Pristine Graphene Microspheres by the Spreading and Trapping of Graphene at an Interface.

The interfacial spreading and exfoliation of graphene was used to create low-density, hollow microspheres defined by a thin shell of graphene. The spheres were templated by a thermodynamically driven self-assembly process in which graphite spontaneously exfoliated and spread at the high-energy interfaces of a water-in-oil emulsion. Graphene thus acted as a 2D surfactant to stabilize the dispersed water droplets utilized as polymerization templates. Using a mixture of organic solvent and monomer as the emulsion oil phase, polystyrene-coated hollow graphene microspheres were created. These spheres were characterized by optical and electron microscopy, thermo-gravimetric analysis, nanoindentation, and particle sizing. The mechanism leading to the microsphere surface morphology and shape is discussed, with the oil phase composition shown to play a critical role.

Interface-exfoliated graphene-based conductive screen-printing inks: low-loading, low-cost, and additive-free.

Paper diagnostics are of growing interest due to their low cost and easy accessibility. Conductive inks, necessary for manufacturing the next generation diagnostic devices, currently face challenges such as high cost, high sintering temperatures, or harsh conditions required to remove stabilizers. Here we report an effective, inexpensive, and environmentally friendly approach to graphene ink that is suitable for screen printing onto paper substrates. The ink formulation contains only pristine graphite, water, and non-toxic alkanes formed by an interfacial trapping method in which graphite spontaneously exfoliates to graphene. The result is a viscous graphene stabilized water-in-oil emulsion-based ink. This ink does not require sintering, but drying at 90 °C or brief microwaving can improve the conductivity. The production requires only 40 s of shaking to form the emulsion. The sheet resistance of the ink is approximately 600 Ω/sq at a thickness of less than 6 µm, and the ink can be stabilized by as little as 1 wt% graphite.

Self-Assembled Graphene Composites for Flow-Through Filtration.

Spontaneously exfoliated pristine graphene is used as a surfactant to template the formation of electrically conductive filters for the adsorption of an organic dye from water. In contrast to other reported graphene-based adsorption materials, our system provides a continuous approach to water treatment rather than a batch approach, and uses pristine graphene instead of the more costly and environmentally challenging graphene oxide. The use of self-assembled graphene also results in our filters being electrically conductive, providing a convenient route to clean the filters by resistive heating. An investigation of the mechanism of formation and filtration by these filters, templated by self-assembled two-dimensional pristine graphene, is presented. The thermodynamically driven exfoliation of natural flake graphite at a high-energy monomer/water interface produces water-in-oil emulsions stabilized by a thin layer of overlapping graphene sheets. Subsequent polymerization of the continuous monomer phase produces polymer foams with cells lined by graphene. With a combination of acoustic spectroscopy and electron microscopy, the effects of graphite concentration and temperature are studied, as is the correlation between droplet size and the size of the cells in the final polymer foam.

Controlled 3D Assembly of Graphene Sheets to Build Conductive, Chemically Selective and Shape-Responsive Materials.

Driven by the surface activity of graphene, electrically conductive elastomeric foams have been synthesized by the controlled reassembly of graphene sheets; from their initial stacked morphology, as found in graphite, to a percolating network of exfoliated sheets, defining hollow spheres. This network creates a template for the formation of composite foams, whose swelling behavior is sensitive to the composition of the solvent, and whose electrical resistance is sensitive to physical deformation. The self-assembly of graphene sheets is driven thermodynamically, as graphite is found to act as a 2D surfactant and is spread at high-energy interfaces. This spreading, or exfoliation, of graphite at an oil/water interface stabilizes water-in-oil emulsions, without the need for added surfactants or chemical modification of the graphene. Using a monomer such as butyl acrylate for the emulsion's oil phase, elastomeric foams are created by polymerizing the continuous oil phase. Removal of the aqueous phase then results in robust, conductive, porous, and inexpensive composites, with potential applications in energy storage, filtration, and sensing.