Groundwater hydro-geochemistry, quality, microbiology and human health risk assessment in semi-arid area of Rajasthan, India: a chemometric approach.

The present investigation focused on groundwater hydro-geochemistry of Alsisar block of Jhunjhunu district, India, aims on evaluating the quality of groundwater for drinking and irrigation purposes and assessing the human health risk from ingestion of groundwater. The groundwater of Alsisar block is neutral to alkaline, brackish and very hard in nature. Total dissolved solids, total hardness, Na+, Mg2+, HCO3-, F- and NO3- in majority of the groundwater samples were exceeding the World Health Organization and Bureau of Indian Standards recommended limits. The drinking water quality index ranged from 111.53 to 492.84. None of the sample belonged to excellent and good categories of drinking water quality. Fluoride varied from 0.018 to 4.176 mg L-1, and nitrate varied from 0.34 to 520.66 mg L-1 in groundwater. The non-carcinogenic risk assessment for children, men and women owing to ingestion of fluoride and nitrate-enriched groundwater indicates human health risks in the entire study area. Irrigation with groundwater of Alsisar block is liable to cause salinity and magnesium hazard to agricultural crops grown in the area. Source apportionment using principal component analysis suggests the geogenic origin of fluoride and anthropogenic origin of nitrate. Na+-Mg2+-Cl- followed by Na+-Mg2+-HCO3- are the predominant hydrochemical facies in the groundwater of Alsisar block. Silicate rock weathering, ion exchange and evaporation are the predominating processes governing ionic concentrations in the groundwater. Biochemical and molecular tests demonstrated the presence of Brevibacillus borstelensis strain DSM 6347 16s rRNA and Bacillus paramycoides strain MCCC 1A04098 16s rRNA in the groundwater of the area.

Geospatial Distributions of Groundwater Quality in Gedaref State Using Geographic Information System (GIS) and Drinking Water Quality Index (DWQI).

The observation of groundwater quality elements is essential for understanding the classification and distribution of drinking water. Geographic Information System (GIS) and remote sensing (RS), are intensive tools for the performance and analysis of spatial datum associated with groundwater sources control. In this study, groundwater quality parameters were observed in three different aquifers including: sandstone, alluvium and basalt. These aquifers are the primary source of national drinking water and partly for agricultural activity in El Faw, El Raha (Fw-Rh), El Qalabat and El Quresha (Qa-Qu) localities in the southern part of Gedaref State in eastern Sudan. The aquifers have been overworked intensively as the main source of indigenous water supply in the study area. The interpolation methods were used to demonstrate the facies pattern and Drinking Water Quality Index (DWQI) of the groundwater in the research area. The GIS interpolation tool was used to obtain the spatial distribution of groundwater quality parameters and DWQI in the area. Forty samples were assembled and investigated for the analysis of major cations and anions. The groundwater in this research is controlled by sodium and bicarbonate ions that defined the composition of the water type to be Na HCO3. However, from the plots of piper diagram; the samples result revealed (40%) Na-Mg-HCO3 and (35%) Na-HCO3 water types. The outcome of the analysis reveals that several groundwater samples have been found to be suitable for drinking purposes in Fa-Rh and Qa-Qu areas.