Enhancing the Thermoelectric and Mechanical Properties of p-Type PbS through Band Convergence and Microstructure Regulation.

While lead sulfide shows notable thermoelectric properties, its production costs remain high, and its mechanical hardness is low, which constrains its commercial viability. Herein, we demonstrate a straightforward and cost-effective method to produce PbS nanocrystals at ambient temperature. By introducing controlled amounts of silver, we achieve p-type conductivity and fine-tune the energy band structure and lattice configuration. Computational results show that silver shifts the Fermi level into the valence band, facilitating band convergence and thereby enhancing the power factor. Besides, excess silver is present as silver sulfide, which effectively diminishes the interface barrier and enhances the Seebeck coefficient. Defects caused by doping, along with dislocations and interfaces, reduce thermal conductivity to 0.49 W m-1 K-1 at 690 K. Moreover, the alterations in crystal structure and chemical composition enhance the PbS mechanical properties. Overall, optimized materials show thermoelectric figures of merit approximately 10-fold higher than that of pristine PbS, alongside an average hardness of 1.08 GPa.

An assessment of how the properties of pyrochar and process thermodynamics impact pyrochar mediated microbial chain elongation in steering the production of medium-chain fatty acids towards n-caproate.

Microbial chain elongation fermentation is an alternative technology for medium-chain fatty acid (MCFA) production. This paper proposed the addition of pyrochar and graphene in chain elongation to improve MCFA production using ethanol and acetate as substrates. Results showed that the yield of, and selectivity towards, C6 n-caproate were significantly enhanced with pyrochar addition. At the optimal mass ratio of pyrochar to substrate of 2 g/g, the maximum n-caproate yield of 13.67 g chemical oxygen demand/L and the corresponding selectivity of 56.8% were obtained; this represents an increase of 115% and 128% respectively as compared with no pyrochar addition. Such improvements were postulated as due to the high electrical conductivity and surface redox groups of pyrochar. The optimal ethanol to acetate molar ratio of 2 mol/mol achieved the highest MCFA yield under pyrochar mediated chain elongation conditions. Thermodynamic calculations modelled an energy benefit of 93.50 kJ/mol reaction for pyrochar mediated n-caproate production.

Emerging bioelectrochemical technologies for biogas production and upgrading in cascading circular bioenergy systems.

Biomethane is suggested as an advanced biofuel for the hard-to-abate sectors such as heavy transport. However, future systems that optimize the resource and production of biomethane have yet to be definitively defined. This paper assesses the opportunity of integrating anaerobic digestion (AD) with three emerging bioelectrochemical technologies in a circular cascading bioeconomy, including for power-to-gas AD (P2G-AD), microbial electrolysis cell AD (MEC-AD), and AD microbial electrosynthesis (AD-MES). The mass and energy flow of the three bioelectrochemical systems are compared with the conventional AD amine scrubber system depending on the availability of renewable electricity. An energy balance assessment indicates that P2G-AD, MEC-AD, and AD-MES circular cascading bioelectrochemical systems gain positive energy outputs by using electricity that would have been curtailed or constrained (equivalent to a primary energy factor of zero). This analysis of technological innovation, aids in the design of future cascading circular biosystems to produce sustainable advanced biofuels.

Anaerobic biotransformation and potential impact of quinoline in an anaerobic methanogenic reactor treating synthetic coal gasification wastewater and response of microbial community.

Phenolic and quinoline compounds are the most primary organic pollutants in coal gasification wastewater (CGW), but the biotransformation of quinoline compounds under methanogenic condition and their potential impacts on treatment performance of CGW are still unclear. Anaerobic biotransformation pathways of quinoline in an upflow anaerobic sludge blanket reactor treating synthetic CGW and response of microbial community were firstly investigated. The result indicated that the degradation of 2(1 H)-quinolinone was the rate-limiting step for the complete conversion of quinoline under methanogenic condition. The reactor performed stably at total phenols concentration of 1000 mg L-1 with a gradual increase of quinoline concentration from 100 to 600 mg L-1. However, the reactor performance was rapidly deteriorated from 98% of COD removal to about 80% at quinoline concentration of 1200 mg L-1 resulting from the accumulation of 2(1 H)-quinolinone. Correspondingly, phenol utilization rate of sludge was significantly reduced by 61% while quinoline utilization rate of sludge was increased by 132%. As phenol degraders, Syntrophorhabdus gradually predominated along with the increase of quinoline concentration, but Syntrophus declined inversely. Compared with syntrophs, acetotrophic methanogens could quickly adapt to quinoline toxicity and tolerate higher quinoline stress. Therefore, anaerobic digestion is an effective method for eliminating quinoline and phenol in CGW.

Influence of particle size distribution on anaerobic degradation of phenol and analysis of methanogenic microbial community.

Sludge morphology considerably affects the mechanism underlying microbial anaerobic degradation of phenol. Here, we assessed the phenol degradation rate, specific methanogenic activity, electron transport activity, coenzyme F420 concentration, and microbial community structure of five phenol-degrading sludge of varying particle sizes (i.e., < 20, 20-50, 50-100, 100-200, and > 200 µm). The results indicated an increase in phenol degradation rate and microbial community structure that distinctly correlated with an increase in sludge particle size. Although the sludge with the smallest particle size (< 20 µm) showed the lowest phenol degradation rate (9.3 mg COD·gVSS-1 day-1), its methanogenic activity with propionic acid, butyric acid, and H2/CO2 as substrates was the best, and the concentration of coenzyme F420 was the highest. The small particle size sludge did not contain abundant syntrophic bacteria or hydrogenotrophic methanogens, but contained abundant acetoclastic methanogens. Moreover, the floc sizes of the different sludge varied in important phenol-degrading bacteria and archaea, which may dominate the synergistic mechanism. This study provides a new perspective on the role of sludge floc size on the anaerobic digestion of phenol.

Hydrogen enrichment as a bioaugmentation tool to alleviate ammonia inhibition on anaerobic digestion of phenol-containing wastewater.

Phenol and ammonia are prevalent toxic pollutants in various industrial wastewaters, but phenol degraders are frequently inhibited by high concentration of ammonia. Hydrogen enrichment was developed to alleviate ammonia inhibition on anaerobic digestion of phenol-containing wastewater. Results indicated that the endurance to ammonia of sludge was improved greatly by hydrogen enrichment at higher ammonia concentration (from 2 to 8 g NH4+-N/L) compared with the control group. Furthermore, phenol utilization rate of sludge was gradually enhanced with the increase of initial hydrogen partial pressure (HPP) at ammonia concentration of 2 g NH4+-N/L and the maximum rate of 199.75 mg/g VSS/d was achieved under 0.8 atm HPP. The maximum SMA of acetate and hydrogen was 0.61 and 0.45 g COD-CH4/g VSS/d, respectively under 0.8 atm HPP. Three hydrogen-consuming pathways including homoacetogenesis, hydrogenotrophic methanogenesis and benzoate generation played the critical roles in enhancing anaerobic digestion of phenol by hydrogen enrichment under high ammonia concentration.

Performance robustness of the UASB reactors treating saline phenolic wastewater and analysis of microbial community structure.

Anaerobic digestion was an important way to remove phenols from saline wastewater; however the anaerobic microorganisms were adversely affected by high concentration of salts. In order to clarify the performance robustness and microbial community structure for anaerobic digestion of saline phenolic wastewater, the UASB reactors were compared to treat phenolic wastewater under saline and non-saline conditions. The saline reactors were operated stably with phenols concentration increasing from 100 to 500mgL-1 at 10g Na+ L-1. The robustness of the saline reactors was weakened at 1000mg phenols L-1 and 10g Na+ L-1. However, the substrate utilization rates (SURs) for phenol, catechol, resorcinol, hydroquinone, and the specific methanogenic activity (SMA) of sludge were decreased by 95%, 85%, 97%, 78%, and 68%, respectively with phenols concentration enhancing from 1000 to 2000mgL-1. Moreover, the SURs for phenol, catechol, resorcinol, hydroquinone, and the SMA of sludge were reduced by 32%, 65%, 74%, 45%, and 59%, respectively with Na+ concentration increasing from 10 to 20gL-1, in comparison with the values obtained at 10g Na+ L-1 and 1000mg phenols L-1. Finally, the analysis of microbial community structure demonstrated that phenols degraders were less tolerant to high concentrations of Na+ and phenols than methanogens.