RESUMO
A highly efficient and operationally simple method for the synthesis of ß-sulfinyl alkenylsulfones through a BF3·OEt2-promoted reaction of alkynes and sodium sulfinates is developed, successfully avoiding the complicated anhydrous treatment before the reaction and greatly simplifying the reaction conditions. As a facile and selective route to the targets, it features good functional group compatibility, mild conditions, easily available starting materials, and excellent yields. Notably, the trace water in solvent plays a key role in promoting the reaction, which provides a more practical pathway for the utilization of the BF3·OEt2 catalytic system.
RESUMO
Intensifying climate change significantly impacts residential electricity consumption, especially in developing countries, such as China, that are experiencing rapid income growth. By combining meteorological and monthly household consumption survey data, this study explores the response function of residential electricity consumption to temperature in China from a micro perspective. Future residential electricity demands and related CO2 emissions are then forecast under different climate scenarios. Overall, the response function is U-shaped, and one additional day above 34 °C will increase monthly residential electricity consumption by 2.11%. Global warming will more likely increase the electricity burden on low-income groups. There will be notable seasonal changes in electricity demand in the future, and the largest increase will occur in August. The total demand for residential electricity caused by temperature change will show a fluctuating growth trend, from 0.8% and 1% in 2025 to 2% and 2.9% in 2060 under the RCP4.5 scenario and RCP8.5 scenario, respectively; meanwhile, this demand will be accompanied by a cumulative increase in carbon dioxide emissions.