Chirped ordered pulses for ultra-broadband ESR spectroscopy.

Recently, applications of swept-frequency pulses proved to be a useful approach to circumvent the problem of limited excitation bandwidth in pulsed ESR posed by conventional pulses. Here, we present a chirped excitation sequence, CHirped ORdered pulses for Ultra-broadband Spectroscopy (CHORUS), for ultra-broadband ESR spectroscopy. It will be demonstrated that the application of this sequence can address the problems of excitation non-uniformity and sensitivity to instrumental instabilities to a greater extent compared to the current state of the art. This sequence is highly promising for finding applications beyond single excitation in many ESR experiments. Theoretical and experimental results for the proposed method are presented along with calibration strategies for experimental implementation.

Improved design of frequency-swept pulse sequences.

Frequency-swept pulses are extensively used in magnetic resonance spectroscopic techniques for the robust manipulation of spins across wide ranges of offset frequencies in the presence of B1 field variations. Nevertheless, designing pulse sequences consisting of multiple frequency-swept pulses can be challenging, as they often require specific timings and parameter tweaking. In the present work we discuss a simple and general approach for constructing such sequences. We present new and improved pulse sequences for applications including broadband B1-tolerant CPMG (CHORUS-CPMG), broadband chirped excitation with suppression of homonuclear J-modulation (PROCHORUS), and the further compression of frequency-swept pulse sequences by superposition of pulses which reduces pulse sequence durations by 25-40%. All sequence design strategies are accompanied by mathematical presentations, experimental results, and supporting simulations.

Towards fully optimised and automated ESR spectroscopy.

To address the problems of instrumental imperfection and time-consuming experimental setup in electron spin resonance (ESR), we present ESR-POISE, a user-friendly software package for fully automated and fast on-the-fly optimisation and acquisition of ESR experiments. This open-source package interfaces with Bruker's Xepr software and allows scientists to run user-defined optimisations.