Electrochemical removal of ammonium nitrogen in high efficiency and N2 selectivity using non-noble single-atomic iron catalyst.

Ammonia nitrogen (NH4+-N) is a ubiquitous environmental pollutant, especially in offshore aquaculture systems. Electrochemical oxidation is very promising to remove NH4+-N, but suffers from the use of precious metals anodes. In this work, a robust and cheap electrocatalyst, iron single-atoms distributed in nitrogen-doped carbon (Fe-SAs/N-C), was developed for electrochemical removal of NH4+-N from in wastewater containing chloride. The Fe-SAs/N-C catalyst exhibited superior activity than that of iron nanoparticles loaded carbon (Fe-NPs/N-C), unmodified carbon and conventional Ti/IrO2-TiO2-RuO2 electrodes. And high removal efficiency (> 99%) could be achieved as well as high N2 selectivity (99.5%) at low current density. Further experiments and density functional theory (DFT) calculations demonstrated the indispensable role of single-atom iron in the promoted generation of chloride derived species for efficient removal of NH4+-N. This study provides promising inexpensive catalysts for NH4+-N removal in aquaculture wastewater.

Ammonia-nitrogen removal from water with gC3N4-rGO-TiO2 Z-scheme system via photocatalytic nitrification-denitrification process.

Photocatalytic removal of NH3-N is expected to be an alternative to the biological method that accompanied with high energy consumption and secondary pollution. However, NH3-N is always oxidized into nitrate and nitrite during the photocatalytic processes, which also need to be removed from the water. Herein, the g-C3N4/rGO/TiO2 Z-scheme photocatalytic system was prepared and used for the NH3-N removal. The results showed the rate constant of NH3-N conversion on it was 0.705 h-1, 1.7 times as high as that on g-C3N4/TiO2, and most of the NH3-N were converted into gaseous products. And the experiment result indicated NH3-N and NO3- in water could enhance the removal of each other. According to the results, the main reaction mechanism is speculated as: ·OH radicals and ·O2- radicals were generated on TiO2 and oxidized the NH3-N into NO3-, and the latter was reduced into non-toxic N2 on the conduction band of g-C3N4. Finally, NH3-N removal performance for actual coking wastewater was investigated, and the stability of the photocatalyst was tested. This work provides some theoretical basis for the two-step degradation of pollutants by Z-scheme photocatalytic system.

New progress of ammonia recovery during ammonia nitrogen removal from various wastewaters.

The recovery of ammonia-nitrogen during wastewater treatment and water purification is increasingly critical in energy and economic development. The concentration of ammonia-nitrogen in wastewater is different depending on the type of wastewater, making it challenging to select ammonia-nitrogen recovery technology. Meanwhile, the conventional nitrogen removal method wastes ammonia-nitrogen resources. Based on the circular economy, this review comprehensively introduces the characteristics of several main ammonia-nitrogen source wastewater plants and their respective challenges in treatment, including municipal wastewater, industrial wastewater, livestock and poultry wastewater and landfill leachate. Furthermore, we introduce the main methods currently adopted in the ammonia-nitrogen removal process of wastewater from physical (air stripping, ion exchange and adsorption, membrane and capacitive deionization), chemical (chlorination, struvite precipitation, electrochemical oxidation and photocatalysis) and biological (classical and typical activated sludge, novel methods based on activated sludge, microalgae and photosynthetic bacteria) classification based on the ammonia recovery concept. We discuss the applicable methods of recovering ammonia nitrogen in several main wastewater plants. Finally, we prospect the research direction of ammonia removal and recovery in wastewater based on sustainable development.

Combined alkali-photocatalytic stimulation enables click microbial domestication for boosted ammonia nitrogen removal.

Microbe-driven ammonia nitrogen removal plays a crucial role in the nitrogen cycle and wastewater treatment. However, the rational methods and mechanisms for boosting nitrogen conversion through microbial domestication are still limited. Herein, a combined alkali-photocatalytic stimulation strategy was developed to activate the Halomonas shizuishanensis DWK9 for efficient ammonia nitrogen removal. The strain DWK9 selected from saline-alkaline soil in Northwestern China possessed strong resistance to stress of saline-alkaline environment and free radicals, and was abundant in nitrogen conversion genes, thus is an ideal model for advanced microbial domestication. Bacterial in the combined alkali-photocatalytic stimulation group achieved a high ammonia nitrogen conversion rate of 67.5 %, 10 times outperforming the non-stimulated and single alkali/photocatalytic stimulation control groups. Morphology analysis revealed that the bacteria in the alkali-photocatalytic stimulated group formed a favorable structure for bioelectric transfer. Remarkably, the domesticated bacteria demonstrated improved electrochemical properties, including increased current capacity and lower overpotentials and impedance. Prokaryotic transcription genetic analysis together with qPCR analysis showed upregulation of denitrification-related metabolic pathway genes. A novel FAD dependent and NAD(P)H independent energy mode has been proposed. The universality and effectiveness of the as-developed combined alkali-photocatalytic microbial domestication strategy were further validated through indicator fish survival experiments. This work provides unprecedented degrees of freedom for the exploration of rational microbial engineering for optimized and controllable biogeochemical conversion.

Electro-oxidation of ammonia nitrogen using W, Ti-doped IrO2 DSA as a treatment method for mariculture and livestock wastewater.

Animal farming wastewater is one of the most important sources of ammonia nitrogen (NH4+-N) emissions. Electro-oxidation can be a viable solution for removing NH4+-N in wastewater. Compared with other treatment methods, electro-oxidation has the advantages of i) high removal efficiency, ii) smaller size of treatment facilities, and iii) complete removal of contaminant. In this study, a previously prepared DSA (W, Ti-doped IrO2) was used for electro-oxidation of synthetic mariculture and livestock wastewater. The DSA was tested for chlorine evolution reaction (CER) activity, and the reaction kinetics was investigated. CER current efficiency reaches 60-80% in mariculture wastewater and less than 20% in livestock wastewater. In the absence of NH4+-N, the generation of active chlorine follows zero-order kinetics and its consumption follows first-order kinetics, with cathodic reduction being its main consumption pathway, rather than escape or conversion to ClO3-. Cyclic voltammetry experiments show that NH4+-N in the form of NH3 can be oxidized directly on the anode surface. In addition, the generated active chlorine combines with NH4+-N at a fast rate near the anode, rather than in the bulk solution. In electrolysis experiments, the NH4+-N removal rate in synthetic mariculture wastewater (30-40 mg/L NH4+-N) and livestock wastewater (~ 450 mg/L NH4+-N) is 112.9 g NH4+-N/(m2·d) and 186.5 g NH4+-N/(m2·d), respectively, which is much more efficient than biological treatment. The specific energy consumption (SEC) in synthetic mariculture wastewater is 31.5 kWh/kg NH4+-N, comparable to other modified electro-catalysts reported in the literature. However, in synthetic livestock wastewater, the SEC is as high as 260 kWh/kg NH4+-N, mainly due to the suppression of active chlorine generation by HCO3- and the generation of NO3- as a by-product. Therefore, we conclude that electro-oxidation is suitable for mariculture wastewater treatment, but is not recommended for livestock wastewater. Electrolysis prior to urea hydrolysis may enhance the treatment efficiency in livestock wastewater.

Improved permeability in ceramsite@powdered activated carbon (PAC)-MnOx coupled gravity-driven ceramic membrane (GDCM) for manganese and ammonia nitrogen removal with intermittent short-term vertical aeration.

In our work, a gravity-driven ceramic membrane bioreactor (GDCMBR) was developed to remove Mn2+ and NH3-N simultaneously through the birnessite water purification layer in-situ construction on the ceramic membrane due to chemical pre-oxidation (powdered activated carbon (PAC)-MnOx). Considering the trade-off of biofouling and water production, the daily intermittent short-term vertical aeration mode was involving to balance this contradiction with the excellent water purification and improved membrane permeability. And the GDCMBR permeability of operation flux was improved for 5-7 LHM with intermittent short-term vertical aeration. Furthermore, only ∼7 % irreversible membrane resistance (Rir) also confirmed the improved membrane permeability with intermittent short-term vertical aeration. And some manganese oxidizing bacteria (MnOB) and ammonia oxidizing bacteria (AOB) species at genus level were identified during long-term operation with the contact circulating flowing raw water, resulting in the better Mn2+ and NH3-N removal efficiency. Additionally, the nano-flower-like birnessite water purification layer was verified in ceramsite@PAC-MnOx coupled GDCMBR, which evolute into a porous flake-like structure with the increasing intermittent short-term aeration duration. Therefore, the sustainable and effective intermittent short-term aeration mode in ceramsite@PAC-MnOx coupled GDCMBR could improve the membrane permeability with the satisfactory groundwater purification efficiency, as well as providing an energy-efficient strategy for membrane technologies applications in water supply safety.

Effect of temperature on fungal nitrification in simulated in-situ aeration of aged MSW landfill.

Fungal nitrification is one kind of heterotrophic nitrification that involves certain species of fungi promoting the transformation of organic nitrogen and ammonia nitrogen to nitrite/nitrate. In this study, simulated aerated landfill reactors (SALRs) were constructed to investigate fungal nitrification in aged municipal solid refuse, with a focus on understanding the effect of temperature on the performance of fungal nitrification as well as fungal contribution to ammonia nitrogen transformation. Different nitrogen metabolism patterns have been observed in the system with fungi only (SALRF) and complete microbial consortium, i.e., bacteria + fungi (SALRC). At a temperature of 35 °C, autotrophic nitrification dominated the ammonia nitrogen transformation, while fungal nitrification did not significantly contribute to ammonia removal. However, at elevated temperatures (i.e., 45 °C and 55 °C), fungi played a crucial role in ammonia transformation through fungal assimilation and fungal nitrification, with bacterial function suppressed. Furthermore, 45 °C was found to be the optimal temperature for fungal nitrification, exhibiting the highest nitrification rate (13.98 mg L-1 d-1) which accounted for 49.80% of total nitrification rate in the aerated landfill. High throughput sequencing revealed reshaping of fungal community in response to temperature variation. The abundance of Aspergillus fumigatus, with a relative abundance ranging from 67.13% to 92.71% at elevated temperatures, suggested its significant potential for fungal nitrification. These findings have implications for the promotion of nitrogen cycle through strengthening fungal nitrification in aerated landfill sites which often operate at high temperatures.

Screening and characteristics of ammonia nitrogen removal bacteria under alkaline environments.

The toxicity of ammonia nitrogen (AN) has always caused severe harm to aquatic animals in intensive aquaculture conditions, especially in saline-alkali aquaculture waters. The application of AN removal bacteria is a safe and effective method for controlling the AN concentration in aquaculture water through direct conversion to bacterial protein. However, there is still a lack of AN removal bacteria that are appropriate for saline-alkali aquaculture conditions. In this study, three AN removal strains, namely, Bacillus idriensis CT-WN-B3, Bacillus australimaris CT-WL5-10, and Pseudomonas oleovorans CT-WL5-6, were screened out under alkaline conditions from the alkali-tolerant strains distributed in carbonate saline-alkali soil and water environments in Northeast China. Under different pH (8.0-9.0), salinities (10-30 g/L NaCl), alkalinities (10-30 mmol/L NaHCO3), and AN concentrations (1-3 mg/L), corresponding to the actual conditions of saline-alkali aquaculture waters, the AN removal rates and relative characteristics of these strains were analyzed. The results showed that all of the three strains were efficient on AN removal under various conditions, and the highest removal rate reached up to 3 × 10-13 mg/cfu/h. Both CT-WL5-10 and CT-WL5-6 were most efficient under pH 9.0 with 3 mg/L initial AN, while pH 8.5 with 2 mg/L AN was the best fit for CT-WN-B3. In 96-h pure incubation of these strains in alkali media, approximately 90% AN was removed, and pH values were decreased by 2.0 units within 12 h accompanied by the growth of the strains. In addition, salinity and alkalinity slightly disturbed the removal rates of CT-WL5-10 and CT-WL5-6, but there were at least 65% AN removed by them within 24 h. These results indicated that all three strains have good application prospect in saline-alkali aquaculture waters.

Improved performance of an opposite-flow low-pressure ultrafiltration membrane system in the treatment of groundwater containing Fe2+, Mn2+, and NH4.

In remote areas, low-pressure ultrafiltration membrane (LPM) systems can be applied in decentralized water supplies for the treatment of groundwater containing Fe2+, Mn2+, and NH4+. However, improving the performance of the LPM systems, such as the stable flux and removal capacity, presents a challenge. In this study, a novel opposite-flow low-pressure ultrafiltration membrane (O-LPM) system was applied, and its performance was evaluated. Experimental results showed that after 46 days of operation, the steady flux of the O-LPM systems were 1.87-fold and 1.74-fold higher than that of the conventional D-LPM systems under Mn2+ concentration of 0.3 mg L-1 and 1.5 mg L-1, respectively. With a mixed pollutant system containing Fe2+ (0.5 mg L-1), Mn2+ (0.3 mg L-1), and NH4+ (1.0 mg L-1), the O-LPM-ripening period for Mn2+ removal was shortened from 16 days to 8 days, and the NH4+ removal efficiency was increased from 61.46% to 80.97%. The bio-cake layer in the O-LPM systems was thinner and had a higher uniformity than in the D-LPM systems, resulting in a larger stable flux range. The relative abundance of functional bacteria (MnOB, IOB, and NOB) was generally higher in O-LPM systems than in the D-LPM systems. Overall, these results are of high relevance for groundwater treatment in remote areas, providing guidance for the widespread application of the O-LPM system in decentralized water supplies.

Simultaneous reductions in antibiotic, antibiotic resistance genes and nitrogen loss during bioaugmentation tylosin fermentation dregs co-composting.

Considering the main problems presented in the typical solid wastes antibiotic fermentation dregs (AFDs) composting that the residual antibiotics could result in the propagation of antibiotic resistance genes (ARGs), and the reduced value of agronomic production caused by the ammonia gas (NH3) emissions. This study established a bio-augmented tylosin fermentation dregs (TFDs) aerobic co-composting system to investigate the effects of a novel isolated high-efficiency strain Klebsiella sp. TN-1 inoculation on tylosin degradation, reduction in ammonia emissions, and ARG abundances during this process. Results showed that the application of strain Klebsiella sp. TN-1 extended the thermophilic stage and promoted compost maturity. Moreover, bio-enhanced co-composting with strain Klebsiella sp. TN-1 led to a totally degradation of tylosin, and removed most of ARGs, metal resistance genes (MRGs) and mobile genetic elements (MGEs), and also effectively reduce ammonia emission by 49.76 %.via increasing ammoxidation rates. Principal co-ordinates analysis further suggested that the strain Klebsiella sp. TN-1 had little influence on the bacterial community composition, while the changes of other physical and chemical properties during this process were the main reasons for the evolution of bacterial community and propagation of ARGs in the TFDs co-composting. This study suggests the potential of the bio-enhanced strain Klebsiella sp. TN-1 for antibiotic biodegradation and its application for nitrogen conservation in the AFDs co-composting process, which could decrease the risk of ARGs spreading and make compost products more secure.

Evaluation of a liquid-phase plasma discharge process for ammonia oxidation in wastewater: Process optimization and kinetic modeling.

Removing ammonia-nitrogen (NH3N) from wastewater is of paramount importance for wastewater treatment. In this study, a novel continuous liquid plasma process (CLPD) was evaluated to remove NH3N from synthetic wastewater. The Box-Behnken experimental design was used to optimize the main process parameters, including the initial NH3N concentration (50-200 mg/L), power input (150-300 W), and gas-flow rate (1.5-2.5 L/min), for efficient NH3N removal from wastewater. The gas-flow rate and power input were found to be significant factors affecting the removal efficiency of NH3N, whereas the initial concentration of NH3N played a vital role in determining the energy efficiency of the process. Under the optimal conditions of an initial NH3N concentration of 200 mg/L, applied power of 223 W, and gas-flow rate of 2.4 L/min, 98.91% of NH3N could be removed with a N2 selectivity of 92.91%, and the corresponding energy efficiency was 0.527 g/kWh after 2 hrs of treatment. A small fraction of undesirable NO3--N (7.05 mg/L) and NO2--N (2.83 mg/L) were also produced. Kinetic modeling revealed that NH3N degradation by the CLPD followed a pseudo-first-order reaction model, with a rate constant (k) of 0.03522 min-1. Optical emission spectroscopy (OES) was used to gather information about the active chemical species produced during the plasma discharge. The obtained spectra revealed the presence of several highly oxidative radicals, including ‧OH, ‧O, and ‧O2+. These results demonstrate the potential of liquid phase plasma discharge as a highly efficient technology for removing ammonia from aqueous solutions.

Application of Pd-Sn modified Ru-Ir electrode for treating high chlorine ammonia-nitrogen wastewater.

Electro-catalytic technology is a promising approach for wastewater treatment, owing to its easy operation, minimal generation of secondary pollution, small foot-print and rapid start-up. In this work, the chlorine evolution potential of the Pd-Sn modified ruthenium(Ru)-iridium(Ir) electrode was investigated for the electro-catalytic treatment of high chlorine ammonia-nitrogen wastewater. The effect of reaction conditions on the removal of ammonia-nitrogen, kinetics and apparent activation energy of ammonia-nitrogen removal were studied. The possible denitrification process of high chlorine ammonia-nitrogen wastewater was discussed. The results indicated that the chlorine evolution potential of the Pd-Sn modified Ru-Ir electrode was 1.0956 V(vs. SCE). The electro-catalytic treatment of high chlorine ammonia-nitrogen conformed to zero-order kinetic law, and the apparent activation energy of removal process was 14.089 kJ/mol. With a current was 0.5 A, the removal efficiency of ammonia-nitrogen could achieve 100% at a reaction time of 40 min. Indirect oxidation played an essential role in the electro-catalytic ammonia-nitrogen removal using the Pd-Sn modified Ru-Ir electrode. This paper demonstrated that the electro-catalytic technology was a promising approach for efficiently treating the high chlorine ammonia-nitrogen wastewater.

Optimization and modeling of ammonia nitrogen removal from anaerobically digested liquid dairy manure using vacuum thermal stripping process.

During anaerobic digestion (AD) of liquid dairy manure, organic nitrogen converts to ammonia nitrogen (NH3-N) and subsequently escalates the NH3-N concentrations in manure. Among different available NH3-N removal processes treating anaerobically digested liquid dairy manure (ADLDM), vacuum thermal stripping is reported to be an effective technique. However, none of the studies have performed multi-parameter optimization, which is of utmost significance in maximizing process efficiency. In this study, critical operational parameters for vacuum thermal stripping of NH3-N from ADLDM were optimized and modeled for the first time via integrating grey relational analysis (GRA)-based Taguchi design, response surface methodology (RSM), and RSM-artificial neural network (ANN). The initial experimental trials conducted using the GRA coupled with Taguchi L16 orthogonal array revealed the order of influence of the process parameters on NH3-N removal as vacuum pressure (kPa) > temperature (°C) > treatment time (min) > mixing speed (rpm) > pH. The values of the first three most influential operating parameters were then further optimized and modeled using RSM and RSM-ANN models. Under the optimized conditions (temperature: 69.6 °C, vacuum pressure: 43.5 kPa, and treatment time: 87.65 min), the NH3-N removal efficiency of 93.58 ± 0.59 % was experimentally observed and was in line with the RSM and RSM-ANN models' predicted values. While the RSM-ANN model showed a better prediction potential than did the RSM model when compared statistically. Moreover, the nutrient contents (nitrogen, N and sulfur, S) of the recovered NH3-N as ammonium sulfate ((NH4)2SO4) were in reasonable agreement with the market-available (NH4)2SO4 fertilizer. The results presented in this study provide important insights into improving the treatment process performance and will help design and operate future pilot- and full-scale vacuum thermal stripping processes in dairy farms.

Characterization and mechanism analysis of tylosin biodegradation and simultaneous ammonia nitrogen removal with strain Klebsiella pneumoniae TN-1.

A novel bacterial strain that exhibited a high capacity for the simultaneous degradation and removal of tylosin and ammonia nitrogen, respectively, was isolated from tylosin fermentation dregs (TFDs) and identified as Klebsiella pneumoniae TN-1. The removal efficiencies of tylosin and ammonia nitrogen reached 95.31% and 83.26%, respectively, at initial concentrations of 300 mg/L for both. Three identified intermediates with less toxicity indicated that de-sugarization and hydrolysis were the proposed biodegradation pathways. The results also suggested that strain TN-1 could reduce nitrogen loss by transforming ammonium into nitrate nitrogen according to the transcriptional expression of nitrogen transformation-related genes and the activities of functional enzymes. Moreover, strain TN-1 effectively reduced ammonia volatilization by 65.20% and facilitated tylosin degradation, with a maximum removal efficiency of 57.35% in the simulated fermentation process of TFDs. This work provides an efficient bioaugmentation for simultaneous antibiotic degradation and nitrogen conservation during the composting process.

Electrolysis-enhanced ecological floating bed and its factors influencing nitrogen and phosphorus removal in simulated hyper-eutrophic water.

To enhance ammonia nitrogen (NH3-N) and phosphate (PO43--P) removal in hyper-eutrophic water, electrolysis-enhanced ecological floating bed (EEEFB) was designed with a Mg-Al alloy anode, a Ir-Ta-Ti metal oxide-coated titanium anode, and an Fe anode with the same graphite cathode. The results showed that the Mg-Al alloy anode with graphite cathode had a better ability to enhance NH3-N and PO43--P removal. When the current density was 0.37 mA·cm-2, the electrolysis time was 24 h/d, and the net removal rates of NH3-N and PO43--P were 62% and 99.4%, respectively. In winter, the purification efficiencies of NH3-N and PO43--P were as high as 7388.4 mg·m-2 and 4297.5 mg·m-2, respectively, by EEEFBs which were significantly higher than the traditional ecological floating bed (p < 0.05). Scanning electron microscopy (SEM) and X-ray spectrometry confirmed that the PO43--P was deposited in the sediment of EEEFBs with Mg-Al alloy anode and Fe anode.

Effective immobilization of Bacillus subtilis in chitosan-sodium alginate composite carrier for ammonia removal from anaerobically digested swine wastewater.

To overcome the easy loss of microorganism, the mass production of sludge and the consumption of aeration energy during biological treatment of anaerobically digested swine wastewater, this study used chitosan-sodium alginate composite carrier to prepare immobilized bacteria pellets. The heterotrophic bacteria tolerant to high concentrations of ammonia nitrogen were isolated and the conditions for immobilizing bacteria were optimized. The performance of immobilized bacteria pellets to remove ammonia nitrogen from ADSW was determined and the corresponding mechanism was investigated. Results showed that the isolated bacteria were Bacillus subtilis, and the optimal conditions to prepare the immobilized bacteria pellets by response surface methodology tests were sodium alginate of 0.84% (m/V), chitosan of 0.22% (m/V), embedding time of 32 min and embedding amount of 15% (V/V). In ADSW treatment, at pH 6, 20 g/L of the immobilized bacteria pellets removed 96.5% of ammonia nitrogen. Both adsorption and microbial action contributed to ammonia nitrogen removal, and their contributions were 54.3% and 42.2%, respectively. Compared with the immobilized bacteria pellets using chitosan-sodium alginate as carrier, the one using mono alginate as carrier had a weaker ability to remove ammonia nitrogen, with a removal efficiency of 67.4%. The main mechanism was the formation of polyelectrolyte membrane by the connection between amino groups of chitosan and carboxyl groups of sodium alginate, which stabilized the immobilized bacteria pellets and prolonged their service life. To sum up, the immobilized bacteria pellets using chitosan-sodium alginate as an embedding agent have a promising prospect in ammonia nitrogen removal from wastewater.

Advanced oxygenation efficiency and purification of wastewater using a constant partially unsaturated scheme in column experiments simulating vertical subsurface flow constructed wetlands.

The presence of sufficient dissolved oxygen (DO) in a constructed wetland (CW) is vital to the process of removing ammonia nitrogen and organics from wastewater. To achieve total nitrogen removal, which is characterised by enhanced ammonia nitrogen removal, this study offers an efficient strategy to increase the oxygen supply by establishing constant unsaturated zones and baffles in simulating constructed wetlands (SCWs). Henceforth, this strategy is addressed as a partially unsaturated SCW. A centrally located high tube was set up inside the wetland to create an unsaturated zone at a higher level. The effectiveness of the unsaturated zone to supplement the oxygen content was evaluated by comparing with controls (an unaerated SCW and an aerated SCW). The results show the chemical oxygen demand removal rate (85 ±â€¯6%) in the partially unsaturated SCW was equivalent to that in the aerated SCW (83 ±â€¯6%), while the ammonia nitrogen removal rate was 11 times higher compared to that of the unaerated SCW. The removal potential of the partially unsaturated SCW under different HRT (hydraulic retention time)s (12, 24, and 36 h) was examined, and the 36 h-SCW performed the best in the removal of organics and nitrogen. The mechanisms behind the unsaturated zone strategy were studied by analysing water and microbe samples along the pathway. The results from the water quality indicators and the quantitative polymerase chain reactions along the pathway showed the unsaturated zone contributed to the removal of primary organics and ammonia nitrogen. The superior performance of unsaturated zone strategy was discussed further using the enrichment of ammonia-oxidising bacteria, mass of oxygen uptake, and baffle design. The results indicate that the amoA gene/16s rRNA gene abundance ratio and the oxygen uptake (336 ±â€¯44 g m-3 d-1) in the partially unsaturated SCW was higher than that observed in the two controls.

Food waste based biochars for ammonia nitrogen removal from aqueous solutions.

Biochar derived from waste has been increasingly considered as a potential green adsorbent due to its significant ability and affordable production costs. This study prepared and evaluated 7 types of food waste-based biochars (FWBBs) (including meat and bone, starchy staples, leafy stemmed vegetables, nut husks, fruit pericarp, bean dreg and tea leaves). The impacts of raw materials, pyrolysis temperatures (300, 400, 500, 600 and 700 °C), and residence time (2 h and 4 h) on the removal of ammonia nitrogen at different ammonia nitrogen concentrations (5, 10, 20, 50, 100, 150 mg/L) were investigated. The batch equilibrium and kinetic experiments confirmed that a FWBB dosage of 3 g/L at 25 °C could remove up to 92.67% ammonia nitrogen. The Langmuir isotherm model had the best fit to equilibrium experimental data with a maximum adsorption capacity of 7.174 mg/g at 25 °C. The pseudo-second order kinetic model well describes the ammonia nitrogen adsorption.

High Efficient Visible-Light Photocatalytic Performance of Cu/ZnO/rGO Nanocomposite for Decomposing of Aqueous Ammonia and Treatment of Domestic Wastewater.

Photocatalytic removal of ammonium-nitrogen ( NH4+ -N) from water using solar energy is an approach of high interest and applicability due to the convenience in application. ZnO has a great potential in photocatalytic decomposition of NH4+ -N and conversion of this nutrient to under visible light irradiations. However the applicability of pristine ZnO though is limited due to its reduced capacity to utilize light from natural light. Herein, we report a two-step ZnO-modified strategy (Cu-doped ZnO nanoparticles, immobilized on reduced graphene oxide (rGO) sheets) for the promotion of photocatalytic degradation of NH4+ -N under visible light. UV-Vis spectra showed that the Cu/ZnO/rGO can be highly efficient in the utilization of photons from the visible region. Hence, Cu/ZnO/rGO managed to demonstrate adequate photocatalytic activity and effective NH4+ -N removal from water under visible light compared to single ZnO. Specifically, up to 83.1% of NH4+ -N (initial concentration 50 mg·L-1, catalyst dosage 2 g·L-1, pH 10) was removed within 2 h retention time under Xe lamp irradiation. From the catalysis, the major by-product was N2. The high ammonia degradation efficiency from the ZnO/Cu/rGO is attributed to the improvement of the reactive oxygen species (ROSs) production efficiency and the further activation of the interfacial catalytic sites. This study also demonstrated that such nanocomposite is a recyclable agent. Its NH4+ -N removal capacity remained effective even after five batch cycles. In addition, Cu/ZnO/rGO was applied to treat real domestic wastewater, and it was found that chemical oxygen demand (COD), total nitrogen (TN) and total phosphorus (TP) removal efficiencies can reach 84.3, 80.7, and 90.3%, respectively. Thus, Cu/ZnO/rGO in the presence of solar light can be a promising photocatalyst in the field of wastewater treatment.

Effective removal of ammonia nitrogen from waste seawater using crystal seed enhanced struvite precipitation technology with response surface methodology for process optimization.

Traditional biological treatment was not effective for removing nitrogen from saline wastewater due to the inhibition of high salinity on biomass activity. In this context, a method of removing ammonia nitrogen from waste seawater was proposed by struvite precipitation which was enhanced by seeding technique. The abundant magnesium contained in waste seawater was used as the key component of struvite crystallization without additional magnesium. The effects of pH and P:N molar ratio on ammonia nitrogen removal efficiency were studied. The results showed that optimum pH value was in range of 8.5-10 and the P:N molar ratio should be controlled within 2:1-3:1. XRD and SEM-EDS analyses of the precipitates proved that Ca2+ and excess Mg2+ contained in waste seawater inhibited the struvite crystallization by competing PO43- to form by-products. Then, seeding technique for enhancing the struvite crystallization was investigated, and the results indicated that using preformed struvite as crystal seed significantly improved the ammonia nitrogen removal efficiency, especially when initial ammonia nitrogen concentration was relatively low. Moreover, response surface optimization experiment following a Box-Behnken design was conducted. A response surface model was established, based on which optimum process conditions were determined and interactions between various factors were clarified. At last, economic evaluation demonstrated this proposed method was economic feasible.