Lithography-Free Nanofabrication on Various Semiconductors by the Codeposition Etching Technique.

Nano-/microstructures can be formed with the aid of small amounts of impurities during deposition with noble gas plasma irradiation, which is referred to as codeposition etching. This can be a new method for lithography-free semiconductor nanofabrication. Here, the codeposition etching method was employed with argon plasma and molybdenum (Mo) impurities on various semiconductors. Structures can be formed only on substrates that have a lower sputtering yield than the seed impurity. The density, area, and height of structures are related to both the impurity deposition rate and the substrate material. Moreover, two mechanisms of impurity nucleation are proposed according to time dependence results for the formation of the structures.

Verdet constant dispersion of magnesium fluoride for deep-ultraviolet and vacuum-ultraviolet Faraday rotators.

The Verdet constant dispersion in magnesium fluoride (MgF2) crystals was evaluated over a wavelength range of 190-300 nm. The Verdet constant was found to be 38.7 rad/(T·m) at a wavelength of 193 nm. These results were fitted using the diamagnetic dispersion model and the classical Becquerel formula. The fitted results can be used for the designing of suitable Faraday rotators at various wavelengths. These results indicate the possibility of using MgF2 as Faraday rotators not only in deep-ultraviolet regions, but also in vacuum-ultraviolet regions owing to its large bandgap.

Fabrication of tungsten-based optical diffuser using fiberform nanostructure via efficient plasma route.

Optical diffusion is an essential process used to manage photons in a wide range of photoelectric systems. This work proposes an approach to fabricate novel optical diffusers by a plasma-processing technique, using fiberform nanostructures formed by helium plasma irradiation and subsequent annealing. After an annealing procedure in the air for oxidation, the optical properties and the light-diffusing abilities of these nanostructured thin films were studied. In addition to the morphology analysis and total transmittance measurement, the diffusion efficiency of the optical diffusers was analyzed using a transmitted scatter distribution function (TDF). It was revealed that the diffusion efficiency of a device with an irradiation time of 30 minutes could reach 97%. The results demonstrate the potential of these nanostructured optical diffusers for various photoelectric applications.

Tb,Y:SrF2 crystal for efficient laser operation in the visible spectral region.

A Tb,Y:SrF2 crystal with high optical quality is grown using the temperature gradient technique. The spectroscopic and laser properties of the crystal in the visible spectral region are studied. A fluorescence lifetime of 5.6 ms is measured from the crystal, which is beneficial for laser operation with a low threshold. A continuous-wave Tb,Y:SrF2 laser delivers an output power of 259 mW at 545 nm, with a slope efficiency of 35.2%. To the best of the authors' knowledge, this is the first report on a Tb-doped SrF2 laser and represents the highest output power for visible alkaline-earth fluoride lasers. The limitations for power scaling are discussed.

Specific methylation of (11R)-carlactonoic acid by an Arabidopsis SABATH methyltransferase.

MAIN CONCLUSION: An Arabidopsis S-adenosyl-L-methionine-dependent methyltransferase belonging to the SABATH family catalyzes the specific carboxymethylation of (11R)-carlactonoic acid. Methyl carlactonoate (MeCLA), found in Arabidopsis (Arabidopsis thaliana) as a non-canonical strigolactone (SL), may be a biosynthetic intermediate of various non-canonical SLs and biologically active as a plant hormone. MeCLA is formed from carlactonoic acid (CLA), but the methyltransferases (MTs) converting CLA to MeCLA remain unclear. Previous studies have demonstrated that the carboxymethylation of acidic plant hormones is catalyzed by the same protein family, the SABATH family (Wang et al. in Evol Bioinform 15:117693431986086. https://doi.org/10.1177/1176934319860864 , 2019). In the present study, we focused on the At4g36470 gene, an Arabidopsis SABATH MT gene co-expressed with the MAX1 gene responsible for CLA formation for biochemical characterization. The recombinant At4g36470 protein expressed in Escherichia coli exhibited exclusive activity against naturally occurring (11R)-CLA among the substrates, including CLA enantiomers and a variety of acidic plant hormones. The apparent Km value for (11R)-CLA was 1.46 µM, which was relatively smaller than that of the other Arabidopsis SABATH MTs responsible for the carboxymethylation of acidic plant hormones. The strict substrate specificity and high affinity of At4g36470 suggested it is an (11R)-CLA MT. We also confirmed the function of the identified gene by reconstructing MeCLA biosynthesis using transient expression in Nicotiana benthamiana. Phylogenetic analysis demonstrated that At4g36470 and its orthologs in non-canonical SL-producing plants cluster together in an exclusive clade, suggesting that the SABATH MTs of this clade may be involved in the carboxymethylation of CLA and the biosynthesis of non-canonical SLs.

Efficient diode-pumped Er:YAP master-oscillator power-amplifier system for laser power improvement at 2920†nm.

We report on the first demonstration of laser-diode-pumped master-oscillator power-amplifier (MOPA) system based on Er-doped bulk material working at 2920 nm. The relaxation oscillation at the beginning of the laser pulse from the Er:YAlO3 (YAP) oscillator was suppressed effectively when the pump frequency was increased to 140 Hz, as a result of the establishment of a three-level system. In the amplifier, the small signal gain of the Er:YAP strongly depends on pump duration and repetition frequency, and can reach the upper limit of parasitic oscillation. Further, 25.5 mJ of output pulse energy has been achieved from the amplifier at 150 Hz frequency (2.2 ms pump duration), with over 32% of optical-to-optical efficiency. Further improvement of the amplification ability of the MOPA system was discussed.

Highly efficient Er:YAP laser with 6.9 W of output power at 2920†nm.

We report on the efficient high-power operation of a laser-diode-pumped Er3+-doped yttrium aluminum perovskite (Er:YAP) laser in the 3 µm spectral region at room temperature. 6.9 W of continuous-wave (CW) output power was obtained at 2920 nm. The slope efficiency was as high as 30.6% with respect to the absorbed pump power, which is close to the quantum defect limit (33.4%). To the best of our knowledge, this is the highest CW output power generated from 3 µm Er3+-doped solid state lasers at room temperature. Furthermore, our analysis has shown that more than 10 W of output power based on Er:YAP is possible by further mitigating the thermal lens effect.

Efficient Pr:YAlO3 lasers at 622†nm, 662†nm, and 747†nm pumped by semiconductor laser at 488†nm.

We report laser operation of Pr:YAlO3 pumped by a frequency-doubled optically pumped semiconductor laser. Continuous-wave laser oscillations at around 622 nm, 662 nm, and 747 nm were demonstrated in plano-concave or/and plano-plano cavities. The maximum slope efficiencies were found to be 37%, 35%, and 59%, respectively, which are record-high values for Pr:YAlO3 lasers. Furthermore, lasing at 622 nm was demonstrated at room temperature for the first time to the best of our knowledge.

Compact deep ultraviolet frequency-doubled Tb:LiYF4 lasers at 272 nm.

A new laser system has been developed to generate coherent deep ultraviolet (DUV) radiation at 272 nm. The DUV lasers were produced via intra-cavity frequency doubling of the Tb3+:LiYF4 lasers emitting fundamentally at 544 nm. Continuous-wave (cw) and Q-switched operations were performed with a type I phase-matched ß-BaB2O4 nonlinear crystal. The cw operation produces 127 mW of averaged DUV output power. Passive Q-switched operation was realized by using Co2+:MgAl2O4 saturable absorbers. At an initial transmittance (excluding Fresnel reflections) of 99% at 544 nm, stable pulsed output at 272 nm with maximum single-pulse energy of 7.6 µJ and peak power of 6.1 W was obtained. Furthermore, by employing a smaller initial transmittance of 94.7%, we achieved maximum averaged DUV output power of 277 mW. The statistically averaged single-pulse DUV energy and peak power were estimated to be around 100 µJ and 320 W, respectively, which indicates great potential for this DUV laser system toward high energy and peak power.

40 kHz, 20 ns acousto-optically Q-switched 4 µm Fe:ZnSe laser pumped by a fluoride fiber laser.

An actively Q-switched mid-infrared Fe:ZnSe laser pumped by a continuous wave fluoride fiber laser has been developed. Stable operation with a pulse duration of 20 ns and a repetition rate of 40 kHz at 4 µm was achieved. The maximum peak power was 1.1 kW. The high-repetition rate, high-peak power nanosecond pulsed laser, which has been created for the first time, to the best of our knowledge, in an actively Q-switched Fe:ZnSe laser, should prove a suitable light source for laser processing and molecular sensing.

Verdet constant of potassium terbium fluoride crystal as a function of wavelength and temperature.

Potassium terbium fluoride KTb3F10 (KTF) crystal is a promising magneto-active material for creating multi-kilowatt average-power Faraday isolators operating at the visible and near-infrared wavelengths. Nevertheless, the key material's parameter needed for the design of any Faraday isolator-the Verdet constant, has not been comprehensively investigated yet. In this Letter, we report on measurement of the Verdet constant of the KTF crystal for wavelengths between 600 and 1500 nm and for temperatures ranging from 15 to 295 K. A suitable model for the Verdet constant as a function of wavelength and temperature has been developed and may be conveniently used for optimal design of KTF-based high-average-power Faraday isolators.

Magneto-optic pyrochlore ceramics of Tb2Hf2O7 for Faraday rotator.

In the first demonstration of the Faraday effect in an optical-grade Tb2Hf2O7 (THO) ceramic, its optical properties and the Verdet constant's wavelength dependence were evaluated at room temperature. The transmittance loss of this material was equally low as for the terbium gallium garnet, a well-known magneto-optic material. The Verdet constant at 1064 nm was 50.4 rad/Tm, which was 1.4 times greater than that of the terbium gallium garnet. THO ceramics show great potential for use in Faraday devices in near-infrared laser applications.

2.92-µm high-efficiency continuous-wave laser operation of diode-pumped Er:YAP crystal at room temperature.

Mid-infrared lasers have attracted attention for application to the fields of medicine and industry. In this study, we demonstrate continuous-wave laser operation of a diode-pumped 5 at % Er-doped YAlO3 (YAP) single-crystal lasing at 2.92 µm with near-quantum-defect slope efficiency at room temperature. A high slope efficiency of 31% is achieved with a maximum output power of 0.674 W for a cavity length of 18 mm and an output coupler transmittance of 2.5%. This efficiency is 94% of the theoretical quantum-defect efficiency. Our results indicate that Er:YAP lasers can potentially be utilized to realize high-power mid-IR lasing.

Optimization of laser emission at 2.8 µm by Er:Lu2O3 ceramics.

We have demonstrated the continuous-wave operation of a highly efficient 2.8 µm Er-doped Lu2O3 ceramic laser at room temperature. An Er:Lu2O3 ceramic with a doping concentration of 11 at.% afforded a slope efficiency of 29% and an output power of 2.3 W with pumping at 10 W. To our knowledge, these are the highest slope efficiency and output power obtained to date for an Er:Lu2O3 ceramic laser at 2.8 µm. In addition, we prepared ceramics with various doping concentrations and determined their emission cross sections by fluorescence lifetime measurements and emission spectroscopy.

Sapphire/Nd:YAG composite by pulsed electric current bonding for high-average-power lasers.

As a new bonding technique for high-power laser optics, pulsed electric current bonding (PECB) of sapphire and Nd:YAG ceramics was demonstrated. The optical properties of the composite were measured, and its microstructure at the interface and laser performance was analyzed. The optical transmittance was equal to the theoretical value, and the transmitted wavefront was λ/3 (λ=633 nm); both are appropriate values for laser applications. The microstructural analysis indicated an absence of scattering sources such as pores or non-contact points at the sapphire/Nd:YAG interface, and the distance of yttrium diffusion into the sapphire was theoretically expected to be less than 10 nm, much smaller than that of ceramic materials bonded by conventional thermal diffusion techniques. The laser performance of the composite material showed an 18% higher output power with almost the same threshold power and slope efficiency as a Nd:YAG ceramic due to the sapphire-conductive cooling effect. This new PECB technique for different transparent materials has the potential to bond large aperture optical materials over 100 mm in diameter and could be especially effective for fabricating active laser media for high-average-power lasers having both high-pulse energy and high repetition rates.

Efficient continuous wave and quasi-continuous wave operation of a 2.8 µm Er:Lu2O3 ceramic laser.

We have demonstrated a highly efficient 2.8 µm Er-doped Lu2O3 ceramic laser and investigated the lasing dynamics by time-resolved spectroscopy. During room-temperature continuous wave operation, a slope efficiency of 22% was achieved with a high-quality transparent ceramic. To our knowledge, this is the highest slope efficiency obtained by an Er:Lu2O3 ceramic laser. In addition, an output peak power of 1.2 W was obtained during quasi-continuous wave operation. Time-resolved spectroscopy showed that the emission wavelengths exhibited a red shift from 2715 to 2845 nm, which indicated that continuous wave operation may be possible at 2740 and 2845 nm.

Cryogenically cooled CeF3 crystal as media for high-power magneto-optical devices.

The thermally induced depolarization and Verdet constant of CeF3 crystals-their most important characteristics-have been studied in the 79-293 K temperature range. It has been found that thermal effects reduce substantially upon cooling down to 79 K and the Verdet constant grows in inverse proportion to the temperature. It was shown that CeF3 crystals are not inferior to TGG as a medium for Faraday isolators, including cryogenic ones.

Faraday rotator based on TSAG crystal with <001> orientation.

A Faraday isolator (FI) for high-power lasers with kilowatt-level average power and 1-µm wavelength was demonstrated using a terbium scandium aluminum garnet (TSAG) with its crystal axis aligned in the <001> direction. Furthermore, no compensation scheme for thermally induced depolarization in a magnetic field was used. An isolation ratio of 35.4 dB (depolarization ratio γ of 2.9 × 10-4) was experimentally observed at a maximum laser power of 1470 W. This result for room-temperature FIs is the best reported, and provides a simple, practical solution for achieving optical isolation in high-power laser systems.

Wavelength dependence of magneto-optic properties of terbium gallium garnet ceramics.

The wavelength dependence of magneto-optic properties of TGG ceramics, including the Verdet constant, has been investigated experimentally. The previously obtained Verdet constant of 36.4 rad/Tm for 1064 nm wavelength and 139.6 rad/Tm for 633 nm are in good agreement with presented white light measurements . The comparison with previously reported Verdet constant and absorption coefficient values for TGG single crystal has shown very similar results. These results lead to the conclusion that TGG ceramics is a very good alternative to TGG single crystal and is a powerful approach for realizing large-aperture optical isolators which are required in high-average-power laser systems.

Terbium gallium garnet ceramic Faraday rotator for high-power laser application.

A terbium gallium garnet (TGG) ceramic Faraday rotator (FR) with an isolation ratio of 33 dB was demonstrated at a laser radiation power of 257 W. This FR can be equipped with a large optical aperture by using ceramics technology to prevent laser damage at high-energy pulse operation. The thermal lens of a 257 W laser with a beam diameter of 2.6 mm had a focal length of 9.5 m, which is easily corrected using a spherical lens to suppress the undesirable effects of thermal lensing. The rotation angle of the FR was stabilized by water cooling. The results indicate that the TGG-ceramic-based FR is suitable for high-energy laser systems with high repetition rates.