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1.
Materials (Basel) ; 16(8)2023 Apr 16.
Artigo em Inglês | MEDLINE | ID: mdl-37109969

RESUMO

The automobile industry commonly uses cyclic corrosion tests (CCTs) to evaluate the durability of materials. However, the extended evaluation period required by CCTs can pose challenges in this fast-paced industry. To address this issue, a new approach that combines a CCT with an electrochemically accelerated corrosion test has been explored, to shorten the evaluation period. This method involves the formation of a corrosion product layer through a CCT, which leads to localized corrosion, followed by applying an electrochemically accelerated corrosion test using an agar gel electrolyte to preserve the corrosion product layer as much as possible. The results indicate that this approach can achieve comparable localized corrosion resistance, with similar localized corrosion area ratios and maximum localized corrosion depths to those obtained through a conventional CCT in half the time.

2.
Materials (Basel) ; 15(19)2022 Sep 24.
Artigo em Inglês | MEDLINE | ID: mdl-36233972

RESUMO

In this work, a cerium/tetraethylenepentamine dithiocarbamate complex was synthesized and evaluated for the corrosion inhibition capability on an AA2024-T3 Al alloy in a 3.5% NaCl medium. The synthesized compounds were characterized via spectroscopic techniques. The corrosion inhibition behaviour of the complex was elucidated by electrochemical measurements and surface analysis techniques. Based on electrochemical test results, the corrosion inhibition efficiency of the complex increases with the immersion time of aluminium alloy in the test solution. The corrosion inhibition reaches 96.80% when the aluminium is immersed in a 3.5% NaCl solution containing a corrosion inhibitor for 120 h. The potentiodynamic polarization test results show that the complex acts as a mixed-type corrosion inhibitor and the passive range is widened. The surface analysis methods reveal that the corrosion inhibition ability of the complex originated from the formation of a protective layer on the Al surface. This film is created from the physisorption and chemisorption of cerium ions and organic parts simultaneously released from the complex molecules.

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