1.
Angew Chem Int Ed Engl
; 55(7): 2564-8, 2016 Feb 12.
Artigo
em Inglês
| MEDLINE
| ID: mdl-26806850
RESUMO
Azulenesulfonium salts may be readily prepared from the corresponding azulenes by an SE Ar reaction. These azulene sulfonium salts are bench-stable species that may be employed as pseudohalides for cross-coupling. Specifically, their application in Suzuki-Miyaura reactions has been demonstrated with a diverse selection of coupling partners. These azulenesulfonium salts possess significant advantages in comparison with the corresponding azulenyl halides, which are known to be unstable and difficult to prepare in pure form.