Constructing Two Cu-Modified Organophosphomolybdates from a Nanocluster to a One-Dimensional Chain for Boosted Visible-Light-Driven Hydrogen Production.

Photocatalytic decomposition of water to produce hydrogen H2 is an ideal way to solve energy and environmental problems, and the development of highly efficient polyoxometalate catalysts for photocatalytic hydrogen production has attracted wide attention. Herein, two Cu-modified Strandberg-type organophosphomolybdates were successfully synthesized, [Cu(C8H7N3)(H2O)2]2[(C6H5PO3)2Mo5O15]·4H2O (1) and [Cu(phen)(H2O)][Cu(phen)(H2O)2][(C6H5PO3)2Mo5O15]·2H2O (2) ([(C6H5P)2Mo5O21]Cu2) (C8H7N3 = 2-(1H-pyrazol-3-yl)pyridine, phen = 1,10-phenanthroline). Two Strandberg-type organophosphomolybdates can be used for visible-light-driven hydrogen production. Also, compound 2 exhibits an H2 production rate of 6399 µmol g-1 h-1 after 8 h light exposure in the presence of photosensitization agent [Ir(dtbbpy)(ppy)2][PF6] and TEOA. In addition, cyclic tests showed that compound 2 could be recycled four times without a significant reduction in catalytic performance. This work offers fresh insight into the development of novel polyoxometalates for efficient hydrogen evolution.

A reduced polyoxometalate-encapsulated organo cobalt modified phosphate framework for improving photocatalytic reduction of CO2.

A reduced polyoxometalate-based organo-metallophosphate (MOPO) framework formulated as [Co4(PO4)(C7H8N4)6](PWVI10WV2O40) (Co-PO4-PW12) with an ultra-high CO production rate of 13 676 µmol g-1 h-1 has been presented through photocatalytic CO2 reduction investigations.