RESUMO
A combination of ex situ and in situ characterization techniques was used to determine the mechanism of calcium carbonate (CaCO3) formation from calcium hydroxide (Ca(OH)2) dispersions in methanol/water (CH3OH/H2O) systems. Mid-infrared (mid-IR) analysis shows that in the absence of carbon dioxide (CO2) Ca(OH)2 establishes a reaction equilibrium with CH3OH, forming calcium hydroxide methoxide (Ca(OH)(OCH3)) and calcium methoxide (Ca(OCH3)2). Combined ex situ mid-IR, thermogravimetric analysis (TGA), X-ray diffraction (XRD), X-ray absorption spectroscopy and scanning electron microscopy examination of the reaction product formed in the presence of CO2 reveals the formation of calcium dimethylcarbonate (Ca(OCOOCH3)2). This strongly suggests that carbonation takes place by reaction with the Ca(OCH3)2 formed from a Ca(OH)2 and CH3OH reaction. Time-resolved XRD indicates that in the presence of H2O the Ca(OCOOCH3)2 ester releases CH3OH and CO2, forming ACC, which subsequently transforms into vaterite and then calcite. TGA reveals that thermal decomposition of Ca(OCOOCH3)2 in the absence of H2O mainly leads to the reformation of Ca(OCH3)2, but this is accompanied by a significant parallel reaction that releases dimethylether (CH3OCH3) and CO2. CaCO3 is the final product in both decomposition pathways. For CH3OH/H2O mixtures containing more than 50 mol % H2O, direct formation of calcite from Ca(OH)2 becomes the dominant pathway, although the formation of some Ca(OCOOCH3)2 was still evident in the in situ mid-IR spectra of 20 and 40 mol % CH3OH systems. In the presence of ≤20 mol % H2O, hydrolysis of the ester led to the formation of an ACC sol-gel. In both the 90 and 100 mol % CH3OH systems, diffusion-limited ACC â vaterite â calcite transformations were observed. Traces of aragonite were also detected. We believe that this is the first time that these reaction pathways during the carbonation of Ca(OH)2 in a methanolic phase have been systematically and experimentally characterized.
RESUMO
Process analytical technologies are widely used to inform process control by identifying relationships between reagents and products. Here, we present a novel process analytical technology system for operando XAS on multiphase multicomponent synthesis processes based on the combination of a conventional lab-scale agitated reactor with a liquid-jet cell. The preparation of sulfonate-stabilized CaCO3 particles from polyphasic Ca(OH)2 dispersions was monitored in real time by Ca K-edge XAS to identify changes in Ca speciation in the bulk solution/dispersion as a function of time and process conditions. Linear combination fitting of the spectra quantitatively resolved composition changes from the initial conversion of Ca(OH)2 to the Ca(R-SO3)2 surfactant to the ultimate formation of nCaCO3·mCa(R- SO3)2 particles. The system provides a novel tool with strong chemical specificity for probing multiphase synthesis processes at a molecular level, providing an avenue to establishing the relationships between critical quality attributes of a process and the quality and performance of the product.