Optoelectronic chromatic dispersion in germanium PN photodiodes: wavelength monitoring and FBG interrogation.

Optoelectronic chromatic dispersion (OED) has recently been shown to be a significant source of chromatic dispersion in photodiodes. We characterize the OED in a commercial germanium PN-type photodiode and determine the optimum conditions for maximum OED sensitivity and wavelength monitoring. A peak OED sensitivity of 1 deg/nm is measured in a spectral range of 1550-1558 nm with 4 MHz modulation. We also demonstrate an application of OED in fiber Bragg grating (FBG) interrogation. Quasi-static and vibration strains are monitored, with a spectral and strain sensitivity of 1.25pm/Hz and 1.08µÎµ/Hz, respectively. Photodiode OED can form the basis of inexpensive chip-scale grating-less spectral analysis.

Fluorescent Biotin Analogues for Microstructure Patterning and Selective Protein Immobilization.

Benzyl substitution on ureido nitrogens of biotin led to manifestation of aggregation-induced emission, which was studied by steady-state fluorescence, microscopy, and TD-DFT, providing a rationale into the observed photophysical behavior. Besides exhibiting solvatochromism, the biotin derivatives revealed emission peaks centered at ∼430 and 545 nm, which has been attributed to the π-π stacking interactions. Our TD-DFT results also correlate the spectroscopic data and quantify the nature of transitions involved. The isothermal titration calorimetry data substantiates that the binding of the biotin derivatives with avidin are pretty strong. These derivatives on lithographic patterning present a platform for site specific strept(avidin) immobilization, thus opening avenues for potential applications exploiting these interactions. The fluorescent biotin derivatives can thus find applications in cellular biology and imaging.

Directional Plasmonic Excitation by Helical Nanotips.

The phenomenon of coupling between light and surface plasmon polaritons requires specific momentum matching conditions. In the case of a single scattering object on a metallic surface, such as a nanoparticle or a nanohole, the coupling between a broadband effect, i.e., scattering, and a discrete one, such as surface plasmon excitation, leads to Fano-like resonance lineshapes. The necessary phase matching requirements can be used to engineer the light-plasmon coupling and to achieve a directional plasmonic excitation. Here, we investigate this effect by using a chiral nanotip to excite surface plasmons with a strong spin-dependent azimuthal variation. This effect can be described by a Fano-like interference with a complex coupling factor that can be modified thanks to a symmetry breaking of the nanostructure.