFO towards biomedical applications focused on advanced diagnostic imaging. FROM THE CLINICAL EDITOR: Bismuth Ferrite nanoparticles (BFO-NP) have been recently successfully introduced as photodynamic tools and imaging probes. However, how these nanoparticles interact with various cells at the cellular level remains poorly understood. In this study, the authors performed in vitro experiments to assess the effects of uncoated and PEG-coated BFO-NP in the form of cytotoxicity, haemolytic response and biocompatibility.

Laser action along and near the optic axis of a holmium-doped KY(WO4)2 crystal.

We demonstrate the first (to our knowledge) quasi-three-level conical refraction laser operating at 2 µm, with 1.6 W of output power at 2074 nm, using a holmium-doped KY(WO4)2 crystal. A maximum slope efficiency of 52% has been achieved, along the optic axis with respect to the absorbed pump power. Furthermore, lasing operation around the optic axis has been performed. In this case, a maximum output power of 3 W has been reached, with a slope efficiency better than 70%, which are the best performances ever reported on this material.

Yb:YAl3(BO3)4 as gain material in thin-disk oscillators: demonstration of 109 W of IR output power.

The first demonstration of an Yb:YAl3(BO3)4 thin-disk laser is reported. An output power of 109 W with an optical efficiency of 50.2% was achieved in multimode CW-operation which is to the best of our knowledge a significant record performance compared to previous reports on CW-lasers with this material. At a lower power level of 19.3 W the material proved its suitability for efficient operation with an optical efficiency of 60.4%. In fundamental-mode operation the extracted output power was 10.4 W with an optical efficiency of 44.5% and a beam propagation factor M(2) = 1.39. The broad emission bandwidth of the material was confirmed by measuring a continuous wavelength tuning range from 1001 to 1053 nm with a maximum output power of 36 W at 1040 nm.

Laser demonstration with highly doped Yb:Gd2O3 and Yb:Y2O3 crystals grown by an original flux method.

We present, to the best of our knowledge, the first laser demonstration of an Yb-doped Gd(2)O(3) cubic crystal. This crystal was obtained by the flux method using an original borate-based solvent, which was particularly well suited to the growth of rare earth sesquioxide crystals at half the working temperature of classical growth techniques. This flux method is a very interesting alternative for the production of laser sesquioxide crystals, not only because it provides access to new matrices of the cubic polymorph, but also because it permits high Yb(3+)-doping levels for these crystals. The first laser results of two highly Yb(3+)-doped sesquioxides, namely Gd(2)O(3) and Y(2)O(3), grown by this flux method are presented here, including the Ti:sapphire and diode pumping configurations. Laser efficiencies and emission spectra for these two crystals were studied and compared.

Strontium Aluminate Persistent Luminescent Single Crystals: Linear Scaling of Emission Intensity with Size Is Affected by Reabsorption.

The green-emitting SrAl2O4:Eu,Dy phosphor is the most widely used and well-studied persistent luminescent phosphor available today. Recent efforts to boost its performance in terms of luminescence intensity and duration are challenged by complex loss mechanisms, including the optically stimulated release of previously trapped charges by excitation light. Here, we present minimally scattering SrAl2O4:Eu,Dy single crystals, which, as opposed to powder phosphors, allow to profit from a so-called volume effect, resulting in a significantly increased emission intensity. Additionally, they allow for the identification of the reabsorption of the afterglow emission by trapped charges as an important loss mechanism, leading to a nonlinear scaling of the emission intensity with the crystal size. If circumvented, the emission intensity could be further increased, in persistent luminescent powders, ceramics, and single crystals.

Single-shot holography for depth resolved three dimensional imaging.

We introduce a method for depth-resolved photorefractive holographic imaging with potentially extremely short acquisition time for a complete three dimensional (3D) image. By combining the advantages of full-field frequency-domain optical coherence tomography with those of photorefractive holography our concept is capable of obtaining 3D information with only one single shot. We describe the operation principle of our concept and give a first experimental proof of principle.

Sub-100 fs single-walled carbon nanotube saturable absorber mode-locked Yb-laser operation near 1 microm.

Transmission- and reflection-type single-walled carbon nanotube saturable absorbers (SWCNT-SAs) were designed and fabricated for passive mode-locking of bulk lasers in the 1 microm spectral range. Mode-locked laser operation based on a diffusion-bonded Yb:KYW/KYW crystal was demonstrated, and pulses as short as 83 fs and 140 fs were achieved applying reflection-type and transmission-type SWCNT-SA, respectively. The nonlinear parameters of the absorbers were measured to be in close vicinity to those of a semiconductor saturable absorber mirror for the same wavelength range. Mode-locking performance with SWCNT-SAs and the SESAM was compared utilizing the same cavity, with the SESAM resulting in only slightly shorter pulses of 66 fs duration. The nearly identical performance indicates that well-optimized SWCNT-SAs can substitute SESAMs even in the 1 microm region.

Temperature-Dependent Evolution of Crystallographic and Domain Structures in (K,Na,Li)(Ta,Nb)O3 Piezoelectric Single Crystals.

(K,Na)NbO3-based ferroelectric single crystals have recently undergone a substantial development, resulting in improved crystal quality and large piezoelectric coefficients, exceeding 700 pC/N, over a broad temperature range. However, further development necessitates a detailed understanding of the mechanisms defining the domain structure and its temperature evolution. This paper presents the investigation into the crystallographic structure and domain configurations of a (K,Na,Li)(Ta,Nb)O3 single crystal over a broad temperature range. The crystal was grown by the submerged-seed solution growth technique and investigated using in situ transmission electron microscopy, X-ray diffraction, dielectric measurements, and polarized light microscopy. The lattice distortion, structural phase transitions, and domain configurations are reported. A transition from the lamellar orthorhombic to the rectangular tetragonal domain structure is observed upon heating. Moreover, the milky optical appearance of the crystal was investigated and found to result from the presence of regions with different domain configurations and domain sizes. The formation of these regions is related to the growth defects, which govern the domain formation when cooling below the Curie temperature.

Segmented grown Yb:KY(WO(4))(2)/KY(WO(4))2(2) for use in continuous-wave and mode-locked lasers.

Segmented growth of monoclinic Yb:KY(WO(4))(2) on KY(WO(4))2(2) substrates was successfully implemented and its excellent laser performance demonstrated. High slope efficiencies up to 80% and an output power of 375 mW were achieved under Ti:sapphire laser pumping in the continuous-wave regime. In the passively mode-locked regime, pulses as short as 99 fs with an average output power of 69 mW were obtained.

Self-induced transverse mode selection in a photorefractive extended cavity laser diode.

Previous works on photorefractive self-organizing laser cavities were about lasers that oscillate, prior the self-organization process occurs, on a set of axial modes sharing the same transverse structure. In a well-designed broad-area laser diode extended cavity, we theoretically and experimentally demonstrate that the insertion of a photorefractive crystal can also affect the transverse modal structure to force the laser, initially oscillating on several transverse modes, to oscillate on a single transverse and axial mode. This spatial self-organization process leads to an enhancement of the single mode operating range of the laser.

Deep UV generation and direct DNA photo-interaction by harmonic nanoparticles in labelled samples.

A biophotonics approach based on the nonlinear optical process of second harmonic generation is presented and demonstrated on malignant human cell lines labelled by harmonic nanoparticles. The method enables independent imaging and therapeutic action, selecting each modality by simply tuning the excitation laser wavelength from infrared to visible. In particular, the generation of deep ultraviolet radiation at 270 nm allows direct interaction with nuclear DNA in the absence of photosensitizing molecules.

Harmonic nanocrystals for biolabeling: a survey of optical properties and biocompatibility.

Nonlinear optical nanocrystals have been recently introduced as a promising alternative to fluorescent probes for multiphoton microscopy. We present for the first time a complete survey of the properties of five nanomaterials (KNbO(3), LiNbO(3), BaTiO(3), KTP, and ZnO), describing their preparation and stabilization and providing quantitative estimations of their nonlinear optical response. In the light of their prospective use as biological and clinical markers, we assess their biocompatibility on human healthy and cancerous cell lines. Finally, we demonstrate the great potential for cell imaging of these inherently nonlinear probes in terms of optical contrast, wavelength flexibility, and signal photostability.

Thin-disk Yb:KLu(WO(4))(2) laser with single-pass pumping.

Single-pass pumping of a thin disk consisting of an only 50 microm thick epitaxial layer of 32 at.% Yb-doped KLu(WO(4))(2) grown on a 0.35 mm thick undoped KLu(WO(4))(2) substrate is demonstrated. The thin-disk laser delivered 9 W of continuous wave output power near 1030 nm with a slope efficiency of 77%.