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1.
J Adolesc ; 96(5): 1102-1115, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-38509447

RESUMO

INTRODUCTION: Left-behind adolescents are vulnerable to depressive symptoms under the context of parent-adolescent separation. However, limited knowledge is available regarding left-behind adolescents' depression trajectory and the protective resources against it. The aim of this longitudinal study was to investigate the depression trajectory and its association with parent-adolescent separation (left-behind status, age of separation and duration of separation) and parent-adolescent cohesion (father-adolescent cohesion, mother-adolescent cohesion) among left-behind adolescents. METHODS: The participants were 1,107 left-behind adolescents (Mage = 13.23 ± 0.86 years at T1; 45.17% girls; 38.48% both-parent migrant adolescents, 61.52% father-only migrant adolescents) from two rural areas of Shandong Province in China, who were participated in assessment at three time points with 6 months apart from November 2014 to November 2015. RESULTS: The results indicated that the trajectory of left-behind adolescents' depression symptoms showed a decreasing trend. Both-parent migrant adolescents reported a higher initial level of depressive symptoms than father-only migrant adolescents. Duration of separation positively predicted the initial level of left-behind adolescents' depressive symptoms. Mother-adolescent cohesion negatively predicted the initial level and positively predicted the change rate of left-behind adolescents' depressive symptoms. Moreover, mother-adolescent and father-adolescent cohesion buffered the negative effect of parent-adolescent separation on the initial level of left-behind adolescents' depressive symptoms. CONCLUSIONS: These findings highlight the protective role of parent-adolescent cohesion for left-behind adolescents, having important implications for interventions targeted toward mitigating the detrimental influence of parent-adolescent separation on left-behind adolescents' depression trajectory.


Assuntos
Depressão , Relações Pais-Filho , Humanos , Adolescente , Feminino , Masculino , Depressão/psicologia , Depressão/epidemiologia , China , Estudos Longitudinais , Migrantes/psicologia , Migrantes/estatística & dados numéricos , Separação da Família
2.
J Youth Adolesc ; 53(9): 2108-2120, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-38750313

RESUMO

Childhood separation caused by parental migration increases the risk of suffering depressive symptoms among college students. However, most studies in this field have focused on environmental factors and largely ignored the role of physiological reactivity to stress (e.g., parasympathetic nervous system activity) in this process. The present study examined the long-term effects of the parent-child separation experience on depressive symptoms in college students, and explored the moderating role of parasympathetic nervous system (PNS) activity in these relationships. The participants were 242 college students (Mage = 18.74 years, SD = 0.79; 32.2% male), including 149 college students who experienced parent-child separation and 93 college students without this experience. Using a three-wave longitudinal design, participants completed the measures of the parent-child separation experience, PNS activity (measured via respiratory sinus arrhythmia, RSA), and depressive symptoms at Time 1 (T1, before the COVID-19 lockdown). Their depressive symptoms were again measured at Time 2 (T2, during the COVID-19 lockdown) and Time 3 (T3, after the COVID-19 lockdown). The results showed that the parent-child separation experience positively predicted depressive symptoms in college students at three time points. Moreover, the parent-child separation experience positively predicted depressive symptoms at T2 among males with less and average RSA suppression but positively predicted depressive symptoms at T2 among females with greater RSA suppression. These findings indicate a long-term effect of parent-child separation on depressive symptoms in college students that still exist after they entered university, and that the effect varies depending on PNS activity and gender.


Assuntos
Depressão , Sistema Nervoso Parassimpático , Estudantes , Humanos , Masculino , Feminino , Sistema Nervoso Parassimpático/fisiopatologia , Adolescente , Estudos Longitudinais , Depressão/psicologia , Estudantes/psicologia , Adulto Jovem , Arritmia Sinusal Respiratória/fisiologia , COVID-19/psicologia , Relações Pais-Filho , Universidades
3.
J Youth Adolesc ; 2024 Sep 25.
Artigo em Inglês | MEDLINE | ID: mdl-39322858

RESUMO

Although numerous studies have explored the causes and consequences of intrinsic and extrinsic life goals, the developmental trend of life goals during adolescence has not been well understood. To address this research gap, this study explored the developmental changes of the pursuit of intrinsic and extrinsic goals during early, middle, and late adolescence, and examined the relation between life goals and internalizing/externalizing problems from a developmental perspective. A total of 4703 Chinese adolescents from primary (N = 1819, 47.8% girls, Mage T1 = 9.34, SDage T1 = 0.58), middle (N = 1525, 47.5% girls, Mage T1 = 12.47, SDage T1 = 0.59), and high school (N = 1646, 51.9% girls, Mage T1 = 15.45, SDage T1 = 0.65) participated in this two-year, three-wave longitudinal study. The results revealed that the pursuit of intrinsic goals increased among primary school students, but decreased among middle and high school students. Conversely, the pursuit of extrinsic goals exhibited a consistent increase among adolescents in primary, middle, and high school. Girls have higher initial levels of intrinsic goals than boys in primary school, and boys' intrinsic goals declined faster than girls' in middle school. Additionally, the initial level and developmental rate of intrinsic goals among three developmental stages were significantly associated with internalizing/externalizing problems, with lower initial level, slower growth rate, and faster decline rate being associated with more internalizing and externalizing problems. The significant association between the initial level and developmental rate of extrinsic goals and internalizing/externalizing problems were mainly observed among late adolescents, with higher initial level and growth rate being associated with more internalizing and externalizing problems. These findings delineate the differences in developmental trends between intrinsic and extrinsic goals, underscore the robust relation between intrinsic goals and internalizing/externalizing problems, and figure out the development-stage differences in the relation between extrinsic goals and internalizing/externalizing problems.

4.
Angew Chem Int Ed Engl ; : e202412853, 2024 Aug 29.
Artigo em Inglês | MEDLINE | ID: mdl-39207269

RESUMO

The practical deployment of Zn-ion batteries faces challenges such as dendrite growth, side reactions and cathode dissolution in traditional electrolytes. Here, we develop a highly conductive and dynamically ion-sieved electrolyte to simultaneously enhance the Zn metal reversibility and suppress the cathode dissolution. The dynamic ion screen at the electrode/electrolyte interface is achieved by numerous pyrane rings with a radius of 3.69 Å, which can selectively facilitate the plating/stripping and insertion/extraction process of [Zn(H2O)6]2+ and Zn2+ on the anode and cathode surfaces. As a proof of concept, Zn//Zn symmetric cells deliver exceptional cyclic stability for over 6,800 h and ultrahigh cumulative plated capacity of 1.95 Ah cm-2. Zn//Na2Mn3O7 cells exhibit satisfactory cycling performance with capacity retention of 82.7 % after 4,000 cycles, and the assembled pouch cells achieve excellent stability and durability. This work provides valuable insights into the development of electrolytes aimed at enhancing the interface stability of aqueous batteries.

5.
Angew Chem Int Ed Engl ; 63(17): e202401996, 2024 Apr 22.
Artigo em Inglês | MEDLINE | ID: mdl-38445364

RESUMO

Metal-organic frameworks (MOFs) show wide application as the cathode of aqueous zinc-ion batteries (AZIBs) in the future owning to their high porosity, diverse structures, abundant species, and controllable morphology. However, the low energy density and poor cycling stability hinder the feasibility in practical application. Herein, an innovative strategy of organic/inorganic double electroactive sites is proposed and demonstrated to obtain extra capacity and enhance the energy density in a manganese-based metal-organic framework (Mn-MOF-74). Simultaneously, its energy storage mechanism is systematically investigated. Moreover, profiting from the coordination effect, the Mn-MOF-74 features with stable structure in ZnSO4 electrolyte. Therefore, the Zn/Mn-MOF-74 batteries exhibit a high energy density and superior cycling stability. This work aids in the future development of MOFs in AZIBs.

6.
Angew Chem Int Ed Engl ; 63(44): e202410568, 2024 Oct 24.
Artigo em Inglês | MEDLINE | ID: mdl-39083345

RESUMO

A ladder-type rigid-coplanar polymer with highly ordered molecular arrangement has been designed via a covalent cycloconjugation conformational strategy. Benefitting from the extended π-electron delocalization in the highly aromatic ladder-type polymeric backbone, the prepared polymer exhibits fast intra-chain charge transport along the polymeric chain, realizing extraordinary proton-storage capability in aqueous proton batteries.Affordable and safe aqueous proton batteries (APBs) with unique "Grotthuss mechanism," are very significant for advancing carbon neutrality initiatives. While organic polymers offer a robust and adaptable framework that is well-suited for APB electrodes, the limited proton-storage redox capacity has constrained their broader application. Herein, a ladder-type polymer (PNMZ) has been designed via a covalent cycloconjugation conformational strategy that exhibits optimized electronic structure and fast intra-chain charge transport within the high-aromaticity polymeric skeleton. As a result, the polymer exhibits exceptional proton-storage redox kinetics, which are evidenced by in-operando monitoring techniques and theoretical calculations. It achieves a remarkable proton-storage capacity of 189 mAh g-1 at 2 A g-1 and excellent long-term cycling stability, with approximately 97.8 % capacity retention over 10,000 cycles. Finally, a high-performance all-polymer APB device has been successfully constructed with a desirable capacity retention of 99.7 % after 6,000 cycles and high energy density of 56.3 Wh kg-1.

7.
Acta Pharmacol Sin ; 44(9): 1790-1800, 2023 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-37142683

RESUMO

Meteorin-like (Metrnl) is a novel secreted protein with various biological activities. In this study, we investigated whether and how Metrnl regulated skin wound healing in mice. Global Metrnl gene knockout mice (Metrnl-/-) and endothelial cell-specific Metrnl gene knockout mice (EC-Metrnl-/-) were generated. Eight-mm-diameter full-thickness excisional wound was made on the dorsum of each mouse. The skin wounds were photographed and analyzed. In C57BL/6 mice, we observed that Metrnl expression levels were markedly increased in skin wound tissues. We found that both global and endothelial cell-specific Metrnl gene knockout significantly retarded mouse skin wound healing, and endothelial Metrnl was the key factor affecting wound healing and angiogenesis. The proliferation, migration and tube formation ability of primary human umbilical vein endothelial cells (HUVECs) were inhibited by Metrnl knockdown, but significantly promoted by addition of recombinant Metrnl (10 ng/mL). Metrnl knockdown abolished the proliferation of endothelial cells stimulated by recombinant VEGFA (10 ng/mL) but not by recombinant bFGF (10 ng/mL). We further revealed that Metrnl deficiency impaired VEGFA downstream AKT/eNOS activation in vitro and in vivo. The damaged angiogenetic activity in Metrnl knockdown HUVECs was partly rescued by addition of AKT activator SC79 (10 µM). In conclusion, Metrnl deficiency retards skin wound healing in mice, which is related to impaired endothelial Metrnl-mediated angiogenesis. Metrnl deficiency impairs angiogenesis by inhibiting AKT/eNOS signaling pathway.


Assuntos
Neovascularização Fisiológica , Proteínas Proto-Oncogênicas c-akt , Animais , Humanos , Camundongos , Movimento Celular , Proliferação de Células , Células Endoteliais da Veia Umbilical Humana/metabolismo , Camundongos Endogâmicos C57BL , Proteínas Proto-Oncogênicas c-akt/metabolismo , Transdução de Sinais , Cicatrização
8.
BMC Musculoskelet Disord ; 24(1): 899, 2023 Nov 18.
Artigo em Inglês | MEDLINE | ID: mdl-37980527

RESUMO

OBJECTIVE: The purpose of this study was to compare the therapeutic effects of Kirschner wire fixation and external fixation in the treatment of proximal humeral fractures in older children and adolescents. METHODS: A retrospective analysis was performed on the clinical data of older children and adolescents who underwent surgery at our institution for proximal humeral fractures between April 2014 and May 2022. One group (n = 28) underwent fracture reduction and Kirschner wire fixation, and the other group (n = 23) underwent external fixation. During the follow-up, the differences in shoulder joint function between the two groups were compared by analysing Quick Disabilities of the Arm, Shoulder, and Hand (Quick DASH) and Constant-Murley scores. Postoperative complications were also recorded. RESULTS: The operation time of the Kirschner wire group was shorter than that of the external fixation group (69.07 ± 11.34 min vs. 77.39 ± 15.74 min, P = 0.33). The time to remove the fixator in the external fixation group was shorter than that in the Kirschner wire group (6.74 ± 1.57 vs. 7.61 ± 1.22, P = 0.032). The Quick DASH score and Constant-Murley score of the patients in the external fixation group were significantly better than those in the Kirschner wire group at 3 months after surgery (5.63 ± 4.33 vs. 8.93 ± 6.40, P = 0.040; 93.78 ± 2.43 vs. 91.75 ± 2.15, P = 0.003). There was no significant difference in the Quick DASH score or Constant-Murley score between the patients in the external fixator group and those in the Kirschner wire group at 9 months after the operation (2.77 ± 3.14 vs. 3.17 ± 3.68, P = 0.683; 97.39 ± 1.80 vs. 96.57 ± 2.15, P = 0.152). The most common complication of the two groups was pin tract infection. The incidence rate of infection was higher in the external fixation group than that in the Kirschner wire group (9 vs. 4, P = 0.043). CONCLUSION: Both Kirschner wire fixation and external fixation of N-H III and IV proximal humeral fractures in older children and adolescents produce good outcomes. External fixation is a preferred surgical treatment option for paediatric proximal humerus fractures because early mobilization of the affected limb can be realized.


Assuntos
Fraturas do Úmero , Fraturas do Ombro , Humanos , Criança , Adolescente , Fios Ortopédicos , Fixação de Fratura/efeitos adversos , Fixadores Externos , Fixação Interna de Fraturas/efeitos adversos , Estudos Retrospectivos , Fraturas do Ombro/diagnóstico por imagem , Fraturas do Ombro/cirurgia , Resultado do Tratamento , Fraturas do Úmero/cirurgia
9.
Sensors (Basel) ; 23(8)2023 Apr 18.
Artigo em Inglês | MEDLINE | ID: mdl-37112417

RESUMO

Aiming at the problem of fast divergence of pure inertial navigation system without correction under the condition of GNSS restricted environment, this paper proposes a multi-mode navigation method with an intelligent virtual sensor based on long short-term memory (LSTM). The training mode, predicting mode, and validation mode for the intelligent virtual sensor are designed. The modes are switching flexibly according to GNSS rejecting situation and the status of the LSTM network of the intelligent virtual sensor. Then the inertial navigation system (INS) is corrected, and the availability of the LSTM network is also maintained. Meanwhile, the fireworks algorithm is adopted to optimize the learning rate and the number of hidden layers of LSTM hyperparameters to improve the estimation performance. The simulation results show that the proposed method can maintain the prediction accuracy of the intelligent virtual sensor online and shorten the training time according to the performance requirements adaptively. Under small sample conditions, the training efficiency and availability ratio of the proposed intelligent virtual sensor are improved significantly more than the neural network (BP) as well as the conventional LSTM network, improving the navigation performance in GNSS restricted environment effectively and efficiently.

10.
Nano Lett ; 22(3): 1198-1206, 2022 Feb 09.
Artigo em Inglês | MEDLINE | ID: mdl-35080406

RESUMO

Two-dimensional conductive metal-organic frameworks (2D CMOFs) can be regarded as high-performance electrode substances owing to their rich hierarchical porous architecture and excellent electrical conductivity. However, the sluggish kinetics behavior of electrodes within the bulk structure restricts their advances in energy storage fields. Herein, a series of graphene-based mixed-dimensional composite aerogels are achieved by incorporating the 2D M-tetrahydroxy-1,4-quinone (M-THQ) (M = Cu, Cu/Co, or Cu/Ni) into CNTs@rGO aerogel electrodes using a 3D-printing direct ink writing (DIW) technique. Benefiting from the high capacity of M-THQ and abundant porosity of the 3D-printed microlattice electrodes, an excellent capacitive performance of the M-THQ@CNTs@rGO cathodes is achieved based on the fast electron/ion transport. Furthermore, the 3D-printed lithium-ion hybrid supercapacitor (LIHCs) device assembled with Cu/Co-THQ@CNTs@rGO cathode and C60@VNNWs@rGO anode delivers a remarkable electrochemical performance. More importantly, this work manifests the practicability of printing 2D CMOFs electrodes, which provides a substantial research basis for 3D printing energy storage.

11.
J Youth Adolesc ; 52(6): 1301-1312, 2023 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-37067641

RESUMO

Parent-child separation caused by parental migration could have adverse effects on individuals' emotional adaptation. However, research on this topic is limited in its focus on childhood or adolescence samples and solely environmental factors, and less is known about how positive environmental factors, biological factors and parent-child separation experience interact to influence emotional adaptation in emerging adulthood. The present study addressed these issues by investigating the relationships between parent-child cohesion and positive/negative affect, and examining the moderating roles of sympathetic nervous system activity (measured by skin conductance level reactivity, SCLR) and parent-child separation experience in the relationships. Data from 248 college students (Mage = 18.91 years, SD = 0.70; 32.3% males), including 158 college students with parent-child separation experience and 90 college students without parent-child separation experience. The results showed that parent-child cohesion predicted college students' positive/negative affect. Moreover, the moderating role of SCLR on the relationship between father-child cohesion and negative affect varied with parent-child separation experience. Specifically, father-child cohesion negatively predicted negative affect when SCLR was lower for college students with parent-child separation experience, while negatively predicted negative affect when SCLR was higher for college students without parent-child separation experience. These results indicate that the interaction pattern of Biological × Environmental predicting college students' positive/negative affect varies across parent-child separation status in childhood or adolescence.


Assuntos
Relações Pais-Filho , Estudantes , Masculino , Adolescente , Humanos , Adulto , Adulto Jovem , Feminino , Estudantes/psicologia , Ajustamento Emocional , Sistema Nervoso Simpático , Afeto
12.
Small ; 18(38): e2203061, 2022 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-35986433

RESUMO

Zinc (Zn) metal possesses broad prospects as an anode for aqueous zinc-ion batteries (AZIBs) due to its considerable theoretical capacity of 820 mAh g-1 . However, the Zn anode suffers from dendrite growth and side reactions during Zn stripping/plating. Herein, a Prussian blue analog of copper hexacyanoferrate (CuHCF) with a 3D open structure and rich polar groups (CN) is coated on Zn foil as a solid-state electrolyte (SSE) protection layer to protect the Zn anode. The CuHCF protection layer possesses low activation energy of 26.49 kJ mol-1 , the high ionic conductivity of 7.6 mS cm-1 , and a large Zn2+ transference number of 0.74. Hence, the Zn@CuHCF||Zn@CuHCF symmetric cell delivers high cycling stability over 1800 h at 5 mA cm-2 , an excellent depth of discharge of 51.3%, and the accumulative discharge capacity over 3000 mAh cm-2 . In addition, the Zn//Ti@CuHCF asymmetric cell achieves the coulombic efficiency (CE) of 99.87% after 2000 cycles. More importantly, the Zn@CuHCF//V2 O5 full cell presents outstanding capacity retention of 87.6% at 10 A g-1 after 3000 cycles. This work develops a type of material to form an artificial protection layer for high-performance AZIBs.

13.
Respir Res ; 23(1): 39, 2022 Feb 26.
Artigo em Inglês | MEDLINE | ID: mdl-35219329

RESUMO

BACKGROUND: Recent studies have demonstrated that airway basal stem cells (BCs) transplantation can ameliorate bleomycin-induced idiopathic pulmonary fibrosis (IPF) through lung regeneration promotion. However, BCs under oxidative stress in the alveolar microenvironment are poor in survival, causing unsatisfied efficacy of BCs transplantation. In this study, we investigated whether Coenzyme Q10(CoQ10) counteracts oxidative stress in the alveolar microenvironment, thus improved the efficacy of BCs transplantation for IPF treatment. METHODS: The protective effects of CoQ10 on H2O2-induced BCs apoptosis and cytoplasmic reactive oxygen species (ROS) level were tested by flow cytometry in vitro. The therapeutic effects of BCs combined with CoQ10 were compared to a single BCs transplantation protocol in IPF treatment after 2 weeks and were evaluated by parameters including changes of body weight and survival rate, as well as various levels of pulmonary inflammation, α-SMA expression and hydroxyproline (HYP) in IPF mouse lung tissues. RESULTS: CoQ10 preincubation with BCs (10 mM, 24 h) significantly reduced the late apoptosis of BCs and the number of oxidative stressful BCs as a result of H2O2 stimulation (1 mM, 6 h) in vitro. IPF mouse model was constructed through bleomycin (5 mg/kg) intratracheal instillation. Bleomycin-induced IPF mice showed weight loss continuously and mortality increased progressively during modeling. Serious pulmonary inflammatory cell infiltration, collagen fiber proliferation, and collagen protein deposition were observed in lung tissues of IPF mice. Though BCs transplantation alone improved indicators above in bleomycin-induced IPF mice to some extent, the combination with CoQ10 improved the transplantation efficacy and obtained better therapeutic effects. CONCLUSION: CoQ10 blocked H2O2-induced apoptosis of BCs and ROS production in vitro, and enhanced the efficacy of BCs transplantation against bleomycin-induced IPF in mice.


Assuntos
Fibrose Pulmonar Idiopática/tratamento farmacológico , Estresse Oxidativo/efeitos dos fármacos , Regeneração/efeitos dos fármacos , Transplante de Células-Tronco/métodos , Ubiquinona/análogos & derivados , Animais , Apoptose/efeitos dos fármacos , Bleomicina/toxicidade , Células Cultivadas , Modelos Animais de Doenças , Humanos , Fibrose Pulmonar Idiopática/induzido quimicamente , Fibrose Pulmonar Idiopática/terapia , Masculino , Camundongos , Camundongos Endogâmicos C57BL , Ubiquinona/uso terapêutico
14.
BMC Pulm Med ; 22(1): 462, 2022 Dec 05.
Artigo em Inglês | MEDLINE | ID: mdl-36471386

RESUMO

BACKGROUND: This study evaluated the effects of less invasive surfactant administration (LISA) and intubation-surfactant-extubation (InSurE) on bronchopulmonary dysplasia (BPD) in preterm infants with respiratory distress syndrome (RDS). METHODS: Neonates with respiratory distress syndrome requiring surfactant, with gestational age < 32 weeks and birth weight < 1500 g admitted to our neonatal intensive care unit from January 2018 to December 2019, were retrospectively analyzed. LISA and InSurE were used independently. The incidence of BPD at 36 weeks postmenstrual age, pre-discharge mortality, and need for mechanical ventilation (MV) within 72 h of birth were compared between LISA and InSurE group. Secondary outcomes including necrotizing enterocolitis requiring surgery, retinopathy of prematurity ≥ stage 3, patent ductus arteriosus requiring medical therapy or surgery, and length of hospitalization were analyzed. RESULTS: Among the 148 included neonates, there were 46 and 102 infants in LISA group and InSurE group, respectively. There were no significant differences in BPD incidence, the severity of BPD at 36 weeks postmenstrual age, and the rate of MV within the first 72 h after birth between the two groups (P > 0.05, respectively). The incidences of necrotizing enterocolitis requiring surgery, retinopathy of prematurity ≥ stage 3, patent ductus arteriosus requiring medical therapy or surgery, and length of hospitalization did not differ significantly between the two groups (P > 0.05, respectively). CONCLUSIONS: For surfactant administration among preterm infants with respiratory distress syndrome, LISA did not decrease bronchopulmonary dysplasia and severity of BPD at 36 weeks postmenstrual age. The benefits of LISA would require further evaluations.


Assuntos
Displasia Broncopulmonar , Permeabilidade do Canal Arterial , Enterocolite Necrosante , Surfactantes Pulmonares , Síndrome do Desconforto Respiratório do Recém-Nascido , Retinopatia da Prematuridade , Lactente , Recém-Nascido , Humanos , Estudos Retrospectivos , Recém-Nascido Prematuro , Displasia Broncopulmonar/epidemiologia , Displasia Broncopulmonar/terapia , Extubação , Enterocolite Necrosante/epidemiologia , Tensoativos/uso terapêutico , Surfactantes Pulmonares/uso terapêutico , Síndrome do Desconforto Respiratório do Recém-Nascido/terapia , Respiração Artificial , Intubação Intratraqueal , Recém-Nascido de muito Baixo Peso
15.
Langmuir ; 36(11): 2837-2846, 2020 Mar 24.
Artigo em Inglês | MEDLINE | ID: mdl-32151133

RESUMO

Surface relief gratings (SRGs) with hierarchical microstructures are highly needed owing to their diverse applications in various fields. Here, we introduce surface-wrinkling templates as novel nonlithographic phase masks to direct the generation of hierarchical well-prescribed SRGs on nonconformally contacted azo-films by a simple single-beam illumination. The light-induced SRGs have controlled microstructures including single/double/triple wavelengths and single/double orientations as well as their organizations. These microstructures can be well tailored by the wavelength of the surface-wrinkling phase masks and the polarization direction of incident light relative to the wrinkling patterns in the phase masks. Interestingly, we find that the larger wavelength is induced prior to the smaller ones, offering another new strategy to tailor the microstructures of SRGs through simple manipulation of the illumination duration. In particular, path-guided SRGs with unprecedented well-organized hierarchical microstructures have been available in the case of controlled moving of the light illumination through the surface-wrinkling phase mask. As demonstrated, the obtained hierarchical SRGs with the capability of multiple optical inscription/erasure have great application potentials in fields such as confidential information (or pattern) records and encryption/decryption.

16.
J Adolesc ; 81: 114-123, 2020 06.
Artigo em Inglês | MEDLINE | ID: mdl-32416383

RESUMO

INTRODUCTION: Perceived discrimination is a significant stressor in the lives of Chinese rural left-behind adolescents. Although some research has examined the effects of perceived discrimination on left-behind adolescents' psychosocial functioning, the majority of existing research is cross-sectional, which limits the understanding of the underlying mechanism of these effects. The current study used a longitudinal design to explore how perceived discrimination is associated with psychosocial functioning (i.e., depressive symptoms and social initiative) over time in Chinese rural left-behind adolescents. METHODS: A total of 1011 rural left-behind adolescents (54% boys) were involved in an ongoing longitudinal study. At Time 1 (Mage = 12.93, SD = 0.86), adolescents completed measures of perceived discrimination, depressive symptoms, and social initiative. At Time 2 (one year later), adolescents again reported on their depressive symptoms and social initiative. RESULTS: Perceived discrimination was concurrently and longitudinally associated with left-behind adolescents' depressive symptoms and social initiative. The effect of perceived discrimination on depressive symptoms was partially mediated by social initiative, while the effect of perceived discrimination on social initiative was fully mediated by depressive symptoms. The associations applied equally to adolescents with two migrant parents and adolescents with only a migrant father. CONCLUSIONS: These findings suggest the harmful impact of perceived discrimination on rural left-behind adolescents' social initiative and depressive symptoms and underscore the importance of eliminating discrimination in the rural left-behind adolescents' intervention program.


Assuntos
Depressão/psicologia , Discriminação Social/psicologia , Interação Social , Adolescente , China , Estudos Transversais , Feminino , Humanos , Estudos Longitudinais , Masculino , População Rural
17.
J Adolesc ; 75: 73-84, 2019 08.
Artigo em Inglês | MEDLINE | ID: mdl-31351377

RESUMO

INTRODUCTION: Planning for the future is important for adolescents' development and academic adaptation. Most prior research has focused primarily on the effects of future planning on adolescents' academic achievement, and there is a dearth of literature examining the effects of adolescents' academic achievement on their future planning. The current study examined the longitudinal reciprocal relations between adolescents' future planning and academic achievement in China. METHODS: The study sample consisted of 775 Chinese junior high school students (391 boys, 384 girls; Mage = 13.38 years, SD = 0.89). Future planning and academic achievement were measured at three time points that were equally spaced by a 6-month lag. Path analyses with cross-lagged effects were used to examine the longitudinal reciprocal relations between adolescents' future planning and academic achievement. RESULTS: The associations between future educational planning and academic achievement were reciprocal. Future occupational commitment predicted adolescents' academic achievement, and academic achievement predicted adolescents' affects concerning future occupation. However, there was no significant association between future occupational exploration and academic achievement. Moreover, these patterns of longitudinal relations applied equally to boys and girls, and younger and older adolescents. CONCLUSIONS: The reciprocal relations between future planning processes and academic achievement differed across domains (e.g., educational and occupational domains). These findings suggest that future planning may be a protective factor for improving adolescents' academic achievement, and high academic achievement may also be beneficial for Chinese adolescents' future planning.


Assuntos
Sucesso Acadêmico , Estudantes/psicologia , Adolescente , China , Feminino , Humanos , Estudos Longitudinais , Masculino
18.
J Youth Adolesc ; 48(6): 1146-1160, 2019 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-30835034

RESUMO

Parental absence, a consequence of parents' rural-to-urban migration, exerts negative influences on their left-behind adolescents in rural China. Existing studies are limited by their focus on the isolated developmental outcomes of left-behind adolescents and by a dearth of work focused on naturally occurring patterns of their developmental outcomes. The present study used a person-centered approach to identify adolescents' adaptation profiles based on internalizing indicators (i.e., depressive symptoms, loneliness, subjective happiness, life satisfaction), externalizing indicators (i.e., rule-breaking behavior, aggressive behavior, prosocial behavior) and academic achievement and to relate these profiles to left-behind status, characteristics of parent-adolescent separation and gender. The study included 2102 adolescents (Mage = 13.48 ± 1.10 years, 46.8% girls) in junior high schools in rural China. A latent profile analysis identified 3 profiles: an adequate adaptation profile, an internalizing problem profile and an externalizing problem profile. These profiles were linked to left-behind status, to characteristics of parent-adolescent separation (i.e., separation duration, interval of long-distance communication and face-to-face communication) and to gender. These findings provide significant implications for future research and the development of interventions.


Assuntos
Adaptação Psicológica , Desenvolvimento do Adolescente , Separação da Família , Saúde Mental , Relações Pais-Filho , Saúde da População Rural , Migrantes , Adolescente , China , Estudos Transversais , Depressão/etiologia , Depressão/psicologia , Feminino , Felicidade , Humanos , Solidão/psicologia , Masculino , Satisfação Pessoal , Comportamento Problema/psicologia , Psicologia do Adolescente
19.
Opt Express ; 26(9): 11553-11567, 2018 Apr 30.
Artigo em Inglês | MEDLINE | ID: mdl-29716074

RESUMO

We propose a design of a retinal-projection-based near-eye display for achieving ultra-large field of view, vision correction, and occlusion. Our solution is highlighted by a contact lens combo, a transparent organic light-emitting diode panel, and a twisted nematic liquid crystal panel. Its design rules are set forth in detail, followed by the results and discussion regarding the field of view, angular resolution, modulation transfer function, contrast ratio, distortion, and simulated imaging.


Assuntos
Lentes de Contato , Modelos Biológicos , Retina/fisiologia , Desenho de Equipamento , Humanos , Cristais Líquidos , Óptica e Fotônica
20.
Langmuir ; 34(16): 4793-4802, 2018 04 24.
Artigo em Inglês | MEDLINE | ID: mdl-29608311

RESUMO

We report a simple and efficient laser-writing strategy to fabricate hierarchical nested wrinkling microstructures on conductive polypyrrole (PPy) films, which enables us to develop advanced functional surfaces with diverse applications. The present strategy adopts the photothermal effect of PPy films to mimick the formation of hierarchical nested wrinkles observed in nature and design controlled microscale wrinkling patterns. Here, the PPy film is grown on a poly(dimethylsiloxane) (PDMS) substrate via oxidation polymerization of pyrrole in an acidic solution, accompanied by in situ self-wrinkling with wavelengths of two different scales (i.e., λ1 and λ2). Subsequent laser exposure of the PPy/PDMS bilayer induces a new surface wrinkling with a larger wavelength (i.e., λ3). Owing to the retention of the initial λ1 wrinkles, we obtain hierarchical nested wrinkles with the smaller λ1 wrinkles nested in the larger λ3 ones. Importantly, we realize the large-scale path-determinative fabrication of complex oriented wrinkling microstructures by controlling the relative motion between the bilayer and the laser. Combined with the induced changes in surface color, surface-wrinkling microstructures, and conductivity in the PPy films, the laser-writing strategy can find broad applications, for example, in modulation of surface wetting properties and fabrication of microcircuits, as demonstrated in this work.

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