Optimized high-yield synthesis of chitin nanocrystals from shrimp shell chitin by steam explosion.

This study attempted for the first time to prepare chitin nanocrystals (ChNCs) from shrimp shell chitin using steam explosion (SE) method. Response surface methodology (RSM) approach was used to optimize the SE conditions. Optimum SE conditions to acquire a maximum yield of 76.78 % were acid concentration (2.63 N), time (23.70 min), and chitin to acid ratio (1:22). Transmission electron microscopy (TEM) revealed the ChNCs produced by SE had an irregular spherical shape with an average diameter of 55.70 ± 13.12 nm. FTIR spectra showed ChNCs were slightly different than chitin due to a shift in peak positions to higher wavenumber and higher peak intensities. XRD patterns indicated ChNCs were a typical α-chitin structure. Thermal analysis revealed ChNCs were less thermally stable than chitin. Compared to conventional acid hydrolysis, the SE approach described in this study is simple, fast, easy, and requires less acid concentration and acid quantity, making it more scalable and efficient for synthesizing ChNCs. Furthermore, the characteristics of the ChNCs will shed light on the potential industrial uses for the polymer.

Morphology, transport characteristics and viscoelastic polymer chain confinement in nanocomposites based on thermoplastic potato starch and cellulose nanofibers from pineapple leaf.

Eco-friendly "green" nano composites were fabricated from potato starch and cellulose nanofibers from pineapple leaf. Nanocomposites of starch/cellulose nanofibers were prepared by solution mixing followed by casting. The investigation of the viscoelastic properties confirms starch macromolecular chain confinement around the nano scale cellulose surface, superior dispersion and very good interaction between thermoplastic starch and cellulose nanofibers. The degree of chain confinement was quantified. The chain confinement was associated with the immobilization of the starch macromolecular chains in the network formed by the nano-scale cellulose fibers as a result of hydrogen boding interactions. From the results, it was assumed that the starch glycerol system exhibits a heterogenous nature and cellulose nanofibers tend to move towards glycerol rich starch phase. Barrier properties also improved with the addition of nanofiller up to 3wt.% but further addition depreciated properties due to possible fiber agglomeration. The kinetics of diffusion was investigated and typical kinetic parameters were determined and found that the nanocomposites follow pseudo fickian behaviour. The outcome of the work confirms that the prepared nanocomposites films can be used as a swap for packaging applications.