Investigating the Inhibitory Properties of Cupressus sempervirens Extract against Copper Corrosion in 0.5 M H2SO4: Combining Quantum (Density Functional Theory Calculation-Monte Carlo Simulation) and Electrochemical-Surface Studies.

The study investigates the potential of Cupressus sempervirens (EO) as a sustainable and eco-friendly inhibitor of copper corrosion in a 0.5 M sulfuric acid medium. The electrochemical impedance spectroscopy analysis shows that the effectiveness of corrosion inhibition rises with increasing inhibitor concentrations, reaching 94% with the application of 2 g/L of EO, and potentiodynamic polarization (PDP) studies reveal that EO functions as a mixed-type corrosion inhibitor. In addition, the Langmuir adsorption isotherm is an effective descriptor of its adsorption. Scanning electron microscopy/energy-dispersive X-ray spectroscopy, atomic force microscopy surface examination, and contact angle measurement indicate that EO may form a barrier layer on the metal surface. Density functional theory calculations, Monte Carlo simulation models, and the radial distribution function were also used to provide a more detailed understanding of the corrosion protection mechanism. Overall, the findings suggest that Cupressus sempervirens (EO) has the potential to serve as an effective and sustainable corrosion inhibitor for copper in a sulfuric acid medium, contributing to the development of green corrosion inhibitors for environmentally friendly industrial processes.

Corrosion Behavior and Susceptibility to Stress Corrosion Cracking of Leaded and Lead-Free Brasses in Simulated Drinking Water.

Duplex α + ß' brasses are widely used in drinking water distribution systems for tube fittings, valves, and ancillaries because they are low cost, easy to fabricate, and exhibit high mechanical strength. However, depending on application conditions and alloy composition, they may undergo dealloying and stress corrosion cracking. In this research, three different brass types, two leaded (CW617N and CW602N) alloys and one lead-free brass (CW724R), were investigated to assess their corrosion behavior and susceptibility to stress corrosion cracking (SCC) in simulated drinking water (SDW) solutions containing different chloride concentrations, compatible with drinking water composition requirements according to Moroccan standard NM 03.7.001. The corrosion behavior was assessed by electrochemical tests such as polarization curve recording and electrochemical impedance spectroscopy (EIS) monitoring, coupled to SEM-EDS surface observations. The susceptibility to SCC was investigated by slow strain rate tests (SSRT). The tests showed that corrosion was mainly under diffusion control and chlorides slightly accelerated corrosion rates. All alloys, and particularly CW617N, were affected by SCC under the testing conditions adopted and in general the SCC susceptibility increased at increasing chloride concentration.