Starch consolidation of calcium carbonate as a tool to develop lightweight fillers for LDPE-based plastics.

Calcium carbonate (CaCO3) is used as a filler to improve the stiffness and processability of plastics at low cost. However, its high density limits the quantity to be used. In this work, the feasibility of using starch consolidation of eggshells-derived CaCO3 (ES) to develop lightweight fillers for low density polyethylene (LDPE)-based materials was studied. Starch, recovered from potato by-products, was combined with ES, gelatinized, dried, and milled as a fine powder. The obtained ES/starch-based particles were then compounded with LDPE and their influence on chromatic, mechanical, morphological, and density properties of mold injected LDPE-based materials was studied. Commercially available CaCO3 (COM) was used as control. ES/starch particles were 18 times less dense than the commercially available CaCO3 (2.62 g cm-3). When incorporated into LDPE-based formulations, ES/starch originated brownish materials with lower density (1.18 g cm-3) and higher stiffness (542 MPa of Young's modulus) than those produced with the COM sample (1.33 g cm-3 of density; 221 MPa of Young's modulus). Therefore, starch consolidation of ES revealed to be a promising approach to develop lightweight fillers able to provide stiffness and color to LDPE-based plastics, while valorizing biomolecules-rich by-products.

Graphene Derivatives in Biopolymer-Based Composites for Food Packaging Applications.

This review aims to showcase the current use of graphene derivatives, graphene-based nanomaterials in particular, in biopolymer-based composites for food packaging applications. A brief introduction regarding the valuable attributes of available and emergent bioplastic materials is made so that their contributions to the packaging field can be understood. Furthermore, their drawbacks are also disclosed to highlight the benefits that graphene derivatives can bring to bio-based formulations, from physicochemical to mechanical, barrier, and functional properties as antioxidant activity or electrical conductivity. The reported improvements in biopolymer-based composites carried out by graphene derivatives in the last three years are discussed, pointing to their potential for innovative food packaging applications such as electrically conductive food packaging.