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Contamination of heavy metals has always been a pressing concern. The dry-wet alternately treated carboxymethylcellulose bentonite (DW-CB) was successfully prepared by intercalating bentonite (BT) with carboxymethyl cellulose (CMC) obtained by solvent processes using enzymatically digested wastepaper as cellulosic raw material, and the adsorption capacity of Cu2+ on DW-CB in aqueous solution was investigated. A 98.18 ± 2.31 % removal efficiency was achieved by 4 g/L of DW-CB after 8 h in a solution containing 100 mg/L of Cu2+, which were 4.1 times and 1.5 times of that of BT and adsorbent prepared without alternating dry-wet process, respectively. The introduction of -COOH groups during the preparation of DW-CB enhanced the electrostatic interaction between DW-CB and Cu2+, which was the main driving force for Cu2+ removal. The pseudo-first-order kinetic model and Langmuir model better described the adsorption process and adsorption capacity of Cu2+ on DW-CB. DW-CB still showed high removal of Cu2+ (19.61 ± 0.99 mg/g) in the presence of multiple metal ions, while exhibiting the potential for removal of Zn2+, Mg2+ and K+, especially Mg2+ (22.69 ± 1.48 mg/g). However, the interactions of organics with Cu2+ severely affected the removal of Cu2+ by DW-CB (removal efficiency: 17.90 ± 4.17 % - 95.33 ± 0.27 %). In this study, an adsorbent with high targeted adsorption of Cu2+ was prepared by utilizing wastepaper and BT, which broadened the way of wastepaper resource utilization and had good economic and social benefits.
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Metais Pesados , Poluentes Químicos da Água , Bentonita , Cobre/análise , Poluentes Químicos da Água/análise , Água , Cinética , Adsorção , Concentração de Íons de HidrogênioRESUMO
Catalytic pyrolysis technology proves to be a highly effective approach for waste cooking oil management. However, high-pressure drops and easy deactivation of powder catalysts hinder the industrialization of this technology. In this study, a bifunctional SiC ball (ZSM-5/SiC ball structured) catalyst was prepared to produce monocyclic aromatics. Bifunctional SiC ball catalyst demonstrates notable microwave-responsive properties and remarkable catalytic efficacy. Results showed that the content of monocyclic aromatics under BFSB catalysis with microwave heating was the highest. Weight hourly space velocity is no longer one of the main factors affecting microwave-assisted catalytic pyrolysis under bifunctional SiC ball catalyst. Monocyclic aromatics content did not decrease significantly and was still higher than 86% when space velocity increased from 30 h-1 to 360 h-1. The highest space velocity could only be 180 h-1 under Powder ZSM-5, and the content of the monocyclic aromatics dropped rapidly to 67.68%. Furthermore, even after five operating cycles, the content of monocyclic aromatics with bifunctional SiC ball catalyst continues to surpass the initial content observed with Powder ZSM-5 at 500 °C and 180 h-1. Related characterizations revealed that coking is the primary cause of catalyst deactivation for both catalyst types; however, the bifunctional SiC ball catalyst exhibits a 29.1% lower occurrence of polyaromatic coke formation compared to Powder ZSM-5.
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Micro-Ondas , Pirólise , Pós , Biomassa , Catálise , Temperatura Alta , BiocombustíveisRESUMO
With the growing emphasis on green chemistry and the ecological environment, researchers are increasingly paying attention to greening materials through the use of carbon-based solid acids. The diverse characteristics of carbon-based solid acids can be produced through different preparation conditions and modification methods. This paper presents a comprehensive summary of the current research progress on carbon-based solid acids, encompassing common carbonization methods, such as one-step, two-step, hydrothermal, and template methods. The composition of carbon source material may be the main factor affecting its carbonization method and carbonization temperature. Additionally, acidification types including sulfonating agent, phosphoric acid, heteropoly acid, and nitric acid are explored. Furthermore, the functions of carbon-based solid acids in esterification, hydrolysis, condensation, and alkylation are thoroughly analyzed. This study concludes by addressing the existing drawbacks and outlining potential future development prospects for carbon-based solid acids in the context of their important role in sustainable chemistry and environmental preservation.
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Microalgal biofilm cultivation is a promising method for efficient microalgae production. However, expensive, difficult-to-obtain and non-durable carriers hinder its up-scaling. This study adopted both sterilized and unsterilized rice straw (RS) as a carrier for the development of microalgal biofilm, with polymethyl methacrylate as control. The biomass production and chemical composition of Chlorella sorokiniana, as well as the microbial community composition during cultivation were examined. The physicochemical properties of RS before and after utilized as carrier were investigated. The biomass productivity of unsterilized RS biofilm exceeded that of suspended culture by 4.85 g m-2·d-1. The indigenous microorganisms, mainly fungus, could effectively fixed microalgae to the bio-carrier and enhance its biomass production. They could also degrade RS into dissolved matters for microalgal utilization, leading to the physicochemical properties change of RS in the direction which favored its energy conversion. This study showed that RS can be used effectively as a microalgal biofilm carrier, thus presenting a new possibility for the recycling of rice straw.
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Chlorella , Microalgas , Oryza , Microalgas/metabolismo , Biomassa , BiofilmesRESUMO
Microplastics (MPs) have already spread across the globe and have been found in drinking water and human tissues. This may pose severe threats to human health and water environment. Therefore, this study accurately evaluated the removal effect of metal-modified biochar on polystyrene microplastics (PS-MPs) (1.0 µm) in the water environment using a high-throughput fluorescence quantification method. The results indicated that Fe-modified biochar (FeBC) and Fe/Zn-modified biochar (Fe/ZnBC) had good removal efficiencies for PS-MPs under the dosage of 3 g/L, which were 96.24% and 84.77%, respectively. Although pore effects were observed (such as "stuck", "trapped"), the electrostatic interaction was considered the main mechanism for the adsorption of PS-MPs on metal-modified biochar, whereas the formation of metal-O-PS-MPs may also contribute to the adsorption process. The removal efficiency of PS-MPs by FeBC was significantly reduced under alkaline conditions (pH = 9 and 11) or in the presence of weak acid ions (PO43-, CO32-, HCO3-). A removal efficiency of 72.39% and 78.33% of PS-MPs was achieved from tap water (TW) and lake water (LW) using FeBC when the initial concentration was 20 mg/L. However, FeBC had no removal effect on PS-MPs in biogas slurry (BS) and brewing wastewater (BW) due to the direct competitive adsorption of high concentrations of chemical oxygen demand (COD). The findings of this study highlighted that metal-modified biochar had a potential application in purifying tap water or lake water which contaminated by MPs.
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Poliestirenos , Poluentes Químicos da Água , Humanos , Microplásticos , Plásticos , Água , Adsorção , MetaisRESUMO
Rice straw and swine wastewater are abundant, easy to obtain, and inexpensive biomass materials. Anaerobic digestion of rice straw and swine wastewater effectively regulates the carbon-to-nitrogen ratio and also improves methane production efficiency. The dense lignocellulosic structure, unsuitable carbon-to-nitrogen ratio, and light texture of rice straw hinder its application in anaerobic digestion. Effective pretreatment technologies can improve degradation efficiency and methane production. Our study is the first to apply domesticated paddy soil microbes to enhance the efficiency of hydrolytic acidification of rice straw and swine wastewater at varying temperatures and times. The results show that the highest total organic carbon (1757.2 mg/L), soluble chemical oxygen demand (5341.7 mg/L), and organic acid concentration (4134.6 mg/L) appeared in the hydrolysate after five days of hydrolytic acidification at 37 °C. Moreover, the use of hydrolysate produced 13% more gas and reduced the anaerobic digestion period by ten days compared to the untreated control. This suggests that using domesticated paddy soil microbes as a pretreatment might be a sustainable and cost-effective strategy for improving the degradation efficacy and methane production from lignocellulosic materials.
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Oryza , Anaerobiose , Animais , Biocombustíveis , Carbono/metabolismo , Digestão , Metano/metabolismo , Nitrogênio/metabolismo , Oryza/química , Solo/química , Suínos , Temperatura , Águas ResiduáriasRESUMO
The integrated process of formic acid pretreatment and pyrolysis of bamboo sawdust (BS) under microwave irradiation is developed to produce high-quality bio-oil in this study. Experimental results indicated that microwave-assisted formic acid (MFA) pretreatment was able to reduce the contents of hydrogen, ash, and volatile in biomass. In the meanwhile, a distinct increase in the higher heating value of pretreated BS was observed. Although a higher pretreatment temperature led to lower mass yield, the corresponding energy yield of solid product was remarkably higher. X-ray diffraction and Fourier transfer infrared spectrometry analyses of pretreated BS suggested that MFA pretreatment could destruct the pristine structure of BS. Therefore, thermal properties of pretreated BS were significantly altered in terms of thermal stability and decomposition temperature according to thermogravimetric analysis. Microwave-assisted pyrolysis of pretreated samples could produce less acids, phenols, and ketones but more sugars, especially gluopyranose. Furthermore, the relevant mechanism of microwave-assisted pyrolysis of pretreated BS was interpreted. In sum, MFA was a feasible and promising technology to improve the quality of bio-oil from microwave pyrolysis of biomass.
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Formiatos , Micro-Ondas , Pirólise , Biocombustíveis , Biomassa , Temperatura Alta , Óleos de Plantas , PolifenóisRESUMO
The recovery of ammonia-nitrogen during wastewater treatment and water purification is increasingly critical in energy and economic development. The concentration of ammonia-nitrogen in wastewater is different depending on the type of wastewater, making it challenging to select ammonia-nitrogen recovery technology. Meanwhile, the conventional nitrogen removal method wastes ammonia-nitrogen resources. Based on the circular economy, this review comprehensively introduces the characteristics of several main ammonia-nitrogen source wastewater plants and their respective challenges in treatment, including municipal wastewater, industrial wastewater, livestock and poultry wastewater and landfill leachate. Furthermore, we introduce the main methods currently adopted in the ammonia-nitrogen removal process of wastewater from physical (air stripping, ion exchange and adsorption, membrane and capacitive deionization), chemical (chlorination, struvite precipitation, electrochemical oxidation and photocatalysis) and biological (classical and typical activated sludge, novel methods based on activated sludge, microalgae and photosynthetic bacteria) classification based on the ammonia recovery concept. We discuss the applicable methods of recovering ammonia nitrogen in several main wastewater plants. Finally, we prospect the research direction of ammonia removal and recovery in wastewater based on sustainable development.
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Amônia/análise , Nitrogênio/análise , Águas Residuárias/química , Purificação da Água/métodos , Oxirredução , Estruvita , Poluentes Químicos da Água/análiseRESUMO
In this work, the selenylation Codonopsis pilosula polysaccharide (Se-CPPS) were synthesized using an optimized microwave-assisted method. Then, physicochemical properties, including molecular weight, particle size, valence state of selenium, antioxidant capacity, release mechanism of selenium under gastrointestinal conditions, as well as their effects on HT-29 cell viability were comprehensively investigated. The results demonstrated that Se-CPPS with the highest selenium content (21.71 mg/g) was synthesized using 0.8% nitric acid concentration under microwave conditions of 90 min at 70 °C. FTIR and XPS analysis revealed that Se was bound to the polysaccharide chain in the form of O-Se-O and O-H···Se, with a valence state of either 0 or +4. In vitro investigations on antioxidant activity and selenium release capacity indicated that selenization not only enhanced the antioxidant activity of CPPS but also endowed Se-CPPS with robust selenium release capability in simulated gastric digestion. The effects of Se-CPPS on HT-29 cells was further investigated by CCK-8 method. The results showed that the selenide modification effectively reduced the toxicity of Na2SeO3 and enhanced the viability of CPPS. The findings of this study offer valuable methodological guidance for the synthesis of Se-polysaccharides with superior functional properties.
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Antioxidantes , Sobrevivência Celular , Codonopsis , Micro-Ondas , Polissacarídeos , Selênio , Codonopsis/química , Humanos , Selênio/química , Polissacarídeos/química , Polissacarídeos/farmacologia , Células HT29 , Antioxidantes/farmacologia , Antioxidantes/química , Antioxidantes/síntese química , Sobrevivência Celular/efeitos dos fármacos , Peso MolecularRESUMO
The presence of organic-complexed copper and zinc in anaerobic digestate effluent (ADE) poses persistent ecological toxicity. This study investigated the detoxification performance and biotic responses of indigenous bacteria against ethylene diamine tetraacetic acid (EDTA)-complexed Cu(II) and Zn(II). Heavy metals (HMs) stress induced reactive oxygen species (ROS) generation and enhanced extracellular polymeric substances (EPS) secretion. At a Cu(II) influent concentration of 20.0 mg·L-1, indigenous bacteria removed 88.2% of Cu(II) within nine days. The majority of copper and zinc sequestered by bacteria were stored in the cell envelope, with over 50% of copper and 60% of zinc being immobilized. Transmission electron microscopy mapping (TEM-mapping) revealed significant mineralization of copper and zinc on the cell wall. Proteins abundant in EPS, alongside humic acid-like substances, effectively adsorbed HMs. Indigenous bacteria exhibited the capacity to reduce cupric to the cuprous state and cupric is preferentially reduced to cuprous before reaching reducing capacity saturation. Sulfur precipitation emerges as a crucial pathway for Zn(II) removal. Metagenomic analysis indicated that indigenous bacteria upregulated genes related to HMs homeostasis, efflux, and DNA repair, enhancing its resistance to high concentrations HMs. This study provided theoretical guidance for employing bacterial consortia to eliminate HMs in complex aquatic environments.
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Cobre , Metais Pesados , Cobre/toxicidade , Cobre/metabolismo , Zinco/toxicidade , Zinco/metabolismo , Anaerobiose , Metais Pesados/metabolismo , Bactérias/genética , Bactérias/metabolismo , Compostos Orgânicos/metabolismoRESUMO
Lignocellulosic biomass, renewable with short growth cycle and diverse sources, can be substituted fossil fuel. However, low effective hydrogen-to-carbon ratio (H/Ceff) limits its applications. Torrefaction and co-pyrolysis with high H/Ceff feedstocks are promising technology. This paper investigated the effect of heating modes on oil-bath torrefaction of walnut shells, followed by fast co-pyrolysis. Six heating modes during oil-bath torrefaction were evaluated. Com1 (Microwave 67 %, Lightwave 33 %) yielded the lowest residual yield 84 wt%, while the highest gas production 495.47 mL/g which mainly composed of CO and CO2. Torrefied feedstock under Com1 had the highest H/Ceff. Decarboxylation and decarbonylation reactions dominated among oil-bath torrefaction. Com1 produced the most hydrocarbons and least oxygen-containing compounds. As microwave ratio decreased, the content of olefins, acids and phenols decreased, monocyclic aromatic hydrocarbons and alcohols was showed opposite tend. This study offers new ideas for microwave and lightwave torrefaction and promoting hydrocarbon production from lignocellulosic biomass.
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Juglans , Pirólise , Juglans/química , Biomassa , Óleos de Plantas/química , Calefação , Biotecnologia/métodos , Micro-Ondas , Temperatura Alta , Lignina/químicaRESUMO
The necessity to look into waste biomass resource regeneration has increased due to growing environmental and energy-related problems. This study successfully developed an innovative fishbone-derived carbon-based solid acid catalyst using the carbonation-sulfonation method, which was subsequently applied to catalyze the hydrolysis of cellulose to produce nanocellulose. The data analysis reveals that the sulfonation treatment affects the microstructure of the catalyst, resulting in a decline in its specific surface area (134.48 m2/g decreased to 9.66 m2/g). However, this treatment doesn't hinder the introduction of acidic functional groups. In particular, the solid acid catalyst derived from fishbone exhibited a total acid content of 3.76 mmol/g, with a concentration of -SO3H groups at 0.48 mmol/g. Furthermore, the solid acids originating from fishbones manifested remarkable thermal stability, exhibiting a mass loss of <15 % at temperatures up to 600 °C. Moreover, the catalyst displayed exceptional catalytic performance during the cellulose hydrolysis reaction, achieving an optimum nanocellulose yield of 45.7 % at an optimized reaction condition. An additional noteworthy feature is the solid acid catalyst's impressive recyclability, maintaining a nanocellulose yield of 44.87 % even after undergoing five consecutive usage cycles. This research outcome underscores an innovative approach to for the sustainable utilization of waste biomass resources.
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Celulose , Celulose/química , Hidrólise , Catálise , Animais , Biomassa , Ácidos/química , TemperaturaRESUMO
Lutein is widely used in medicine, health care, and food processing due to its antioxidant effects; however, it is difficult for the traditional extraction of lutein using marigolds to meet the increasing market demand for lutein. To achieve high-efficiency lutein production, we investigated the effects of different conditions on the biomass accumulation and lutein yield of Chlorella vulgaris. The optimized cultivation conditions include mixotrophic cultivation using sodium nitrate as a nitrogen source, maintaining a total-organic-carbon-to-total-nitrogen ratio of 12:1, a total-nitrogen-to-total-phosphorus ratio of 10:1, and lighting duration of 24 h. The results of the study indicated that under these specific conditions, Chlorella vulgaris attained a final biomass concentration, biomass productivity, and growth yield of 6.08 g·L-1, 1.00 g·L-1·d-1, and 1.67 g biomass/g TOC, respectively. Additionally, the concentrations of total chlorophyll, carotenoid, lutein, and protein reached 139.20 mg·L-1, 31.87 mg·L-1, 15.02 mg·L-1, and 2.17 g·L-1, respectively, and the content of lutein reached 2.47 mg·g-1. This study supplies a theoretical basis for the industrial application of lutein production using Chlorella vulgaris.
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The presence of excessive residual Cu(II), a high-risk heavy metal with potential toxicity and biomagnification property, substantially impede the value-added utilization of anaerobic digestion effluent (ADE). This study adapted indigenous bacterial consortium (IBCs) to eliminate Cu(II) from ADE, and their performances and resistance mechanisms against Cu(II) were analyzed. Results demonstrated that when the Cu(II) exposure concentration exceeded 7.5 mg/L, the biomass of IBCs decreased significantly, cells produced a substantial amount of ROS and EPS, at which time the intracellular Cu(II) content gradually decreased, while Cu(II) accumulation within the EPS substantially increased. The combined features of a high PN/PS ratio, a reversed Zeta potential gradient, and abundant functional groups within EPS collectively render EPS a primary diffusion barrier against Cu(II) toxicity. Mutual physiological and metagenomics analyses reveal that EPS synthesis and secretion, efflux, DNA repair along with coordination between each other were the primary resistance mechanisms of IBCs against Cu(II) toxicity. Furthermore, IBCs exhibited enhanced resistance by enriching bacteria carrying relevant resistance genes. Continuous pretreatment of actual ADE with IBCs at a 10-day hydraulic retention time (HRT) efficiently eliminated Cu(II) concentration from 5.01 mg/L to â¼0.68 mg/L by day 2. This elimination remained stable for the following 8 days of operation, further validated their good Cu(II) elimination stability. Notably, supplementing IBCs with 200 mg/L polymerized ferrous sulfate significantly enhanced their settling performance. By elucidating the intricate interplay of Cu(II) toxicity and IBC resistance mechanisms, this study provides a theoretical foundation for eliminating heavy metal barriers in ADE treatment.
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Cobre , Metais Pesados , Anaerobiose , BactériasRESUMO
Emulsion gels from the pomelo peel insoluble dietary fiber (PIDF) were developed. The emulsification potentials of PIDFs subjected to various degrees of ball milling (M-PIDFs), cellulase hydrolysis (C-PIDF), and cellulase hydrolysis followed by ball milling (CM-PIDFs) were evaluated. Emulsions prepared by M-PIDFs for different lengths of ball milling time exhibited similar stability characteristics, confirming that M-PIDF emulsion stability might be determined by the three-dimensional structure formed by M-PIDF stacking and oil droplet capture. C-PIDF had characteristics resembling those of Pickering particles. CM-PIDF emulsions got destabilized with ball milling time prolongation. Interface tension and particle size of C/CM-PIDF decreased gradually during ball milling. Rheological and fluorescence microscopy results revealed that the intact internal crosslinking structure frameworks were disrupted in CM-PIDF emulsions. Therefore, intact fiber-based networks, rather than small particle size or low interfacial tension, determine the stability of PIDF emulsions. This study deepens the understanding of PIDF as a clean emulsifier.
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Celulase , Emulsões/química , Porosidade , Emulsificantes , Tamanho da Partícula , Fibras na Dieta , Água/químicaRESUMO
Spent bleaching clay, a solid waste generated during the refining process of vegetable oils, lacks an efficient treatment solution. In this study, spent bleaching clay was innovatively employed to fabricate ceramic foams. The thermal stability analysis, microstructure, and crystal phase composition of the ceramic foams were characterized by TG-DSC, SEM, and XRD. An investigation into the influence of Al2O3 content on the ceramic foams was conducted. Results showed that, as the Al2O3 content increased from 15 wt% to 30 wt%, there was a noticeable decrease in bulk density and linear shrinkage, accompanied by an increase in compressive strength. Additionally, the ceramic foams were used as catalyst supports, to synthesize ZSM-5@ceramic foam composite catalysts for pyrolysis of waste oil. The open pores of the ZSCF catalyst not only reduced diffusion path length but also facilitated the exposure of more acid sites, thereby increasing the utilization efficiency of ZSM-5 zeolite. This, in turn, engendered a significant enhancement in monocyclic aromatic hydrocarbons content from 39.15 % (ZSM-5 powder catalyst) to 78.96 %. Besides, a larger support pore size and a thicker ZSM-5 zeolite coating layer led to an increase in monocyclic aromatic hydrocarbons content. As the time on stream was extended to 56 min, the monocyclic aromatic hydrocarbon content obtained with the composite catalyst remained 12.41 % higher than that of the ZSM-5 powder catalyst. These findings validate the potential of the composite catalyst. In essence, this study advances the utilization of spent bleaching clay and introduces a novel concept for ceramic foam fabrication. Furthermore, it contributes to the scaling up of catalytic pyrolysis technology.
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High organic matter preservation during ensiling promotes material conversion and energy output. In this study, the effects of co-ensiling distillers grains and rice straw on methane production was evaluated, as distillers grains are highly acidic. For co-ensiling, distillers grains and rice straw were mixed to produce methane at five carbon/nitrogen (C/N) ratios. RD20 (C/N20) and RD25 (C/N25) were defined as high-distillers-grain groups and other mixed groups as low-distillers-grain groups. The results showed that Lactobacillus was enriched in RD25, with the highest lactic acid content reaching 54.0 g/kg of dry matter. The pH and organic dry matter loss of RD25 were lower than those of low-distillers-grain groups, but the result for lignocellulose degradation rate was reversed. An 8.6% increase in methane yield and 7.9% increase in energy output were achieved in RD25. Ensiling-anaerobic digestion systems of C/N25 provide high organic matter preservation and energy output.
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Oryza , Oryza/metabolismo , MetanoRESUMO
Pyrolysis of nitrogen-containing biomass holds tremendous potential for producing varieties of high value-added products, alleviating energy depletion. Based on the research status about nitrogen-containing biomass pyrolysis, the effect of biomass feedstock composition on pyrolysis products is first introduced from the aspects of elemental analysis, proximate analysis, and biochemical composition. The properties of biomass with high and low nitrogen used in pyrolysis are briefly summarized. Then, with the pyrolysis of nitrogen-containing biomass as the core, biofuel characteristics, nitrogen migration during pyrolysis, the application prospects, unique advantages of nitrogen-doped carbon materials for catalysis, adsorption and energy storage are introduced, as well as their feasibility in producing nitrogen-containing chemicals (acetonitrile and nitrogen heterocyclic) are reviewed. The future outlook for the application of the pyrolysis of nitrogen-containing biomass, specifically, how to realize the denitrification and upgrading of bio-oil, performance improvement of nitrogen-doped carbon materials, as well as separation and purification of nitrogen-containing chemicals, are addressed.
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Nitrogênio , Pirólise , Biomassa , Biocombustíveis , Catálise , Temperatura AltaRESUMO
Lignocellulosic biomass is a rich source of fixed renewable carbon and a promising alternative to fossil sources. However, low effective hydrogen to carbon ratio limits its applications. This work studied the influence of oil-bath co-torrefaction of corncob and waste cooking oil for co-pyrolysis. It was compared with dry torrefaction and hydrothermal wet torrefaction firstly. Residual of oil-bath co-torrefaction were the highest of 97.01 %. Oil-bath co-torrefaction could maximize hydrogen atoms retention in corncob, which has a positive significance for deoxygenation during pyrolysis. Oil-bath co-torrefaction could also reduce the average activation energy required for corncob decomposition, while it was increased with dry torrefaction. Oil-bath co-torrefaction coupled with co-pyrolysis was more suitable for hydrocarbon-rich bio-oil production. Oil-bath co-torrefaction temperature had the greatest influence on bio-oil composition. High pressure promoted formation of the CC double bond and degradation of lignin, which further promoted the formation of monocyclic aromatics in bio-oil.
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Temperatura Alta , Zea mays , Pirólise , Biocombustíveis , Culinária , Biomassa , Carbono , HidrogênioRESUMO
The current high volume of plastic waste, but low recycling rate, has led to environmental pollution and wasted energy. Greenhouse gas CO2 can facilitate thermal cracking to dehydrogenate waste plastics, and has potential value for producing olefins. In this work, the pyrolysis properties of low-density polyethylene (LDPE) were studied by thermogravimetric analysis and Py-GC/MS. The effect of the pyrolysis atmosphere, using N2 or CO2, with various MCM-41 catalyst ratios on pyrolysis product distribution, were investigated. The experimental results show that the olefin selectivity under a N2 atmosphere was from 30.32 % to 44.66 % which increased as the MCM-41 catalyst was increased. Under a CO2 atmosphere, the olefin selectivity reached a maximum of 60.39 %. The Boudouard reaction was also enhanced by the introduction of CO2. The carbon content of the subdivided olefins showed that in CO2, the promotion of C5-C12 olefins was relatively weak when non-catalyzed or at low catalytic ratios, but increased significantly at higher MCM-41 catalyst ratios. With a ratio of LDPE: MCM-41 = 5:4, the CO2 atmosphere showed the greatest promotion of C5-C12 olefins over N2, with an increase of 14.66 % compared to N2, representing a 48.54 % yield of the liquid product. Producing C5-C12 olefins under these conditions maximized energy efficiency. These results show that catalytic pyrolysis of LDPE under a CO2 atmosphere has great potential to produce C5-C12 olefins, which can be used to produce high-value chemicals such as naphtha and gasoline. This opens new opportunities for the chemical recycling of plastic waste.