A biogenic hydrogel to recover Au(III) from electronic waste.

In the course of this investigation, we undertook the contemplation of a green chemistry paradigm with the express intent of procuring valuable metal, namely gold, from electronic waste (e-waste). In pursuit of this overarching objective, we conceived a procedural framework consisting of two pivotal stages. As an initial stage, we introduced a physical separation procedure relying on the utilization of the Eddy current separator, prior to embarking on the process of leaching from e-waste. Subsequent to the partitioning of metals from the non-metal constituents of waste printed circuit boards (PCB), we initiated an investigation into the hydrogel derived from basil seeds (Ocimum basilicum L.), utilizing it as a biogenic sorbent medium. The thorough characterization of hydrogel extracted from basil seeds involved the application of an array of analytical techniques, encompassing FTIR, XRD, SEM, and BET. The batch sorption experiments show more than 90% uptake in the pH range of 2-5. The sorption capacity of the hydrogel material was evaluated as 188.44 mg g-1 from the Langmuir Isotherm model. The potential interference stemming from a spectrum of other ions, encompassing Al, Cu, Ni, Zn, Co, Cr, Fe, Mn, and Pb was systematically examined. Notably, the sole instance of interference in the context of adsorption of gold ions was observed to be associated with the presence of lead. The application of the hydrogel demonstrated a commendable efficiency in the recovery of Au(III) from the leached solution derived from the waste PCB.

Intercalation of V2O5 and Polypyrrole into a Graphene Oxide Layer: A Hybrid Multifunctional Photothermal Structure for Efficient Solar Evaporation, Water Purification, Disinfection, and Power Production.

Development of a hybrid multifunctional photothermal structure with multifunctional capabilities is deliberated as an effective approach for harvesting abundant solar energy for sustainable environmental applications. Achieving enhanced solar to thermal conversion efficiency utilizing a suitably designed, environmentally compatible thermal management structure however remains a significant challenge. Herein, we report the intercalation of V2O5 and polypyrrole into a graphene oxide layer to design a hybrid photothermal assembly (PPy-V2O5-GO) and its multifunctional proficiencies. The hybrid photothermal structure demonstrated synergistic photothermal conversion, buoyant porous structure sustaining water transmission, and efficient steam release. V2O5 and polypyrrole-intercalated optimized graphene oxide structure attained an evaporation rate of 1.9 kg m-2 h-1 with a conversion efficiency of 92% under 1 sun solar radiation. At maximum, the assembly's surface temperature hit 64 ± 2 °C, suggesting its suitability as a solar water purifier. Outdoor experiments suggest the evaporator assembly's capability to accumulate a total output of 15 kg m-2 over a single day. Cell viability investigations revealed strong antimicrobial properties of PPy-V2O5-GO against both Gram-negative Escherichia coli and Gram-positive Staphylococcus aureus bacteria, eliminating nearly all under 1 sun, making it a potential candidate for photothermal therapy. Furthermore, when combined with a commercial thermoelectric module, the framework displayed exceptional photothermal conversion efficiency, hinting at its potential for electrical power generation. The integration of PPy-V2O5-GO with a Bi2Te3-based thermoelectric module significantly boosted the thermoelectric generator's performance, offering an enhanced power output of 2.8 mW and a high power density of 1.24 mW/cm2, making them suitable for off-grid or remote-area application. Overall, the PPy-V2O5-GO photothermal assembly's stability, lack of leaching, effectiveness in producing pure water from seawater, antimicrobial efficacies, and recyclability make it an excellent choice for sustainable water treatment and power generation.

Development of magnetic La doped Al2O3 core-shell nanoparticle loaded hydrogel for selective recovery of fluoride from aquatic medium.

The selective removal of pollutants from water bodies is regarded as a conciliation between the rapid expansion of industrial activities and need of clean water for sustainability. Fluoride is one such geogenic pollutant, and various materials have already been reported. Developing an efficient field employable material is however a challenge. Herein, we report the synthesis and competencies of strategically designed magnetic La-doped Al2O3 core-shell nanoparticle loaded polymeric nanohybrid as a benchmark fluoride sorbent. A facile synthesis strategy involved fabrication of Fe3O4 magnetic core followed by growth of La doped Al2O3 shell using sol-gel method. Doping of La2O3 into Al2O3 structure was optimised (6%), resulting in Fe3O4-Al0.94 La0.06O1.5 core-shell particles which provided exceptional fluoride affinity. The obtained magnetic Fe3O4-Al0.94La0.06O1.5 core-shell nanoparticles were then loaded (22%) into alginate to form cross-linked hydrogel beads (Fe3O4-Al0.94 La0.06 O1.5-Ca-ALG). These prepared hydrogel beads were characterised and utilized for selective recovery of fluoride under different ambient conditions. Driving forces for enhanced fluoride uptake by La doped Al2O3 were investigated and explained with the help of both experimental observation and theoretical simulation. Density functional theory calculations indicated significant expansion in the cell volume of Al2O3 due to La doping which favoured the fluoride sorption. The calculated defect formation energy for the incorporation of F into Al2O3 was found to decrease in the presence of La. XPS analysis suggested direct interaction of fluoride with Al, forming Al-F bond and breaking Al-O bond. Different vital parameters for uptake were optimised. Also, kinetics, isotherm and diffusion models were evaluated. Developed hydrogel beads attained record sorption capacity of 132.3 mgg-1 for fluoride. Overall, excellent stability, no leaching of constituents, effectiveness for selective fluoride recovery from groundwater, brand it a perfect epitome of sustainable water treatment application.