RESUMO
OBJECTIVE: To measure the interrater reliability of assessing the frequency of vegetable intake using mobile photos and descriptions. DESIGN: Repeated measures design. SETTING: A Midwestern university. PARTICIPANTS: Undergraduate students (N = 165). MEASURABLE OUTCOME/ANALYSIS: Number of times each of these vegetable subgroups were consumed daily: dark green vegetables, beans and peas, starchy vegetables, and other vegetables. Analysis: Two raters independently coded meals using mobile photos and descriptions of meals. Cohen κ was calculated to determine interrater reliability. RESULTS: A value of κ = 0.9 (p < .001) was obtained, indicating an almost perfect agreement between the two raters. Nearly 92% of participants complied with providing photos along with descriptions of their meals. CONCLUSIONS AND IMPLICATIONS: A frequency method using mobile photos and descriptions of meals is a reliable strategy to assess vegetable consumption. This frequency method can improve data quality, reduce participant burden, and minimize recall bias in college nutrition programs.
RESUMO
Carbon xerogels were synthesized using a soft-template route with resorcinol as the carbon source and sodium carbonate as the catalyst. The influence of the resorcinol to catalyst ratio in the range of 500-20,000 on pore structure, graphitic domains, and electronic conductivity of as-prepared carbon xerogels, as well as their performance in an aluminium ion battery (AIB), was investigated. After carbonization steps of the polymers up to 800 °C, all carbon samples exhibited similar specific volumes of micropores (0.7-0.8 cm³ g-1), while samples obtained from mixtures with R/C ratios lower than 2000 led to carbon xerogels with significantly higher mesopore diameters up to 6 nm. The best results, in terms of specific surface (1000 m² g-1), average pore size (6 nm) and reversible capacity in AIB cell (28 mAh g-1 @ 0.1 A g-1), were obtained with a carbon xerogel sample synthetized at a resorcinol to catalyst ratio of R/C = 500 (CXG500). Though cyclic voltammograms of carbon xerogel samples did not exhibit any sharp peaks in the applied potential window, the presence of both oxidation and a quite wide reduction peak in CXG500-2000 cyclic voltammograms indicated pseudocapacitance behaviour induced by diffusion-controlled intercalation/de-intercalation of AlCl4- ions into/from the carbon xerogel matrix. This was confirmed by shifting of the (002) peak towards lower 2θ angle values in the XRD pattern of the CXG500 electrode after the charging step in AIB, whereas the contribution of pseudocapacitance, calculated from half-cell measurements, was limited to only 6% of overall capacitance.