Monolithic Catalyst of Ni Foam-Supported MnOx for Boosting Magnetocaloric Oxidation of Toluene.

Catalytic oxidation has been considered an effective technique for volatile organic compound degradation. Development of metal foam-based monolithic catalysts coupling electromagnetic induction heating (EMIH) with efficiency and low energy is critical yet challenging in industrial applications. Herein, a Mn18.2-NF monolithic catalyst prepared by electrodeposition exhibited superior toluene catalytic activity under EMIH conditions, and the temperature of 90% toluene conversion decreased by 89 °C compared to that in resistance furnace heating. Relevant characterizations proved that the skin effect induced by EMIH encouraged activation of gaseous oxygen, leading to superior low-temperature redox properties of Mn18.2-NF under the EMIH condition. In situ Fourier transform infrared spectroscopy results showed that skin effect-induced activation of oxidizing species further accelerated the conversion of intermediates. As a result, the Mn18.2-NF monolithic catalyst under EMIH demonstrated remarkable performance for the toluene oxidation, surpassing the conventional nonprecious metal catalyst and other reported monolithic catalysts.

Unveiling the Position Effect of Ce within Layered MnO2 to Prolong the Ambient Removal of Indoor HCHO.

The position of Ce doping has a significant effect on ambient HCHO storage and catalytic oxidation on layered MnO2. By associating structure and performance, it is unveiled that doping Ce into the in-layered lattice of MnO2 is favorable to the generation of high-valence Mn cations, enhancing the oxidizing ability and capacity, but an opposite influence is displayed by interlayered Ce doping. From the aspect of energy minimization calculated by DFT, in-layered Ce doping is also recommended due to the decreased energies for molecule adsorption and oxygen vacancy formation. As a result, in-layered Ce-doped MnO2 displays exceptional activity in catalyzing the deep oxidation of HCHO and a fourfold higher capacity of ambient HCHO storage than pristine MnO2. The optimal oxide is combined with electromagnetic induction heating to complete the "storage-oxidation" cycle as a promising approach absolutely depending on non-noble oxides and household appliances to realize the long-acting removal of indoor HCHO at room temperature.