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1.
Environ Res ; 212(Pt D): 113490, 2022 09.
Artigo em Inglês | MEDLINE | ID: mdl-35594958

RESUMO

Electro-dewatering technology shows a good application prospect because of its high efficiency in removing water from sludge and low energy consumption, but the potential mechanisms of sludge electro-dewatering have not been investigated in depth, which seriously limits the further development and application of electro-dewatering technology. In this study, the effects of voltage and pressure on sludge electro-dewatering performance, physicochemical characteristics and extracellular polymeric substances (EPS) compositions and distributions were investigated. The spatial distributions of EPS main components, including polysaccharide (PS) and protein (PN), were characterized by a confocal laser scanning microscopy (CLSM). The experimental results showed that under the conditions of a voltage of 40 V and a pressure of 90 kPa, the moisture content of sludge was reduced from 83.15% to 53.12%, and the bound water content of sludge in the anode layer, middle layer and cathode layer were decreased significantly from 1.16 g/g dry solid (DS) to 0.20, 0.47 and 0.35 g/g DS, respectively. The PN content of EPS in anode layer was significantly lower than that in cathode layer due to the electrochemical oxidation, while the variation of PS content showed the opposite trend, which agreed with the results visualized by CLSM. Pearson's correlation coefficient and hierarchical cluster analysis revealed that PN in TB-EPS was the major factor influencing the effect of sludge electro-dewatering. This work can be helpful to understand the potential mechanisms of electro-dewatering and provide theoretical support for the further popularization and application of electro-dewatering technology.


Assuntos
Matriz Extracelular de Substâncias Poliméricas , Esgotos , Eletrodos , Matriz Extracelular de Substâncias Poliméricas/química , Proteínas , Esgotos/química , Eliminação de Resíduos Líquidos/métodos , Águas Residuárias/análise , Água/química
2.
Environ Res ; 214(Pt 3): 113974, 2022 11.
Artigo em Inglês | MEDLINE | ID: mdl-35952734

RESUMO

The addition of sludge-based biochar during electrochemical pretreatment of sewage sludge, as an efficient hybrid technology, is potentially to be applied in sludge deep-dewatering. The chars functioned as conductors, catalysts and skeleton particles could enhance the sludge dewaterability and increase the calorific value of the dewatered sludge cake. However, the effect of synthesis conditions on the char properties and further on the dewatering performance is still unknown. Herein, the sludge-based particle electrodes (SPEs) under three main synthesis conditions, including liquid-solid ratio, pyrolysis temperature and time, were prepared. The sludge-based biochars (i.e., SPE-400, SPE-600, and SPE-800 pyrolyzed under 400, 600 and 800 °C, respectively) were characterized and utilized as three-dimensional electrodes during sludge electrolysis. The increased pyrolysis temperature (within 400-800 °C) resulted in the enrichment of metallic ions and increment of specific surface area and pore volume of SPE, which led to the increased catalysis and adsorption sites for viscous proteins (PNs). Particularly, the pores of SPE-800 provided more drainage channels as skeleton builders. Compared with raw sludge, the capillary suction time (CST) and the specific resistance of filtration (SRF) of the treated sludge with 3D-SPE-800 were reduced by 58.12% and 81.01%, respectively, but the net sludge solids yield (YN) was increased by 87.05%. The highest decrease of hydrophilic α-Helix content in PNs (from 9.93% to 7.30%) was observed when using SPE-800 as particle electrode, revealing the crucial role of char characteristics on protein reduction and subsequent dewatering enhancement. The synergistic effects of electrolysis and sludge-based biochar provided a new insight for a closed-loop pretreatment of sewage sludge in the wastewater treatment plant.


Assuntos
Carvão Vegetal , Esgotos , Carvão Vegetal/química , Eletrólise , Filtração , Esgotos/química , Eliminação de Resíduos Líquidos/métodos , Água
3.
Environ Res ; 201: 111510, 2021 10.
Artigo em Inglês | MEDLINE | ID: mdl-34147466

RESUMO

Electro-dewatering of sludge has received considerable attention due to its low energy consumption for sludge deep-dewatering. However, prior studies have shown the resistance of dried sludge near anode significantly hinders electro-dewatering. The dewatering performance may be improved by reducing the resistance with the addition of conductive material into sludge. We conditioned municipal sludge by anthracite powder, an inexpensive product, to increase solid conductivity, followed by electro-dewatering. After running for 20 min under a constant voltage of 30 V, when the anthracite powder mass was 10%-22% of raw sludge dry solids mass (DS), the final dry solids content of the mud cake after dehydration was 6.2%-12.9% higher than that from dehydration of unconditioned sludge. The average filtrate flow rate ranged from 0.0243 to 0.0285 g s-1. The lowest unit energy consumption, 0.19 kW h·kgwater-1, which was 14% lower than that of control, was reached when 18% DS of anthracite was added. Our theoretical analysis indicates that properly increasing solid conductivity of sludge can reduce the adverse effect caused by the high electrical resistance of sludge near anode. The experimental results, along with the theoretical analysis, show that using anthracite powder for sludge modification is an economical approach to improve sludge dewatering rate and reduce energy consumption.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Carvão Mineral , Pós , Águas Residuárias , Água
4.
Environ Res ; 198: 110453, 2021 07.
Artigo em Inglês | MEDLINE | ID: mdl-33188765

RESUMO

The high energy consumption of high apparent electrical resistivity (AER) in sludge during the later stages of the electro-dewatering (EDW) process is a difficult problem; however, analysis of sludge AER may contribute to a reduction in energy consumption. In this study, the variations in the AER of activated sludge and potential mechanisms related to sludge properties were systematically examined. First, a sludge cake was divided into four horizontal layers, in order to investigate the sludge AER in each layer. Then, the effects of variations in water distribution, oxidation-reduction potential (ORP), pH, metal ions, sludge conductivity, zeta potential, temperature, and sludge microstructure on the AER in each layer were explored. The results showed that the sludge AER began to increase from the bottom layers to the top layers when the moisture content (MC) was decreased to 60%. The formation of nonionic chemical systems and the gas barrier layer could increase the AER in the top layers, and the increase in sludge AER in the bottom layers was due to the decrease in MC and sludge conductivity. In addition, electrolyte release and electromigration had a significant effect on the sludge AER. This work identifies potential causes for the increase in AER, and provides a reference for solving problems related to high AER in sludge during the later stages of the EDW process.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Eletricidade , Águas Residuárias , Água
5.
J Environ Sci (China) ; 101: 339-350, 2021 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-33334528

RESUMO

The increase of electrical resistance (ER) and energy consumption (EC) during the later stage of dewatering is a major problem hindering the development of electro-dewatering (EDW) technology. As the variations of sludge characteristics are significant during the EDW process, the relationships between sludge characteristics and ER and EC during EDW remain unclear. In this study, the effects of moisture content (MC), thickness, pH, conductivity, zeta potential, temperature, and gas volume on the ER and EC during the EDW process were statistically investigated using correlation and multiple linear regression analyses. Herein, the results showed that the ER of the sludge near the anode was primarily affected by pH, whereas the sludge near the cathode was primarily affected by the MC and conductivity. Further, sludge temperature and conductivity were the most reliable indicators to predict the EC near the anode and cathode, respectively. The results of this study provide theoretical guidance useful for solving the increase of ER and EC during the later stage of the EDW process.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Condutividade Elétrica , Impedância Elétrica , Eletrodos , Água
6.
Environ Res ; 186: 109487, 2020 07.
Artigo em Inglês | MEDLINE | ID: mdl-32334167

RESUMO

The efficiency of common sludge electro-dewatering (EDW) is restrained by the following issues: 1, the near-anode sludge dries out quickly, causing a rapid increase in electrical resistance; 2, the pH at anode decreases by the accumulation of H+ from the electrolysis of moisture, resulting in a decrease in Zeta potential (ζ). Alleviating the negative impact of these problems is the key to improving the dewatering efficiency of EDW. Therefore, in this study, calcium oxide (CaO) was used for near-anode sludge modification to increase its pH and electrical conductivity. With increasing CaO dosage, pH rose from 6.0 to 12.2, electrical conductivity increased from 368 ± 16 µS/cm to 6285 ± 21 µS/cm and the ζ declined from -15.3 ± 0.6 mV to -8.8 ± 0.4 mV. The EDW tests were conducted at 30 V and 25.5 kPa. The results indicate near-anode sludge modification with CaO weighing 3%-5% mass of raw sludge (mu(RS)) improved the EDW effect, while the energy consumption increased slightly. When 3%-5% mu(RS) of CaO was added, the final moisture content of sludge was 54.5%-44.3%, below that of the blank group (no CaO added), which was 57.9%; the time to obtain target moisture content (60%) was 910 s-590 s, lower than the blank group's 1060 s; and the energy consumption to obtain target moisture content was 0.233 kW h/kg H2O-0.271 kW h/kg H2O, higher than the blank group's 0.157 kW h/kg H2O. A quantitative criterion (KsiEDW) was adopted to assess the feasibility of EDW. Economically and energetically, the experiment with 4% mu(RS) of CaO added for near-anode modification was the optimal condition in this research, due to its second smallest KsiEDW, the best sludge reduction effect (67.2%), lower final moisture content (46.2%) and less time (640 s) to obtain target moisture content. The results show some mechanisms of EDW and provide experience for practical application.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Compostos de Cálcio , Eletrodos , Óxidos , Água
7.
Environ Res ; 184: 109335, 2020 05.
Artigo em Inglês | MEDLINE | ID: mdl-32169737

RESUMO

Electro-dewatering (EDW) is an emerging technology for improved sludge/sediment dewatering enabling subsequent cost effective treatment for toxicity and pathogenic reduction if required and/or disposal, but the effects of sediment/sludge properties on the efficacy of EDW remain unclear. Here we investigate EDW in the absence of chemical conditioning which can result in secondary pollution. The influence of sediment/sludge volatile solids content (VS), electrical conductivity (EC), pH and zeta potential (ζ), on mechanical and electrical behaviors determining dewaterability and energy consumption (PE) was investigated. Optimization of EDW parameters increased the final solids content (DSf) from 40 wt% to more than 55 wt% for river sediment, while the solids content in municipal sludge was only increased from 10 wt% to 15-20 wt%. Multiple linear regression and statistical analysis showed that electro-dewatering performance is primarily affected by VS and PE is mainly affected by EC. A theoretical basis for engineering design and selection of operational parameters for sludge/sediment electro-dewatering is provided by this study.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Condutividade Elétrica , Eletricidade , Rios , Água
8.
Environ Res ; 180: 108862, 2020 01.
Artigo em Inglês | MEDLINE | ID: mdl-31706597

RESUMO

In this study, the effects of electro-dewatering technology applied to high-salt industrial sludge dewatering performance were investigated, in terms of ions migrations and distributions by model simulation and layered tests. The simulation results of Na+ and K+ migrations were consistent with layered experiments during electro-dewatering, where Na+ ions migrated faster than K+ ions. More than 80% Na+ ions were removed by electromigration, which would be useful in subsequent sludge utilization. The mass specific energy consumption was reduced from 350.08 to 295.88 kWh per ton sludge by means of piecewise voltage electro-dewatering method. This study provided insights into the soluble ions migration and distribution mechanism in electro-dewatering process, and a method to improve commercial application performance of high-salt industrial sludge electro-dewatering.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Eletricidade , Íons , Metais , Água
9.
Environ Res ; 190: 110011, 2020 11.
Artigo em Inglês | MEDLINE | ID: mdl-32763282

RESUMO

Since the effect of electro-dewatering (EDW) on sludge water holding capacity was unknown, tests were conducted in this study to investigate the water holding capacity of EDW sludge and the potential mechanism related to the sludge physicochemical characteristics, EPS properties and sludge structure. Sludge was dewatered to the average moisture content (AMC) of 80%, 70% and 60% with different applied voltages at 20, 30 and 40V in EDW, respectively. Then the dewatered sludge near the anode and cathode were rewatered. The variation of sludge water holding capacity in EDW process was evaluated in terms of filterability and saturated moisture content (SMC), and the filterability was assessed by the specific resistance to filtration (SRF) of rewatered sludge. The results indicated that SRF of rewatered sludge near the cathode increased greatly. The proteins/polysaccharides (PN/PS) of loosely bound extracellular polymeric substances (LB-EPS) was significantly positively correlated with SRF (r = 0.891, p < 0.01). Moreover, the exposure of hydrophobic sites or groups in PN near the cathode improved the surface hydrophobicity of sludge, which reduced the filterability. In addition, higher voltage could destroy the sludge structure near the anode at the later stage of EDW process, leading to the decrease of SRF and SMC. These results expanded the knowledge about changes in sludge properties and water holding capacity during EDW process.


Assuntos
Esgotos , Água , Matriz Extracelular de Substâncias Poliméricas , Filtração , Eliminação de Resíduos Líquidos , Águas Residuárias
10.
J Environ Manage ; 265: 110541, 2020 Jul 01.
Artigo em Inglês | MEDLINE | ID: mdl-32275248

RESUMO

The work evaluated the influence of different operating conditions (voltage, ionic strength and mechanical pressure) on algae electro-osmotic dewatering effect and extracellular organic matter (EOM) regionalization. It was found that the algae electro-dewatering effect became better as the voltage and ionic strength increased, but electro-dewatering effect was decreased when ionic strength was more than 0.006gNaCl/gTSS, this indicated that too high ionic strength will reduce algae electro-dewatering effect. In addition, electro-osmosis effect first increases and then weakens when the pressure was increased. The content of dissolved organic materials (DOM) in the filtrate of both electrodes was increased when the voltage and ionic strength enhanced, the DOM content of filtrate at cathode and anode were increased from 42.9 mg/L, 36.7 mg/L to 68.2 mg/L, 85.3 mg/L when ionic strength raised from 0gNaCl/gTSS to 0.01gNaCl/gTSS, this indicated that a large amount of EOM dissolution as the voltage and ionic strength increased. The DOM content of both electrodes did not change significantly when mechanical pressure changed, anodic oxidation can oxidize and decompose macromolecular weight substances into mid-molecular weight and low molecular weight substances.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Eletricidade , Eletrodos , Concentração Osmolar
11.
J Environ Manage ; 268: 110689, 2020 Aug 15.
Artigo em Inglês | MEDLINE | ID: mdl-32383657

RESUMO

Waste activated sludge requires effective dewatering, high biological stability and retention of nutrients prior to disposal for agricultural application. The study was conducted to evaluate the impact of pressure-driven electro-dewatering (EDW) on improving sludge characteristics related to disposal in agriculture, including biological stability, pathogen availability, heavy metals concentrations and nutrients content. Thickened conditioned and mechanically dewatered sludge samples were collected from two wastewater treatment plants (WWTPs), characterized by different stabilization processes, and treated by a lab-scale device at 5, 15 and 25 V. EDW increased significantly the dry solid (DS) content, up to 43-45%, starting from 2 to 3% of raw sludge. The endogenous value of specific oxygen uptake rate (SOUR), monitored as indicator of biological stability, increased up to 56% and 39% after EDW tests for sludge from two WWTPs. On the other hand, the exogenous SOUR decreased, indicating a significant drop in the active bacterial population. Likewise, a 1-2 log unit reduction was observed for E. coli after EDW tests at 15 and 25 V. However, no remarkable removal of heavy metals, namely chromium, nickel, lead, copper and zinc, was achieved. Finally, the concentration of nutrients for soil, such as carbon, nitrogen, phosphorus and sulfur, was not affected by the EDW process. In conclusion, EDW exerts considerable effects on the biological characteristics of sludge, which should be considered in a proper design of sludge management to ensure safe and sustainable resource recovery.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Agricultura , Escherichia coli , Água
12.
Environ Res ; 157: 30-36, 2017 08.
Artigo em Inglês | MEDLINE | ID: mdl-28511078

RESUMO

The feasibility of pressure-driven electro-dewatering (EDW) on sludge samples taken after different biological processes, stabilisation methods or mechanical dewatering techniques was assessed. First, the influence of potential values on EDW of anaerobically and aerobically stabilised, mechanically dewatered, sludge samples was investigated. Preliminary tests carried out by applying a constant potential (10, 15 and 20V) in a lab-scale device confirmed the possibility to reach a dry solid (DS) content of up to 42.9%, which corresponds to an increase of 15% of the dry content in dewatered sludge without the application of the electrical field. Dewatering increased with the applied potential but at the expense of a higher energy consumption. A potential equal to 15V was chosen as the best compromise for EDW performance, in terms of DS content and energy consumption. Then, the influence of the mechanical dewatering was studied on aerobically stabilised sludge samples with a lower initial DS content: the higher initial water content led to a lower final DS content but with a considerable reduction of energy consumption. Finally, the biological process, studied by comparing sludge samples from conventional activated sludge and membrane bioreactor processes, didn't evidence any influence on EDW. Experimental results shown that DS obtained after mechanical dewatering, volatile solids and conductivity are the main factors influencing EDW. Anaerobically digested sludge reached the highest DS content, thanks to lower organic fraction.


Assuntos
Eletro-Osmose/métodos , Esgotos/análise , Eliminação de Resíduos Líquidos/métodos , Eletro-Osmose/instrumentação
13.
Chemosphere ; 358: 142265, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38719121

RESUMO

Electro-dewatering of sewage sludge with pulsating voltage was conducted under the two different wave shapes (square wave (SQW) and half-sine wave (HSW)) to investigate the influence of wave shape and duty cycle on sludge dewatering performance. The results indicated that, under the same average voltage, the moisture content of dewatered sludge with HSW was 10.3%-35.4% lower than that with SQW, suggesting the better dewatering performance of HSW. The optimal dewatering performance was achieved at duty cycle of 80% for SQW and 60% for SHW. The chemical oxygen demand of filtrate from HSW could be 13% higher than that from SQW, indicating the higher capacity of HSW in breaking sludge cells/floc structure. The applied voltage during electrochemical treatment promoted the hydrolysis of protein in filtrate, and the main components in the electro-dewatered filtrate were fulvic acid- and humic acid-like substances. The specific energy consumption for sludge electro-dewatering were 0.015-0.269 kWh/(kg removed water), and it was almost in linear relationship with duty cycle. By overall considering the energy consumption and electro-dewatering performance, the condition of 60% duty cycle with HSW was obviously better than other conditions, which provides a meaningful guidance for future application of sludge electro-dewatering technology with pulsating voltage.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Esgotos/química , Eliminação de Resíduos Líquidos/métodos , Análise da Demanda Biológica de Oxigênio , Técnicas Eletroquímicas/métodos , Substâncias Húmicas/análise , Água/química , Benzopiranos
14.
Sci Total Environ ; 814: 152544, 2022 Mar 25.
Artigo em Inglês | MEDLINE | ID: mdl-34952058

RESUMO

Residual biosolids can be land applied if they meet microbiological requirements at the time of application. Electro-dewatering technology is shown to reduce biosolids bacterial counts to detection limits with little potential for bacterial regrowth during incubations. Here, we investigated the impacts on Escherichia coli regrowth and microbial communities of biosolids pH, removed nutrients via the filtrate, and inhibitory compounds produced in electro-dewatered biosolids. Findings suggest pH as the primary mechanism impacting E. coli regrowth in electro-dewatered biosolids. Propidium monoazide treatments were effective at removing DNA from dead cells, based on the removal of obligate anaerobes observed after anaerobic incubation. Analyses of high throughput sequenced data showed lower alpha-diversities associated with electro-dewatering treatment and incubation time. Moreover, biosolids pH and incubation period were the main factors contributing to the variations in microbial community compositions after incubation. Results highlight the role of electro-dewatered biosolids' low pH on inhibiting the regrowth of culturable bacteria as well as reducing the microbial community variance.


Assuntos
Escherichia coli , Microbiota , Biossólidos , Concentração de Íons de Hidrogênio , Esgotos
15.
Chemosphere ; 304: 135338, 2022 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-35709836

RESUMO

Lead-containing sludge produced from lead-acid battery factory will cause environmental hazards if they are not treated properly. A novel process was developed to recycle lead from sludge back into Fe-doped PbO2 electrodes and realize sludge reduction in this study. The effects of Fenton conditioning on Pb removal efficiency in electro-kinetic (EK) treatment process and its mechanism as well as electro-dewatering (ED) performance were investigated. It was found that the oxidation of Fenton can promote desorption and release of Pb from the organic binding state, and improve the removal efficiency of Pb during EK process, as well as enhance sludge ED performance. About 63.8 wt% Pb can be removed from sludge during EK process, achieving sludge reduction of 63.5 wt% by ED treatment. The composite PbO2@Fe electrode recovered from lead-containing sludge showed a high electrocatalytic activity for acid red G (ARG) degradation. The electrode obtained by electrodeposition at 20 mA cm-2 had the largest exchange current density (3.26 × 10-5 A cm-2). In the experiment of dye wastewater electrocatalytic degradation, over 99.5% organic matter was degraded within 80 min.


Assuntos
Esgotos , Poluentes Químicos da Água , Eletrodos , Galvanoplastia , Chumbo , Oxirredução , Águas Residuárias , Poluentes Químicos da Água/análise
16.
Chemosphere ; 292: 133416, 2022 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-34953873

RESUMO

The high moisture content (MC) of activated sludge dewatered by traditional vertical electro-dewatering (VED) is unable to meet the disposal requirements. Therefore, different iron forms (ZVI vs. Fe(II))/peroxydisulfate (PDS) combined VED (ZVI/PDS-VED and Fe(II)/PDS-VED) were employed to enhance the dewaterability of activated sludge. The dewatering behaviors of the two combined dewatering processes and the underlying mechanism related to the sludge characteristics were investigated and compared. Sludge was conditioned using ZVI/PDS and Fe(II)/PDS, respectively, and then dewatered by the VED in the experiment. Experimental results showed that with 0.3 g (g dry solids (DS))-1 of iron activators, 0.583 g (g DS) -1 of PDS, and 30 V of voltage, the MC of sludge after ZVI/PDS-VED and Fe(II)/PDS-VED reached the minimum values of 50.6 ± 1.2% and 32.1 ± 1.5%, respectively. ZVI/PDS and Fe(II)/PDS conditioning reduced the MC difference of sludge between the anode and the cathode during the VED, facilitating the water homogenization in the sludge cake. ZVI/PDS-VED and Fe(II)/PDS-VED could effectively reduce the bound water and the free water. Free water had high correlations with α-helix (r = 0.999, p < 0.05) and CO (r = 0.998, p < 0.05). Compared with the traditional VED and the ZVI/PDS-VED, the Fe(II)/PDS-VED had a greater improvement of sludge dewaterability due to the more efficient degradation of extracellular polymeric substances and the increase of sludge surface hydrophobicity. This study promoted the development of the new sludge deep-dewatering technology.


Assuntos
Ferro , Esgotos , Matriz Extracelular de Substâncias Poliméricas , Compostos Ferrosos , Oxirredução , Eliminação de Resíduos Líquidos , Água
17.
Sci Total Environ ; 818: 151787, 2022 Apr 20.
Artigo em Inglês | MEDLINE | ID: mdl-34808190

RESUMO

Pressurized vertical electro-osmotic dewatering (PVEOD) has been regarded as a feasible method to achieve sludge deep-dewatering, but the dewatering efficiency is still challenged by high electric resistance. This study employed cationic polyacrylamide (CPAM) as a skeleton builder to enhance electro-osmotic flow in PVEOD. The sludge dewatering efficiency and synergistic effect of CPAM and PVEOD were elucidated. The sludge morphology, surface property, extracellular polymeric substances (EPS) destruction and migration, spatial distributions of proteins and polysaccharides, and current changes were investigated. After the addition of optimal CPAM dose, the sludge formed a uniform and porous structure that provided water channels and enhanced electric transport, thus promoting EPS destruction. The sludge moisture content (MC) analysis indicated the more liberation of bound water due to EPS destruction. Besides, the re-flocculation of disintegrated sludge flocs improved the sludge filtration and thus dewaterability. Instantaneous energy consumption (Et,0.5) was optimized and two-step synergistic mechanism was thus proposed. These findings indicated that the combination of CPAM and PVEOD is a promising strategy to broaden the scope of industrial application of sludge deep-dewatering.


Assuntos
Resinas Acrílicas , Esgotos , Resinas Acrílicas/química , Matriz Extracelular de Substâncias Poliméricas , Floculação , Esgotos/química , Eliminação de Resíduos Líquidos/métodos , Água/química
18.
Sci Total Environ ; 801: 149753, 2021 Dec 20.
Artigo em Inglês | MEDLINE | ID: mdl-34438136

RESUMO

Electro-dewatering (ED) is an attractive technology for enhancing dewaterability of waste activated sludge (WAS), and the distribution and composition of EPS and secondary structure of extracellular protein in sludge has a great influence on the sludge dewaterability. Therefore, in order to optimize and regulate sludge ED process, it is necessary to study the influence of EPS components and composition on the efficiency of sludge ED. In this study, the effects of distribution and composition of EPS and the structure of extracellular proteins on the ED rates and performance were analyzed using eight sludges from different sewage treatment process. The results showed that ED rates at both electrodes were significantly negatively correlated with the concentration of soluble EPS (S-EPS) and loosely bound EPS (LB-EPS), and this correlation was gradually weakened with the in-depth structure of layered EPS structure. High concentration of S-EPS and LB-EPS decreased the initial current and the pH gradient, deteriorating the anodic oxidation and acidification, which affect the release and degradation of EPS. Additionally, the proteins secondary structure can be destroyed and transformed by anodic oxidation and acidification, which can impact the protein water-holding capacity and ED performance.


Assuntos
Matriz Extracelular de Substâncias Poliméricas , Esgotos , Eliminação de Resíduos Líquidos , Águas Residuárias , Água
19.
Water Res ; 189: 116611, 2021 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-33221587

RESUMO

The disposal of huge municipal sludge with high moisture content has led to numerous energy consumption and brought extensive concerns in the world. In this paper, three dewatering modes, ultrahigh-pressure mechanical dewatering mode (UMDW), pressurized electro-dewatering (PEDW) with constant voltage mode (U-PEDW) and constant voltage gradient mode (G-PEDW) were performed on a self-designed pressurized electro-dewatering apparatus for municipal sludge. The pore structures and moisture distributions were detected by low-field nuclear magnetic resonance technology. Meanwhile, the moisture distributions and quantitative bound strength were analyzed by the thermogravimetric differential scanning calorimetry test. Moreover, a pore-scale electro-osmosis model was accordingly developed based on the fractal characteristics of pore size distribution. Finally, the effect of dewatering modes and operating parameters on moisture content and energy consumption were examined in detail. The results indicate that the pore-scale electro-osmosis model show good consistency with experimental data. The electric field can drive the middle-layers-water to overcome the capillary pressure, and make G-PEDW removing more water than UMDW. The moisture content of dewatered municipal sludge by G-PEDW and U-PEDW reaches to 28.41% and 27.33%, respectively. Furthermore, the energy consumption of G-PEDW is 189.62Wh/kg.H2O, it is much lower than that of U-PEDW. Therefore, the G-PEDW mode with low moisture content and less energy consumption indicates best dewatering performance compared with UMDW and U-PEDW modes. The present work is helpful to understand the dewatering mechanisms of G-PEDW and provides useful guidelines for G-PEDW dewatering technology.


Assuntos
Esgotos , Eliminação de Resíduos Líquidos , Eletricidade , Águas Residuárias , Água
20.
Chemosphere ; 243: 125372, 2020 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-31759206

RESUMO

Electro-dewatering of sewage sludge with pulsating direct current (PDC-dewatering) was conducted to investigate the effects of pulsating frequency (0.01-60 Hz) and duty cycle (DTC) (20-100%) on sludge dewatering. The results indicated that both the frequency and DTC showed marked influences on electro-dewatering. Compared with the condition under the stable direct current (SDC-dewatering) of 30 V, the filtrate discharged from PDC-dewatering (at DTC of 40-60% and frequency of 30 Hz) was about 8% higher than that from SDC-dewatering. At DTC of 40%, the sludge electro-dewatering performance was promoted when the frequency increased from 0.01 Hz to 30 Hz. Compared with SDC-dewatering, PDC-dewatering can effectively mitigate ohmic heating. Layered tests were also conducted to investigate the differences of SDC- and PDC-dewatering in the distributions of water, pH, organic matters, zeta potential and conductivity in the upper, middle and lower layer of sludge cake. The results indicated that the variation tendencies of these parameters were similar between SDC- and PDC-dewatering, but the water, organic matters and charged ions in sludge cake were more homogeneously distributed during PDC-dewatering than SDC-dewatering. In addition, the anodic pH of PDC-dewatering was higher than that of SDC-dewatering, suggesting the potential of mitigating anodic corrosion during PDC-dewatering. Finally, energy consumptions of PDC- and SDC-dewatering were calculated and compared. The effects of frequency and DTC on energy consumption were investigated. PDC-dewatering was found to be more energy efficient than that of SDC-dewatering, making PDC-dewatering a promising electro-dewatering technology in future.


Assuntos
Eliminação de Resíduos Líquidos/métodos , Eletricidade , Eletrodos , Íons , Esgotos , Águas Residuárias , Água
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