1.
Dalton Trans
; 40(47): 12663-6, 2011 Dec 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22015646
RESUMO
A new oxidation procedure of alkynes catalyzed by Tp(PPh(3))(CH(3)CN)Ru-Cl is presented, which provides an efficient way to obtain alkenyl 1,2-diketones via ruthenium alkenyl 1,2-diketone intermediates. In contrast, the analogous reactions with Tp(PPh(3))(PhCN)Ru-Cl gave rise to the ruthenium metallacycle complexes.