RESUMO
Replacing fossil fuels with energy sources and carriers that are sustainable, environmentally benign, and affordable is amongst the most pressing challenges for future socio-economic development. To that goal, hydrogen is presumed to be the most promising energy carrier. Electrocatalytic water splitting, if driven by green electricity, would provide hydrogen with minimal CO2 footprint. The viability of water electrolysis still hinges on the availability of durable earth-abundant electrocatalyst materials and the overall process efficiency. This review spans from the fundamentals of electrocatalytically initiated water splitting to the very latest scientific findings from university and institutional research, also covering specifications and special features of the current industrial processes and those processes currently being tested in large-scale applications. Recently developed strategies are described for the optimisation and discovery of active and durable materials for electrodes that ever-increasingly harness first-principles calculations and machine learning. In addition, a technoeconomic analysis of water electrolysis is included that allows an assessment of the extent to which a large-scale implementation of water splitting can help to combat climate change. This review article is intended to cross-pollinate and strengthen efforts from fundamental understanding to technical implementation and to improve the 'junctions' between the field's physical chemists, materials scientists and engineers, as well as stimulate much-needed exchange among these groups on challenges encountered in the different domains.
Assuntos
Desenvolvimento Industrial , Água , Eletricidade , Eletrólise , Humanos , HidrogênioRESUMO
The COVID-19 pandemic sent the oil industry into turmoil on a scale not seen since the 1970s. While the sector appears to be recovering, questions remain about the extent to which the pandemic has offered a glimpse into the possible future of the industry. This future is critical to the success of climate change mitigation, which requires significant cuts to the carbon dioxide emissions from using oil for energy. Therefore, it makes sense to consider future scenarios in which global oil demand peaks and then declines alongside scenarios of continued demand growth. This is a significant departure from historical development of oil demand and the dominant discussion of many decades about "peak oil" and the fear of demand outstripping readily available supply. The implications of peaking oil demand would be massive, not only for the oil industry but also for society as whole. There is not enough understanding of what the impacts would be, or how to prepare for them. The research community needs to take a clear-eyed view of potential futures of oil, which includes considering scenarios in which demand goes into long-term decline.
RESUMO
Weather-dependent renewable energy resources are playing a key role in decarbonizing electricity. There is a growing body of analysis on the impacts of wind and solar variability on power system operation. Existing studies tend to use a single or typical year of generation data, which overlooks the substantial year-to-year fluctuation in weather, or to only consider variation in the meteorological inputs, which overlooks the complex response of an interconnected power system. Here, we address these gaps by combining detailed continent-wide modeling of Europe's future power system with 30 years of historical weather data. The most representative single years are 1989 and 2012, but using multiple years reveals a 5-fold increase in Europe's inter-annual variability of CO2 emissions and total generation costs from 2015 to 2030. We also find that several metrics generalize to linear functions of variable renewable penetration: CO2 emissions, curtailment of renewables, wholesale prices, and total system costs.
RESUMO
As wind and solar power provide a growing share of Europe's electricity1, understanding and accommodating their variability on multiple timescales remains a critical problem. On weekly timescales, variability is related to long-lasting weather conditions, called weather regimes2-5, which can cause lulls with a loss of wind power across neighbouring countries6. Here we show that weather regimes provide a meteorological explanation for multi-day fluctuations in Europe's wind power and can help guide new deployment pathways which minimise this variability. Mean generation during different regimes currently ranges from 22 GW to 44 GW and is expected to triple by 2030 with current planning strategies. However, balancing future wind capacity across regions with contrasting inter-regime behaviour - specifically deploying in the Balkans instead of the North Sea - would almost eliminate these output variations, maintain mean generation, and increase fleet-wide minimum output. Solar photovoltaics could balance low-wind regimes locally, but only by expanding current capacity tenfold. New deployment strategies based on an understanding of continent-scale wind patterns and pan-European collaboration could enable a high share of wind energy whilst minimising the negative impacts of output variability.