A novel electrical depercolation model for stretchable nanocomposite strain sensors.

Flexible strain sensors have been subject to intense research efforts in recent years, in an attempt to overcome the limitations of their rigid counterparts and find use in demanding applications. In this work, the effective calibration of resistive-type, stretchable strain sensors is discussed. A new model for the piezoresistive response of stretchable polymer nanocomposite strain sensors is presented which facilitates calibration over the full conducting strain range of the material. This offers the potential to vastly improve the practical working range of sensors made using soft conductive nanocomposites, as well as to obtain key information towards improvement of sensing performance. The model has been successfully applied to multiple experimental measurements on silicone rubber (SR) nanocomposites reinforced with reduced graphene oxide (rGO) over a range of filler loadings. The effect of parameters such as filler dimensions, filler orientation and dispersion state is discussed, while predictions on sensitivity and working range are made on the basis of interparticle distance modelling.

Explosive percolation yields highly-conductive polymer nanocomposites.

Explosive percolation is an experimentally-elusive phenomenon where network connectivity coincides with onset of an additional modification of the system; materials with correlated localisation of percolating particles and emergent conductive paths can realise sharp transitions and high conductivities characteristic of the explosively-grown network. Nanocomposites present a structurally- and chemically-varied playground to realise explosive percolation in practically-applicable systems but this is yet to be exploited by design. Herein, we demonstrate composites of graphene oxide and synthetic polymer latex which form segregated networks, leading to low percolation threshold and localisation of conductive pathways. In situ reduction of the graphene oxide at temperatures of <150 °C drives chemical modification of the polymer matrix to produce species with phenolic groups, which are known crosslinking agents. This leads to conductivities exceeding those of dense-packed networks of reduced graphene oxide, illustrating the potential of explosive percolation by design to realise low-loading composites with dramatically-enhanced electrical transport properties.