Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 20 de 23
Filtrar
1.
Environ Sci Technol ; 58(19): 8393-8403, 2024 May 14.
Artigo em Inglês | MEDLINE | ID: mdl-38691770

RESUMO

The chemistry of ozone (O3) on indoor surfaces leads to secondary pollution, aggravating the air quality in indoor environments. Here, we assess the heterogeneous chemistry of gaseous O3 with glass plates after being 1 month in two different kitchens where Chinese and Western styles of cooking were applied, respectively. The uptake coefficients of O3 on the authentic glass plates were measured in the dark and under UV light irradiation typical for indoor environments (320 nm < λ < 400 nm) at different relative humidities. The gas-phase product compounds formed upon reactions of O3 with the glass plates were evaluated in real time by a proton-transfer-reaction quadrupole-interface time-of-flight mass spectrometer. We observed typical aldehydes formed by the O3 reactions with the unsaturated fatty acid constituents of cooking oils. The formation of decanal, 6-methyl-5-hepten-2-one (6-MHO), and 4-oxopentanal (4-OPA) was also observed. The employed dynamic mass balance model shows that the estimated mixing ratios of hexanal, octanal, nonanal, decanal, undecanal, 6-MHO, and 4-OPA due to O3 chemistry with authentic grime-coated kitchen glass surfaces are higher in the kitchen where Chinese food was cooked compared to that where Western food was cooked. These results show that O3 chemistry on greasy glass surfaces leads to enhanced VOC levels in indoor environments.


Assuntos
Poluição do Ar em Ambientes Fechados , Culinária , Vidro , Ozônio , Compostos Orgânicos Voláteis , Ozônio/química , Vidro/química , Poluentes Atmosféricos
2.
Nutr Neurosci ; : 1-8, 2023 Nov 23.
Artigo em Inglês | MEDLINE | ID: mdl-37997257

RESUMO

Objectives: This study aimed to assess the contribution of edible/cooking oils and mayonnaise sauce in the severity, motor and non-motor symptoms, and risk of Parkinson's disease (PD).Methods: In this study, 120 patients with PD and 50 healthy individuals participated. The frequency and quantity of edible/cooking oils including animal and plant source oils (hydrogenated and nonhydrogenated) and mayonnaise sauce used by participants were determined using a food frequency questionnaire. The severity of PD was determined by the Unified Parkinson's Disease Rating Scale (UPDRS).Results: Patients with PD had lower use of hydrogenated plant-based oil (HPO) (p < 0.001) and animal oils (p < 0.001) but had higher use of non-hydrogenated plant-based oil (NHPO) (p < 0.001), olive oil (p = 0.02), and mayonnaise sauce (p < 0.001) compared with the healthy subjects. Use of each unit HPO reduced 4% the odds of PD (p = 0.01). The odds of PD increased 20% by each unit increase in NHPO usage (p = 0.001), 49% by olive oil (p = 0.02), and 127% by mayonnaise sauce (p = 0.004) intake. According to receiver operator characteristics curve analysis, mayonnaise sauce and NHPO had the largest area under the curve in predicting PD. Intake of animal oil was positively correlated with total score of UPDRS (p = 0.05) and motor symptoms (p = 0.04). Intake of butter was positively correlated with total score of UPDRS (p = 0.047), nonmotor aspects of experiences of daily living (p = 0.02), and motor examination (p = 0.02).Discussion: The findings indicate that high intake of HPO reduces, while high intake of NHPO, olive oil, and mayonnaise sauce increases the odds of PD.

3.
BMC Med ; 19(1): 92, 2021 04 15.
Artigo em Inglês | MEDLINE | ID: mdl-33853582

RESUMO

BACKGROUND: Increasing evidence highlights healthy dietary patterns and links daily cooking oil intake with chronic diseases including cardiovascular disease (CVD) and diabetes. However, food-based evidence supporting the consumption of cooking oils in relation to total and cardiometabolic mortality remains largely absent. We aim to prospectively evaluate the relations of cooking oils with death from cardiometabolic (CVD and diabetes) and other causes. METHODS: We identified and prospectively followed 521,120 participants aged 50-71 years from the National Institutes of Health-American Association of Retired Persons Diet and Health Study. Individual cooking oil/fat consumption was assessed by a validated food frequency questionnaire. Hazard ratios (HRs) and 95% confidence intervals (CIs) were estimated for mortality through the end of 2011. RESULTS: Overall, 129,328 deaths were documented during a median follow-up of 16 years. Intakes of butter and margarine were associated with higher total mortality while intakes of canola oil and olive oil were related to lower total mortality. After multivariate adjustment for major risk factors, the HRs of cardiometabolic mortality for each 1-tablespoon/day increment were 1.08 (95% CI 1.05-1.10) for butter, 1.06 (1.05-1.08) for margarine, 0.99 (0.95-1.03) for corn oil, 0.98 (0.94-1.02) for canola oil, and 0.96 (0.92-0.99) for olive oil. Besides, butter consumption was positively associated with cancer mortality. Substituting corn oil, canola oil, or olive oil for equal amounts of butter and margarine was related to lower all-cause mortality and mortality from certain causes, including CVD, diabetes, cancer, respiratory disease, and Alzheimer's disease. CONCLUSIONS: Consumption of butter and margarine was associated with higher total and cardiometabolic mortality. Replacing butter and margarine with canola oil, corn oil, or olive oil was related to lower total and cardiometabolic mortality. Our findings support shifting the intake from solid fats to non-hydrogenated vegetable oils for cardiometabolic health and longevity.


Assuntos
Doenças Cardiovasculares , Margarina , Manteiga , Culinária , Gorduras na Dieta , Humanos , Azeite de Oliva , Óleos de Plantas
4.
Arch Anim Nutr ; 75(5): 355-375, 2021 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-34461782

RESUMO

This research aimed to determine the effect of dietary supplementation of pomegranate peels powder and waste soybean cooking oil on the performance and meat quality of male Ross 308 broiler chickens. Before start of the experiment, the metabolisable energy of pomegranate peels and other nutritive and chemical contents of pomegranate peels were measured. Also, peroxidation indices and fatty acids profiles of experimental oils were analysed. The experiment was designed as a 3 × 3 × 2 factorial arrangement of treatments including i) pomegranate peels (0, 4 and 8%), ii) waste soybean cooking oil (0, 2 and 4%) and iii) vitamin E (0 and 200 mg/kg diet). Supplementation of 8% pomegranate peels significantly decreased growth performance of broiler chickens (p < 0.05). The supplementation of 4% waste cooking oil significantly reduced body weight gain during the grower and whole experimental period (p < 0.05). Pomegranate peels supplementation decreased peroxide value (PV) and thiobarbituric acid (TBA) and increased pH of meat (p < 0.05). Supplementation of 4% waste cooking oil increased PV and TBA and reduced crude protein, water holding capacity (WHC), and pH of meat (p < 0.05). Vitamin E supplementation significantly decreased TBA and increased WHC of meat (p < 0.05). Supplementation of pomegranate peels decreased saturated fatty acids (SFA) and increased polyunsaturated fatty acids (PUFA) of meat (p < 0.05). Broilers fed diets with 4% waste cooking oil showed higher SFA and lower PUFA contents in meat (p < 0.05). So it can be concluded that 4% pomegranate peels could be used as an alternative feed ingredient and a source of antioxidants in broiler diets, and also 2% waste soybean cooking oil can be included as feed ingredient in broiler diets without adversely affecting performance.


Assuntos
Punica granatum , Vitamina E , Ração Animal/análise , Animais , Galinhas , Culinária , Dieta/veterinária , Suplementos Nutricionais/análise , Ácidos Graxos , Carne/análise , Óleo de Soja , Glycine max
5.
J Nutr ; 150(7): 1799-1807, 2020 07 01.
Artigo em Inglês | MEDLINE | ID: mdl-32364230

RESUMO

BACKGROUND: Evidence suggests that the relations between intakes of individual fatty acids and risk of type 2 diabetes (T2D) vary. However, associations between intakes of different cooking oils as sources of fatty acids and incident T2D remain largely unknown. OBJECTIVES: We aimed to evaluate relations between intakes of individual cooking oils and incident T2D in a nationwide Chinese cohort. METHODS: Overall 15,022 Chinese adults aged ≥20 y from the China Health and Nutrition Survey (CHNS) without self-reported T2D at entry in the 1997, 2000, 2004, 2006, or 2009 rounds were followed up until 2011. Consumption of various cooking oils/fats including lard, peanut oil, soybean oil, canola oil, sesame oil, and refined blended plant oil was assessed using 3-d 24-h records in each survey and the cumulative mean intake was calculated. Multivariable-adjusted Cox proportional hazards regression models were constructed to estimate the HRs of T2D. RESULTS: A total of 1014 cases were recorded after a median follow-up of 14 y. The intakes of animal and plant cooking oils/fats were both associated with higher T2D risk. Compared with nonconsumers, multivariable-adjusted HRs and 95% CIs for the highest tertiles were 1.31 (1.03, 1.67) for lard, 1.36 (1.10, 1.66) for peanut oil, 1.14 (0.91, 1.43) for soybean oil, 1.11 (0.87, 1.43) for canola oil, 1.02 (0.79, 1.32) for sesame oil, and 1.42 (1.12, 1.82) for refined blended plant oil. Substituting 1 tablespoon/d (8 g · 2000 kcal-1 · d-1) of soybean oil for the sum of lard, peanut oil, refined blended plant oil, and other plant oils was associated with a 3% (HR: 0.97; 95% CI: 0.95, 0.99) lower risk of T2D. CONCLUSIONS: Intakes of lard, peanut oil, and refined blended plant oil but not soybean oil, canola oil, and sesame oil are associated with higher T2D risk. Reducing the consumption of cooking oils in general may be protective against T2D among the Chinese population.This trial was registered at clinicaltrials.gov as NCT03259321.


Assuntos
Povo Asiático , Culinária , Diabetes Mellitus Tipo 2/induzido quimicamente , Gorduras na Dieta , Óleos de Plantas , Adulto , China , Estudos de Coortes , Dieta , Feminino , Humanos , Masculino
6.
J Pak Med Assoc ; 67(6): 957-958, 2017 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-28585605

RESUMO

Fats and oils are one of the very important components of diet. However excess of either overall fat or certain kind of fats in the diet may result in negative health impacts including risk of obesity, dyslipidaemia, cardiovascular diseases and certain malignancies. It is thus important to have an optimum amount of fat in the diet, and also important to choose appropriate sources of fat in the diet. In this mini review we suggest pragmatic selection of cooking oils for optimum health benefits.


Assuntos
Culinária , Gorduras Insaturadas/química , Ghee , Óleos de Plantas/química , Dieta Saudável , Gorduras na Dieta , Gorduras/química , Ácidos Graxos/química , Humanos
7.
Public Health Nutr ; 18(18): 3260-4, 2015 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-25757509

RESUMO

OBJECTIVE: Long-chain n-3 fatty acid intake in Colombia is low because fish consumption is limited. Vegetable oils with high n-3 fatty acid content are recommended, but their concentrations of trans fats were high in previous studies. Thus, regular monitoring of the fatty acid composition of vegetable oils is required. Our objective was to quantify the fatty acid composition in commercially available oils in Bogota, Colombia and determine if composition changed from 2008 to 2013. DESIGN: Cross-sectional study. We obtained samples of all commercially available oils reported in a survey of low- and middle-income families with a child participating in the Bogota School Children Cohort. SETTING: Bogota, Colombia. SUBJECTS: Not applicable. RESULTS: Sunflower oil had the highest trans-fatty acid content (2.18%). Canola oil had the lowest proportion of trans-fatty acids (0.40%) and the highest n-3 fatty acid content (9.37%). In terms of percentage reduction from 2008 to 2013 in 18:1 and 18:2 trans-fatty acids, canola oil had 89% and 65% reduction, mixed oils had 44% and 48% reduction, and sunflower oil had 25% and 51 % reduction, respectively. Soyabean oil became widely available in 2013. CONCLUSIONS: The content of trans-fatty acids decreased in all oils from 2008 to 2013, suggesting a voluntary reduction by industry. We believe that regular monitoring of the fatty acid composition of oils is warranted.


Assuntos
Culinária , Gorduras Insaturadas na Dieta/análise , Fidelidade a Diretrizes , Política Nutricional , Óleos de Plantas/química , Ácidos Graxos trans/análise , População Urbana , Estudos de Coortes , Colômbia , Custos e Análise de Custo , Estudos Transversais , Inquéritos sobre Dietas , Gorduras Insaturadas na Dieta/administração & dosagem , Gorduras Insaturadas na Dieta/efeitos adversos , Gorduras Insaturadas na Dieta/economia , Família , Rotulagem de Alimentos , Indústria de Processamento de Alimentos/economia , Indústria de Processamento de Alimentos/tendências , Humanos , Renda , Óleos de Plantas/administração & dosagem , Óleos de Plantas/efeitos adversos , Óleos de Plantas/economia , Ácidos Graxos trans/administração & dosagem , Ácidos Graxos trans/efeitos adversos , Ácidos Graxos trans/economia
8.
Life (Basel) ; 14(3)2024 Feb 27.
Artigo em Inglês | MEDLINE | ID: mdl-38541638

RESUMO

Anaerobic co-digestion of waste wheat straw and horse manure in two steps was revealed as a promising option for renewable energy production in the form of hydrogen and methane. Addition of waste cooking oils, disposal of which could cause damage to health or the environment, as a third substrate for digestion, is suggested as an approach not only to help handle the increasing volume of food waste worldwide but also to improve process performance. In the present study, waste cooking oil, in a concentration of 5%, appeared to be a positive modulator of anaerobic digestion with the production of hydrogen and did not lead to inhibition of the hydrolysis phase. The overall efficiency of the two-stage anaerobic digestion of the mixture, which contains mainly lignocellulose waste, is positively dependent on thermochemical pretreatment with the alkali reagent (Ca(OH)2), but elevated temperature (55 °C) and cooking oil addition revealed the opportunity to omit the pre-treatment step. Nevertheless, the overall energy production was lower due to the methane production step. However, the addition of waste cooking oils to the process in which lig-nocellulose is not pretreated (V3) led to an increase in the methane production and energy yield compared to V1. The anaerobic digestion of lignocellulosic waste is a complex process and comprises successive degradation pathways and syntrophic microbial associations' activities, so the division in two reactors ensured suitable conditions for the microorganisms residing in each of them. In this study, along with the production of hydrogen and methane and the separation of the hydrolysis and methanogenesis stages, utilization of agriculture- and kitchen-generated wastes was realized in the context of waste-to-energy sustainable production methods.

9.
Appl Biochem Biotechnol ; 195(1): 432-450, 2023 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-36087232

RESUMO

The enzymatic production of biodiesel from waste cooking oils (WCOs) offers a green and sustainable solution for the liquid fuel manufacture as well as waste resource recovery. In present study, liquid lipase was used to simplify the catalysis process, thereby reducing biodiesel production costs. An engineered Escherichia coli expressing Geobacillus thermocatenulatus lipase 2 (GTL2) was screened at an enzyme activity of 6.96 U/mg, after evaluating the propagating stability of the recombinant plasmids exceeding 86.11%. Through the beneficial feeding strategy and effective pH control, high-level production of GTL2 by fed-batch fermentation was achieved with an enzyme activity of 434.32 U/mg, which was almost 62 times that of shake flask fermentation. In addition, liquid GTL2 was used to prepare fatty acid methyl esters (FAMEs) using WCOs. The effects of the reaction time, catalyst loading, temperature, and methanol-to-oil molar ratio on FAMEs production using WCOs were explored, and a maximum FAMEs yield of 96.62% was achieved under optimized conditions. These results indicate that liquid GTL2 is a promising biocatalyst for efficient utilization of WCOs in the synthesis of biodiesel and provide a novel enzymatic process for biodiesel reducing the cost of production.


Assuntos
Biocombustíveis , Lipase , Lipase/química , Fermentação , Escherichia coli/genética , Escherichia coli/metabolismo , Esterificação , Enzimas Imobilizadas/química , Óleos , Catálise , Culinária , Óleos de Plantas/química
10.
Heliyon ; 9(11): e21500, 2023 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-38027829

RESUMO

Purpose: This review aims to examine the potential of oleogels as a frying medium to decrease oil absorption during deep-frying and enhance the nutritional and energy content of foods. By investigating the factors influencing oil incorporation during deep-frying and examining the application of oleogels in this process, we seek to provide insights into using oleogels as an alternative to traditional cooking oils. Scope: Deep-frying, a widely used cooking method, leads to the retention of large amounts of oil in fried food, which has been associated with health concerns. To address this issue, researchers have investigated various methods to minimize oil absorption during frying. One promising approach is the use of oleogels, which are thermo-reversible, three-dimensional gel networks formed by entrapment of bulk oil with a low concentration (<10% of weight) of solid lipid materials known as oleogelators. This review will focus on the following aspects: a) an overview of deep-fried foods, b) factors influencing oil uptake and underlying mechanisms for oil absorption during deep-frying, c) the characterization and application of different frying oils and their oleogels in deep-fried foods, d) components of the oleogel system for deep-frying, and e) the health impact, oxidative stability, and sensory acceptability of using oleogels in deep-frying. Key findings: The review highlights the potential of oleogels as a promising alternative frying medium to reduce fat absorption in deep-fried foods. Considering the factors influencing oil uptake during deep-frying, as well as exploring the properties and applications of different frying oils and their oleogels, can result in improved product qualities and heightened consumer acceptance. Moreover, oleogels offer the advantage of lower fat content in fried products, addressing health concerns associated with traditional deep-frying methods. The capacity to enhance the nutritional and energy profile of foods while preserving sensory qualities and oxidative stability positions oleogels as a promising choice for upcoming food processing applications.

11.
Enzyme Microb Technol ; 163: 110164, 2023 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-36455467

RESUMO

The development of biorefinery approaches is of great relevance for the sustainable production of valuable compounds. In accordance with circular economy principles, waste cooking oils (WCOs) are renewable resources and biorefinery feedstocks, which contribute to a reduced impact on the environment. Frequently, this waste is wrongly disposed of into municipal sewage systems, thereby creating problems for the environment and increasing treatment costs in wastewater treatment plants. In this study, regenerated WCOs, which were intended for the production of biofuels, were transformed through a chemo-enzymatic approach to produce hydroxy fatty acids, which were further used in polycondensation reaction for polyester production. Escherichia coli whole cell biocatalyst containing the recombinantly produced Elizabethkingia meningoseptica Oleate hydratase (Em_OhyA) was used for the biocatalytic hydration of crude WCOs-derived unsaturated free fatty acids for the production of hydroxy fatty acids. Further hydrogenation reaction and methylation of the crude mixture allowed the production of (R)- 10-hydroxystearic acid methyl ester that was further purified with a high purity (> 90%), at gram scale. The purified (R)- 10-hydroxystearic acid methyl ester was polymerized through a polycondensation reaction to produce the corresponding polyester. This work highlights the potential of waste products to obtain bio-based hydroxy fatty acids and polyesters through a biorefinery approach.


Assuntos
Ácidos Graxos , Poliésteres , Óleos , Biocombustíveis , Ácidos Graxos Insaturados , Culinária , Ésteres
12.
Foods ; 12(6)2023 Mar 15.
Artigo em Inglês | MEDLINE | ID: mdl-36981180

RESUMO

INTRODUCTION: Toxic aldehydic lipid oxidation products (LOPs) arise from the thermo-oxidative deterioration of unsaturated fatty acids present in heated culinary oils when exposed to high-temperature frying episodes, and currently these effects represent a major public health concern. OBJECTIVES: In this study, we investigated the applications of low-field (LF), benchtop NMR analysis to detect and quantify toxic aldehyde species in culinary oils following their exposure to laboratory-simulated shallow frying episodes (LSSFEs) at 180 °C. Four culinary oils of variable fatty acid (FA) composition were investigated to determine the analytical capabilities of the LF NMR instrument. Oil samples were also analysed using a medium-field (400 MHz) NMR facility for comparative purposes. RESULTS: Aldehydes were quantified as total saturated and total α,ß-unsaturated classes. The time-dependent production of α,ß-unsaturated aldehydes decreased in the order chia > rapeseed ≈ soybean > olive oils, as might be expected from their polyunsaturated and monounsaturated FA (PUFA and MUFA, respectively) contents. A similar but inequivalent trend was found for saturated aldehyde concentrations. These data strongly correlated with medium-field 1H NMR data obtained, although LF-determined levels were significantly lower in view of its inability to detect or quantify the more minor oxygenated aldehydic LOPs present. Lower limit of detection (LLOD) values for this spectrometer were 0.19 and 0.18 mmol/mol FA for n-hexanal and trans-2-octenal, respectively. Aldehydic lipid hydroperoxide precursors of aldehydic LOPs were also detectable in LF spectra. CONCLUSIONS: We therefore conclude that there is scope for application of these smaller, near-portable NMR facilities for commercial or 'on-site' quality control determination of toxic aldehydic LOPs in thermally stressed frying oils.

13.
R Soc Open Sci ; 9(4): 211554, 2022 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-35601448

RESUMO

The acid-promoted epoxidation of vegetable oils was studied using a variety of acidic ion exchange resins as heterogeneous acid catalysts. Quantitative and selective epoxidation of a series of vegetable oils with different composition of saturated, mono-, di- and tri-unsaturated fatty acids was obtained upon identification of the more efficient catalyst and experimental conditions. Furthermore, optimized reaction conditions were successfully applied to the epoxidation of a waste cooking oil, thus extending our procedure to the valorization of a biowaste, an area of increasing importance within a more sustainable society. The use of quantitative 1HNMR besides making accurate evaluation of the amounts of reagents to be employed and of the selectivity, allowed facile and rapid quantification of mono-, di- and tri-epoxides, thus providing an indirect indication on the fatty acid composition of the vegetable oils, even in the presence of very low quantities of linolenic acid.

14.
Waste Manag ; 136: 219-229, 2021 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-34700162

RESUMO

Biodiesel production from edible sources faces several challenges such as food security and cost issues. Waste cooking oils (WCOs) can be an alternative feedstock due to their large production. The comprehensive characterization of WCOs has been rarely reported in previous studies. In this study, six different WCOs including chicken oil (CO), fat, oil, and grease (FOG), beef hotpot oil (BHP), mixed waste cooking oil (MWO), duck oil (DO), and vegetable hotpot oil (VHP) were assessed for the biodiesel production. Lipid content of WCOs ranged from 73 to 84.5% with the highest C16 in DO (32.1%) and C18 in VHP (71.4%). The highest saturated (such as C16:0 and C18:0), monounsaturated (such as C18:1) and poly unsaturated (such as C18:2, and C18:3) fatty acids were 58%, 59%, and 21% in BHP, VHP, and MWO, respectively. The diverse nature of fatty acids in WCOs makes it highly recommended for biodiesel production, as its derived biodiesel complied with international standards. Fourier transform infrared spectroscopy confirmed the presence of linkages specific to lipid and thermogravimetric analysis showed high volatile matter content (>97%). Biochemical composition, fatty acids profile, and the properties of the produced biodiesel demonstrated that these WCOs could be promising candidates for biodiesel production, solving waste management and socio-economic challenges of conventional feedstocks. However, the commercialization of WCOs' biodiesel requires further investigation of produced biodiesel and their petro-diesel blends on the engine performance, efficiency, and emissions (SO×, NO×, and CO×) parameters to produce quality and cost-effective biodiesel.


Assuntos
Biocombustíveis , Culinária , Animais , Biocombustíveis/análise , Bovinos , Ácidos Graxos , Lipídeos , Óleos de Plantas
15.
Bioresour Bioprocess ; 8(1): 78, 2021 Aug 23.
Artigo em Inglês | MEDLINE | ID: mdl-38650210

RESUMO

Producing high value-added products from waste lipid feedstock by microbial cell factory has great advantages to minimize the pollution as well as improve the economic value of wasted oils and fats. Yarrowia lipolytica is a non-conventional oleaginous yeast and can grow on a variety of hydrophobic substrates. In this study, we explored its ability to synthesize α-farnesene, an important sesquiterpene, using lipid feedstock. Based on the α-farnesene production strain, we constructed previously, we identified that Erg12 was the key limiting factor to further increase the α-farnesene production. The α-farnesene production was improved by 35.8% through increasing the copy number of ERG12 and FSERG20 on oleic acid substrate. Expression of heterologous VHb further improved α-farnesene production by 12.7%. Combining metabolic engineering with the optimization of fermentation conditions, the α-farnesene titer and yield reached 10.2 g/L and 0.1 g/g oleic acid, respectively, in fed-batch cultivation. The α-farnesene synthesis ability on waste cooking oil and other edible oils were also explored. Compared with using glucose as carbon source, using lipid substrates obtained higher α-farnesene yield and titer, but lower by-products accumulation, demonstrating the advantage of Y. lipolytica to synthesize high value-added products using lipid feedstock.

16.
J Forensic Sci ; 66(2): 534-546, 2021 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-33136299

RESUMO

Analysis of fire debris for triglyceride-based oils may be of interest to fire investigators depending on the circumstances of a particular fire. Such circumstances include accidental or intentionally set cooking oil fires, fires involving triglyceride-based "eco" fire log products, and spontaneous ignition fires that involve drying oils on rags. Many forensic laboratories utilize gas chromatography-mass spectrometry following fatty acid methyl esterification to identify triglyceride residues in fire debris extracts. This study explores an alternate approach, which involves the identification of intact triglycerides by liquid chromatography-mass spectrometry-mass spectrometry (LC-MS/MS). 52 triglyceride-based oils and fats (22 different types) were analyzed by LC-MS/MS using multiple reaction monitoring to investigate variation in triglyceride content between different brands and types of oil and fat. Selected oils were then degraded by exposure to air, typical cooking conditions and/or fire conditions to simulate samples that are typically encountered by Fire Debris Analysts in fire investigation cases. Triglycerides were identified in all pristine and degraded oil samples, and relative peak areas for degraded samples often resembled their pristine oil counterparts. In samples where relative peak area differences were noted, more predominant degradation was observed for triglycerides with a higher proportion of poly-unsaturated fatty acids. Variability in triglyceride content between different brands and types of oil are discussed, as well as factors affecting the identification of triglyceride peaks in commercial oil samples, as compared to the corresponding analytical standard.

17.
Clin Nutr ; 39(12): 3703-3710, 2020 12.
Artigo em Inglês | MEDLINE | ID: mdl-32359931

RESUMO

BACKGROUND & AIMS: Evidence linking individual cooking oil consumption with total mortality is limited in China. The aim of this study was to examine the associations of intakes of plant-sourced and animal-sourced cooking oils with total mortality in a Chinese nationwide cohort. METHODS: We analyzed data from 14,305 adults aged ≥20 y at entry in the China Health and Nutrition Survey (CHNS). The 3-day 24-h dietary records were used to collect dietary information. Cox proportional hazards regression models were established to estimate hazard ratios (HRs) and 95% confidence intervals (CIs) of all-cause death. RESULTS: Overall 1006 deaths were documented during a median of 14 years (199,091 person-years) of follow-up. Multivariate-adjusted HRs (95% CIs) of total mortality via comparing the highest tertile of cooking oil consumption with no consumption were 0.86 (0.70-1.06) for lard, 0.59 (0.47-0.74) for peanut oil, 0.71 (0.54-0.93) for soybean oil, 0.76 (0.61-0.94) for canola oil, 0.71 (0.50-0.99) for salad oil, and 0.59 (0.44-0.79) for other plant cooking oils. Replacing animal cooking oils with 1 tablespoon/d of total plant cooking oils or other plant cooking oils was related to 4% or 17% lower total mortality, respectively, while consumption of peanut oil or salad oil in replacement of animal cooking oils had a marginal inverse association with total mortality. CONCLUSIONS: Intakes of plant-sourced cooking oils, including peanut oil, soybean oil, canola oil, salad oil, and other plant cooking oils and substituting plant cooking oils for animal cooking oils were associated with lower total mortality among general Chinese population (NCT03259321).


Assuntos
Dieta/mortalidade , Gorduras na Dieta/análise , Óleos de Plantas/análise , Adulto , Idoso , China/epidemiologia , Culinária , Dieta/métodos , Características da Família , Feminino , Humanos , Estudos Longitudinais , Masculino , Pessoa de Meia-Idade , Inquéritos Nutricionais , Modelos de Riscos Proporcionais , Estudos Prospectivos
18.
Food Chem Toxicol ; 144: 111648, 2020 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-32745572

RESUMO

Deep-frying is the most common food preparation method, manifestations of color, taste, flavor, and fried consistency. The beneficial role of vegetable oils become deteriorate when repeatedly treated with higher temperature and air. Repeatedly heated cooking oils (RCO) produce various byproducts, containing polycyclic aromatic hydrocarbons (PAHs) and aldehydes, well-known to be a carcinogenic, mutagenic, and tumorigenic properties. RCO is nowadays one of the often consumed media for cooking and frying, which intake can cause various unhealthy adverse effects including various cancer in the multiple organs. Hence, the present comprehensive study targets to provide the intake of RCO elevate the risks of human breast cancer. The data on RCO and its impacts were obtained via various electronic findings and library databases. Notable studies have confirmed that the effects of RCO have been attributed to their unfavorable effects, and underlying molecular mechanisms can also strongly promoting tumorigenic effects in the mammary organ.


Assuntos
Aldeídos/toxicidade , Neoplasias da Mama/induzido quimicamente , Culinária , Mutagênicos/toxicidade , Metástase Neoplásica , Neoplasias da Mama/patologia , Feminino , Humanos , Hidrocarbonetos Policíclicos Aromáticos/toxicidade , Fatores de Risco
19.
Waste Manag ; 78: 611-620, 2018 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-32559952

RESUMO

The article quantifies, in a set of 23 countries, the amounts consumed of vegetable oils, the amounts of used oils produced after cooking, the amounts available for valorisation, and finally the quantities being valorised. The management practices adopted are also reviewed. Based on data collected, a production factor, relating vegetable oil consumption with used cooking oil production, of 0.32 is proposed. The valorisation factor, which quantifies the fraction of UCO being valorised, is higher in better performing countries (0.749) and worst in the remaining (0.232). Three consumption-valorisation factors, relating consumption with valorisation, were obtained: for high performing countries (0.274); intermediate performing (0.105); and under-performing (0.078). The management systems adopted by the different countries are based on either second-generation economic instruments (USA and Brazil), or on third-generation economic instruments (EU, Argentina, Japan). The former has allowed countries to attain better valorisation rates.

20.
J Agric Food Chem ; 66(19): 4977-4984, 2018 May 16.
Artigo em Inglês | MEDLINE | ID: mdl-29716192

RESUMO

Lipids account for a high proportion of dietary calories, which greatly affect human health. As a result of differences in composition of fatty acid of individual cooking oils, certain biological effects of these oils may vary. This study aimed to compare postprandial metabolomic profiles of six commonly consumed cooking oils/fats. Adopting a switch-over experimental design ( n = 15), we carried out a human feeding study with six groups (control without oils, soybean oil, olive oil, palm oil, camellia oil, and tallow) and collected fasting and postprandial serum samples. The metabolomic profile was measured by ultra-high-pressure liquid chromatography-quadrupole time of flight. We observed significant differences between the control group and experimental groups for 33 serum metabolites (false discovery rate; p < 0.05), which take part in lipid digestion, fatty acid metabolism, metabolism of pyrimidines and pyrimidine nucleosides, amino acid metabolism, neurobiology, and antioxidation. Sparse partial least squares discriminant analysis revealed distinct metabolomics patterns between monounsaturated fatty acid (MUFA) and saturated fatty acid oils, between soybean oil, olive oil, and palm oil, and between two MUFA-rich oils (olive and camellia oils). The present metabolomics study suggests shared and distinct metabolisms of various cooking oils/fats.


Assuntos
Óleos de Plantas/metabolismo , Adulto , Culinária , Gorduras na Dieta/metabolismo , Ácidos Graxos/metabolismo , Humanos , Masculino , Metabolômica , Pessoa de Meia-Idade , Período Pós-Prandial , Triglicerídeos/metabolismo , Adulto Jovem
SELEÇÃO DE REFERÊNCIAS
DETALHE DA PESQUISA